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Zirconium,tetrakis(2,4-pentanedionato-kO2,kO4)-,(SA-8-11''11''1'1'''1'1''')-

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

Product name

Zirconium(IV) acetylacetonate

2. HAZARDS IDENTIFICATION

Classification of the substance or mixture

According to Regulation (EC) No1272/2008

Acute toxicity, Inhalation (Category 4)

Acute toxicity, Dermal (Category 4)

Acute toxicity, Oral (Category 4)

Skin irritation (Category 2)

Eye irritation (Category 2)

Reproductive toxicity (Category 2)

Specific target organ toxicity - single exposure (Category 3)

According to European Directive 67/548/EEC as amended.

Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin.

Possible risk of harm to the unborn child.

Label elements

Pictogram

Signal word

Hazard statement(s)

H302

H312

H315

H319

H332

H335

H361

Precautionary statement(s)

P261

P280

P305 + P351 + P338

Warning

Harmful if swallowed.

Harmful in contact with skin.

Causes skin irritation.

Causes serious eye irritation.

Harmful if inhaled.

May cause respiratory irritation.

Suspected of damaging fertility or the unborn child.

Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.

Wear protective gloves/ protective clothing.

IF IN EYES: Rinse cautiously with water for several minutes. Remove

contact lenses, if present and easy to do. Continue rinsing.

Hazard symbol(s)

R-phrase(s)

R20/21/22

R36/37/38

R63

S-phrase(s)

S26

S36/37

Harmful

Harmful by inhalation, in contact with skin and if swallowed.

Irritating to eyes, respiratory system and skin.

Possible risk of harm to the unborn child.

Keep container tightly closed.

In case of contact with eyes, rinse immediately with plenty of water and

seek medical advice.

Wear suitable protective clothing and gloves.

Other hazards - none

3. COMPOSITION/INFORMATION ON INGREDIENTS

Synonyms

Formula

Molecular Weight

Tetrakis(2,4-pentanedionato)zirconium(IV)

2,4-Pentanedionezirconium(IV) derivative

Zirconium(IV) 2,4-pentanedionate

C20H28O8Zr

487,66 g/mol

CAS-No.

EC-No.

Classification

Concentration

Zirconium(IV) acetylacetonate

17501-44-9

241-510-5

Acute Tox. 4; Skin Irrit. 2; Eye

Irrit. 2; Repr. 2; STOT SE 3;

H302, H312, H315, H319,

H332, H335, H361

Xn, R20/21/22 - R36/37/38 -

R63

For the full text of the H-Statements mentioned in this Section, see Section 16.

4. FIRST AID MEASURES

General advice

Consult a physician. Show this safety data sheet to the doctor in attendance.

If inhaled

If breathed in, move person into fresh air. If not breathing give artificial respiration Consult a physician.

In case of skin contact

Wash off with soap and plenty of water. Consult a physician.

In case of eye contact

Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

If swallowed

Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

5. FIRE-FIGHTING MEASURES

Suitable extinguishing media

Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Special protective equipment for fire-fighters

Wear self contained breathing apparatus for fire fighting if necessary.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions

Use personal protective equipment. Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation.

Environmental precautions

Do not let product enter drains.

Methods and materials for containment and cleaning up

Pick up and arrange disposal without creating dust. Keep in suitable, closed containers for disposal.

7. HANDLING AND STORAGE

Precautions for safe handling

Avoid contact with skin and eyes. Avoid formation of dust and aerosols.

Provide appropriate exhaust ventilation at places where dust is formed. Normal measures for preventive fire

protection.

Conditions for safe storage

Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

hygroscopic

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Personal protective equipment

Respiratory protection

Where risk assessment shows air-purifying respirators are appropriate use a full-face particle respirator

type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering controls. If the

respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and

components tested and approved under appropriate government standards such as NIOSH (US) or CEN

(EU).

Hand protection

The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the

standard EN 374 derived from it.

Handle with gloves.

Eye protection

Safety glasses with side-shields conforming to EN166

Skin and body protection

Choose body protection according to the amount and concentration of the dangerous substance at the

work place.

