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Section 1 - Chemical Product and Company Identification |
MSDS Name: Decahydronaphthalene-d18, 99.5 atom % D
Catalog Numbers:
AC202760000, AC202760010
Synonyms:
Bicyclo(4.4.0)decane; Decalin; Naphthalane; Perhydronaphthalene;
Decahydronaphthalene.
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
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Section 2 - Composition, Information on Ingredients
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| CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
| 28788-42-3 |
Decahydronaphthalene-D18 |
99.5 | unlisted |
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Section 3 - Hazards Identification
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EMERGENCY OVERVIEW
Appearance: clear, colorless liquid. Flash Point: 57 deg C.
Warning! Causes respiratory tract
irritation. Flammable liquid and vapor.
Causes eye and skin irritation. Aspiration hazard if swallowed. Can
enter lungs and cause damage. May form explosive peroxides. May
cause central nervous system depression. This material has been
reported to be susceptible to autoxidation and therefore should be
classified as peroxidizable. Hygroscopic (absorbs moisture from the
air).
Target Organs: Central nervous system, eyes,
skin, mucous membranes.
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye
burns.
Skin:
Prolonged and/or repeated contact may cause irritation and/or
dermatitis. Exposure may cause irritation and possible burns.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. Aspiration of material into the lungs may cause chemical
pneumonitis, which may be fatal. May cause blue or greenish-brown
urine.
Inhalation:
Inhalation of high concentrations may cause central nervous system
effects characterized by nausea, headache, dizziness, unconsciousness
and coma. Causes respiratory tract irritation. May cause kidney
damage. High concentrations may cause pulmonary edema and lung
hemmorrages.
Chronic:
Prolonged or repeated skin contact may cause defatting and
dermatitis. In Decalin studies, NTP found clear evidence of
carcinogenicity in male rats. However, the mechanism is not relevant
to humans. NTP found no evidence of carcinogenicity in female rats,
no evidence in male mice, and equivocal evidence in female mice.
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Section 4 - First Aid Measures
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Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
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Section 5 - Fire Fighting Measures
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General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Containers may explode in the heat of a fire. Flammable liquid and
vapor. Vapors are heavier than air and may travel to a source of
ignition and flash back. Vapors can spread along the ground and
collect in low or confined areas.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam. For large fires, use water spray or fog. Do
NOT use straight streams of water. Cool containers with flooding
quantities of water until well after fire is out.
Flash Point: 57 deg C ( 134.60 deg F)
Autoignition Temperature: 250 deg C ( 482.00 deg F)
Explosion Limits, Lower: 0.7 @ 100?C
Upper: 4.9 @ 100?C
NFPA Rating:
(estimated) Health: 2; Flammability: 2; Instability: 0
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Section 6 - Accidental Release Measures
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General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation.
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Section 7 - Handling and Storage
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Handling:
Use with adequate ventilation. Ground and bond containers when
transferring material. Avoid contact with eyes, skin, and clothing.
Empty containers retain product residue, (liquid and/or vapor), and
can be dangerous. Keep container tightly closed. Avoid ingestion and
inhalation. If peroxide formation is suspected, do not open or move
container. Do not use if the material has evaporated to dryness. Do
not pressurize, cut, weld, braze, solder, drill, grind, or expose
empty containers to heat, sparks or open flames.
Storage:
Keep away from sources of ignition. Store in a tightly closed
container. Keep under a nitrogen blanket. Store in a cool, dry,
well-ventilated area away from incompatible substances. After
opening, purge container with nitrogen before reclosing.
Periodically test for peroxide formation on long-term storage.
Addition of water or appropriate reducing materials will lessen
peroxide formation. Containers should be dated when opened and
tested periodically for the presence of peroxides. Should crystals
form in a peroxidizable liquid, peroxidation may have occurred and
the product should be considered extremely dangerous. In this
instance, the container should only be opened remotely by
professionals. All peroxidizable substances should be stored away
from heat and light and be protected from ignition sources.
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Section 8 - Exposure Controls, Personal Protection
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Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
| Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
| Decahydronaphthalene-D18
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none listed
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none listed
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none listed
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| Decahydronaphthalene
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none listed
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none listed
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none listed
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OSHA Vacated PELs:
Decahydronaphthalene-D18:
No OSHA Vacated PELs are listed for this chemical.
Decahydronaphthalene:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
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Section 9 - Physical and Chemical Properties
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Physical State: Liquid
Appearance: clear, colorless
Odor: aromatic odor
pH: Not available.
Vapor Pressure: 1 mm Hg @ 22.7C
Vapor Density: 4.8 (air=1)
Evaporation Rate:Not available.
Viscosity: 3 mPa s 20 C
Boiling Point: 70-71 deg C @ 17 mm Hg
Freezing/Melting Point:-31 deg C
Decomposition Temperature:Not available.
Solubility: Insoluble.
Specific Gravity/Density:1.0100
Molecular Formula:C10D18
Molecular Weight:156.40
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Section 10 - Stability and Reactivity
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Chemical Stability:
Stable under normal temperatures and pressures. Prolonged exposure
to air and sunlight may form unstable peroxides. Under normal storage
conditions, peroxidizable compounds can form and accumulate peroxides
which may explode when subjected to heat or shock. This material is
most hazardous when peroxide levels are concentrated by distillation
or evaporation.
Conditions to Avoid:
Light, ignition sources, exposure to air, excess heat, moist air.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
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Section 11 - Toxicological Information
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RTECS#:
CAS# 28788-42-3
unlisted.
CAS# 91-17-8:
QJ3150000
LD50/LC50:
Not available.
CAS# 91-17-8:
Inhalation, rat:
LC50 = 710 ppm/4H;
Oral, rat: LD50
= 4170 mg/kg;
Skin, rabbit: LD50 =
5900 uL/kg;
.
Carcinogenicity:
CAS# 28788-42-3:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 91-17-8:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No information present.
Teratogenicity:
No information present.
Reproductive Effects:
No information present.
Mutagenicity:
No information present.
Neurotoxicity:
No information present.
Other Studies:
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Section 12 - Ecological Information
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No information available.
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Section 13 - Disposal Considerations
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Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
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Section 14 - Transport Information
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US DOT |
Canada TDG |
| Shipping Name: |
DOT regulated - small quantity provisions apply (see 49CFR173.4) |
No information available. |
| Hazard Class: |
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| UN Number: |
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| Packing Group: |
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Section 15 - Regulatory Information
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US FEDERAL
TSCA
CAS# 28788-42-3 is not listed on the TSCA inventory.
It is for research and development use only.
CAS# 91-17-8 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 91-17-8: immediate, fire.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 28788-42-3 is not present on
state lists from CA, PA, MN, MA, FL, or NJ.
CAS# 91-17-8 can be found on the
following state right to know lists: New Jersey, Pennsylvania,
Massachusetts.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system and skin.
Safety Phrases:
S 23 Do not inhale gas/fumes/vapour/spray.
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 28788-42-3: No information available.
CAS# 91-17-8: 1
Canada - DSL/NDSL
CAS# 91-17-8 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of D2B, B3.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
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Section 16 - Additional Information
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MSDS Creation Date: 9/02/1997
Revision #11 Date: 10/03/2005
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
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