allyl succinic acid
Conditions | Yield |
---|---|
With acetyl chloride for 3h; Cyclization; Heating; | 85% |
Conditions | Yield |
---|---|
With 4-methoxy-phenol; dimethyltin dichloride In toluene at 175 - 200℃; under 21307.1 - 32788.1 Torr; for 12 - 48h; Reactivity; | 41% |
With 4-methoxy-phenol; Trichlorbutylstannan In toluene at 175℃; for 12h; Reactivity; | |
With 4-methoxy-phenol; dibutyltin chloride In toluene at 175℃; for 12h; Reactivity; | |
With 4-methoxy-phenol; cadmium(II) iodide In toluene at 200℃; for 12h; Reactivity; |
Conditions | Yield |
---|---|
With benzene at 250℃; | |
With benzene at 200℃; |
Conditions | Yield |
---|---|
at 250℃; under 54427.6 Torr; |
3-((tert-butoxy)carbonyl)hex-5-enoic acid
allylsuccinic anhydride
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 80 percent / trifluoroacetic acid / CH2Cl2 / 24 h / 20 °C 2: 85 percent / AcCl / 3 h / Heating View Scheme |
Conditions | Yield |
---|---|
In dichloromethane at 25℃; for 18h; | 100% |
methanol
allylsuccinic anhydride
dimethyl 2-(prop-2-en-1-yl)butanedioate
Conditions | Yield |
---|---|
With hydrogenchloride; silica gel In water at 70℃; Schlenk technique; | 100% |
Conditions | Yield |
---|---|
With 2,2'-azobis(isobutyronitrile) at 72℃; for 2h; | 99.6% |
allylsuccinic anhydride
n-perfluorohexyl iodide
3-(perfluorohexyl)-2-iodopropyl-2-butane-1,4-dioic acid anhydride
Conditions | Yield |
---|---|
With 2,2'-azobis(isobutyronitrile) at 70 - 92℃; for 7h; | 99.6% |
Conditions | Yield |
---|---|
With water at 110℃; Inert atmosphere; Schlenk technique; | 98.5% |
With sodium carbonate |
Conditions | Yield |
---|---|
Stage #1: 1,4-bis(dimethylsilyl)benzene; allylsuccinic anhydride With dihydrogen hexachloroplatinate In ethanol; toluene at 70℃; Stage #2: 1,4-bis(dimethylsilyl)benzene In ethanol; toluene at 70 - 90℃; for 3.33333h; | 95% |
allylsuccinic anhydride
n-butylguanidine hydrochloride
Conditions | Yield |
---|---|
With 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; N-ethyl-N,N-diisopropylamine In N,N-dimethyl-formamide at 50℃; for 5h; Reagent/catalyst; Inert atmosphere; | 85% |
allylsuccinic anhydride
1,3,3,5,5-hexamethyltrisiloxane
4-vinyl benzylamine
Conditions | Yield |
---|---|
Stage #1: allylsuccinic anhydride; 1,3,3,5,5-hexamethyltrisiloxane With platinum 1,3-divinyl-1,1,3,3-tetramethyldisiloxane at 90 - 110℃; for 1.5h; Inert atmosphere; Stage #2: 4-vinyl benzylamine In toluene at 20℃; for 0.5h; Stage #3: With pyridine; acetic anhydride In toluene at 60℃; for 2h; | 81% |
allylsuccinic anhydride
trimethoxysilylethyl-1,1,3,3-tetramethyldisiloxane
C16H34O7Si3
Conditions | Yield |
---|---|
platinum 1,3-divinyl-1,1,3,3-tetramethyldisiloxane at 100 - 110℃; for 2h; Inert atmosphere; | 76.7% |
allylsuccinic anhydride
Conditions | Yield |
---|---|
With dibenzoyl peroxide In water; toluene | 67.3% |
Conditions | Yield |
---|---|
at 145 - 160℃; under 0.1 Torr; | 63% |
allylsuccinic anhydride
bis(pinacol)diborane
(Z)-3-[2,3-bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)allyl]dihydrofuran-2,5-dione
Conditions | Yield |
---|---|
With (CH3Si(C6H4P(C6H3(CF3)2)2)2)Pd(SO3CF3); triethylaluminum In toluene at 60℃; for 6h; Inert atmosphere; | 59% |
With AlEt3; (CH3Si(C6H4P(C6H3(CF3)2)2)2)Pd(SO3CF3) In toluene 2 equiv. B2pin2, 60°C, 6 h; | 59% |
With (CH3Si(C6H4P(C6H3(CF3)2)2)2)Pd(SO3CF3); triethylaluminum In toluene at 60℃; for 6h; Inert atmosphere; stereoselective reaction; | 52% |
allylsuccinic anhydride
t-butyldimethylsiyl triflate
Conditions | Yield |
---|---|
Stage #1: allylsuccinic anhydride With triethylamine In diethyl ether at 0℃; for 0.166667h; Inert atmosphere; Stage #2: t-butyldimethylsiyl triflate In diethyl ether at 0 - 23℃; Inert atmosphere; | 53% |