Hygiene measures

Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at

the end of workday.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance

Form

Colour

Safety data

Melting point

Boiling point

Flash point

Ignition temperature

Lower explosion limit

Upper explosion limit

Water solubility

powder

light yellow

no data available

191 °C

no data available

10. STABILITY AND REACTIVITY

Chemical stability

Stable under recommended storage conditions.

Conditions to avoid

Avoid moisture.

Materials to avoid

Strong oxidizing agents, Strong acids

Hazardous decomposition products

Hazardous decomposition products formed under fire conditions. - Carbon oxides, Zirconium oxides

11. TOXICOLOGICAL INFORMATION

Acute toxicity

LD50 Intraperitoneal - mouse - 316 mg/kg

Remarks: Peripheral Nerve and Sensation:Flaccid paralysis without anesthesia (usually neuromuscular

blockage). Sense Organs and Special Senses (Nose, Eye, Ear, and Taste):Eye:Other. Lungs, Thorax, or

Respiration:Dyspnea.

Skin corrosion/irritation

no data available

Serious eye damage/eye irritation

no data available

Respiratory or skin sensitization

no data available

Germ cell mutagenicity

no data available

Carcinogenicity

IARC: No component of this product present at levels greater than or equal to 0.1% is identified as

probable, possible or confirmed human carcinogen by IARC.

Reproductive toxicity

Suspected human reproductive toxicant

Specific target organ toxicity - single exposure

Inhalation - May cause respiratory irritation.

Specific target organ toxicity - repeated exposure

no data available

Aspiration hazard

no data available

Potential health effects

Inhalation

Ingestion

Skin

Eyes

Aggravated

Harmful if inhaled. Causes respiratory tract irritation.

Harmful if swallowed.

Harmful if absorbed through skin. Causes skin irritation.

Causes eye irritation.

May cause nervous system disturbances.,

Medical Condition

Signs and Symptoms of Exposure

May liberate 2,4-pentanedione upon decomposition. 2,4-Pentanedione has the following toxicological hazards:

toxic, irritant, neurological hazard, teratogen, possible mutagen, target organ - thymus. In humans, 2,4-

pentanedione is reported to cause contact dermatitis and contact urticaria.

Additional Information

RTECS: ZH9280000

12. ECOLOGICAL INFORMATION

Toxicity

no data available

Persistence and degradability

no data available

Bioaccumulative potential

no data available

Mobility in soil

no data available

PBT and vPvB assessment

no data available

Other adverse effects

no data available

13. DISPOSAL CONSIDERATIONS

Product

Observe all federal, state, and local environmental regulations. Contact a licensed professional waste

disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn

in a chemical incinerator equipped with an afterburner and scrubber.

Contaminated packaging

Dispose of as unused product.

14. TRANSPORT INFORMATION

ADR/RID

Not dangerous goods

IMDG

Not dangerous goods

IATA

Not dangerous goods

15. REGULATORY INFORMATION

This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.

16. OTHER INFORMATION

Text of H-code(s) and R-phrase(s) mentioned in Section 3

Acute Tox.

Eye Irrit.

H302

H312

H315

H319

H332

H335

H361

Repr.

Skin Irrit.

R20/21/22

R36/37/38

R63

Acute toxicity

Eye irritation

Harmful if swallowed.

Harmful in contact with skin.

Causes skin irritation.

Causes serious eye irritation.

Harmful if inhaled.

May cause respiratory irritation.

Suspected of damaging fertility or the unborn child.

Reproductive toxicity

Skin irritation

Harmful

Harmful by inhalation, in contact with skin and if swallowed.

Irritating to eyes, respiratory system and skin.

Possible risk of harm to the unborn child.

Further information

The above information is believed to be correct but does not purport to be all inclusive and
shall be used only as a guide. The information this document is based on the resent state
of our knowledge and is applicable to the product with regard to appropriate safety precautions.
It does not represent any guarantee of the properties of the product. Lookchem shall not be
held liable for any damage resulting from handling or from contact with the above product.
See reverse side of invoice or packing slip for additional terms and conditions of sale.

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