Conditions | Yield |
---|---|
Erwaermen des Reaktionsprodukts mit Schwefelsaeure enthaltendem Methanol; |
allylsuccinic anhydride
1H,1H,2H,2H-Perfluorodecanethiol
3-[3-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluoro-decylsulfanyl)-propyl]-dihydro-furan-2,5-dione
Conditions | Yield |
---|---|
With 2,2'-azobis(isobutyronitrile) at 50 - 88℃; for 2h; | 31.0 g |
allylsuccinic anhydride
2-perfluorohexylethanethiol
[3-(perfluorohexylethanethia)]prop-1-yl-2-butane-1,4-dioic acid anhydride
Conditions | Yield |
---|---|
With 2,2'-azobis(isobutyronitrile) In hexane at 70℃; for 18h; | 4.3 mmol |
Conditions | Yield |
---|---|
In toluene at 6 - 108℃; for 2.5h; |
Conditions | Yield |
---|---|
In dichloromethane; toluene at 10 - 119℃; for 2h; |
Conditions | Yield |
---|---|
With modified cinchona alkaloid (DHQD)2AQN In diethyl ether at -24℃; |
allylsuccinic anhydride
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 63 percent / 145 - 160 °C / 0.1 Torr 2: 94 percent / DCC View Scheme |
allylsuccinic anhydride
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: 99.6 percent / AIBN / 7 h / 70 - 92 °C 2: aq. KOH / 6.5 h / 25 °C 3: aq. H2SO4 View Scheme |
allylsuccinic anhydride
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: 99.6 percent / AIBN / 7 h / 70 - 92 °C 2: aq. KOH / 6.5 h / 25 °C 3: aq. H2SO4 View Scheme |
allylsuccinic anhydride
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 99.6 percent / AIBN / 7 h / 70 - 92 °C 2: aq. KOH / 6.5 h / 25 °C View Scheme |
allylsuccinic anhydride
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 4.3 mmol / AIBN / hexane / 18 h / 70 °C 2: CH2Cl2 / 72 h / 25 °C View Scheme |
allylsuccinic anhydride
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 4.3 mmol / AIBN / hexane / 18 h / 70 °C 2: CH2Cl2 / 5.5 h / 18 - 25 °C View Scheme |
Molecular Formula: C7H8O3
Molar mass: 140.14 g/mol
EINECS: 231-412-0
Density: 1.149 g/cm3
Flash Point: 115.9 °C
Index of Refraction: 1.469
Boiling Point: 254 °C at 760 mmHg
Vapour Pressure: 0.0177 mmHg at 25°C
Product categories of Allylsuccinic anhydride (7539-12-0): Professional Olefins
Structure of Allylsuccinic anhydride (7539-12-0):
XLogP3-AA: 0.7
H-Bond Donor: 0
H-Bond Acceptor: 3
Systematic Name: 3-Allyltetrahydrofuran-2,5-dione
SMILES: O=C1OC(=O)CC1C\C=C
InChI: InChI=1/C7H8O3/c1-2-3-5-4-6(8)10-7(5)9/h2,5H,1,3-4H2
InChIKey: WUMMIJWEUDHZCL-UHFFFAOYAU
Std. InChI: InChI=1S/C7H8O3/c1-2-3-5-4-6(8)10-7(5)9/h2,5H,1,3-4H2
Std. InChIKey: WUMMIJWEUDHZCL-UHFFFAOYSA-N
1. | skn-rbt 10 mg/24H open SEV | AIHAAP American Industrial Hygiene Association Journal. 23 (1962),95. | ||
2. | orl-rat LD50:1070 mg/kg | AIHAAP American Industrial Hygiene Association Journal. 23 (1962),95. | ||
3. | skn-rbt LD50:320 mg/kg | AIHAAP American Industrial Hygiene Association Journal. 23 (1962),95. |
Poison by skin contact. Moderately toxic by ingestion. A severe skin irritant. See also ANHYDRIDES and ALLYL COMPOUNDS. When heated to decomposition it emits acrid smoke and irritating fumes.
Risk Statements:
20: Harmful by inhalation
21: Harmful in contact with skin
22: Harmful if swallowed
36: Irritating to the eyes
37: Irritating to the respiratory system
38: Irritating to the skin
Safety Statements:
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36: Wear suitable protective clothing
37: Wear suitable gloves
39: Wear eye/face protection
Allylsuccinic anhydride (7539-12-0) also can be called 3-Allyl(dihydro)furan-2,5-dione ; 2,5-furandione, dihydro-3-(2-propen-1-yl)- and Succinic anhydride, allyl- .
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