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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

1H-Pyrrole, 2-phenyl-

Cas:3042-22-6

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

1H-Pyrrole, 2-phenyl-

Cas:3042-22-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

2-PHENYLPYRROLE CAS:3042-22-6 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermedia

2-PHENYLPYRROLE CAS:3042-22-6

Cas:3042-22-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

1H-Pyrrole, 2-phenyl-

Cas:3042-22-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

1H-Pyrrole, 2-phenyl-

Cas:3042-22-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

2-Phenyl-1H-pyrrole

Cas:3042-22-6

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

2-phenyl-1H-Pyrrole

Cas:3042-22-6

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

2-PHENYLPYRROLE

Cas:3042-22-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

2-phenyl-1H-Pyrrole

Cas:3042-22-6

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Hangzhou Huarong Pharm Co., Ltd.

We Huarong Pharm can provide Customized Synthesis & Process R&D & APIs and intermediates Production & Quality Research & Registration Application, especially our GMP validation service which complies with SFDA, FDA, WHO and EU EMPA. O

2-PHENYLPYRROLE

Cas:3042-22-6

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

2-phenyl-1H-Pyrrole

Cas:3042-22-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

2-phenyl-1H-Pyrrole

Cas:3042-22-6

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

SAGECHEM LIMITED

SAGECHEM is a chemical R&D, manufacturing and distribution company in China since 2009, including pharmaceutical intermediates, agrochemical, dyestuff intermediates, organosilicone, API and etc. We also offer a full range of services in custom synthe

SAGECHEM/2-Phenylpyrole

Cas:3042-22-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

2-phenyl-1H-Pyrrole

Cas:3042-22-6

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

2-phenyl-1H-Pyrrole

Cas:3042-22-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Finebiotech Co.,Ltd.

Shanghai Finebiotech Co.,Ltd.was established in 2020, which providing professional chemical services. As a customer-oriented company, we have distinguished ourself from others in providing worldwide customers with cost-effective and efficient service

2-Phenyl-1H-pyrrole

Cas:3042-22-6

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Henan Tianfu Chemical Co., Ltd.

1.Our services:A.Supply sampleB.The packing also can be according the customers` requirmentC.Any inquiries will be replied within 24 hoursD.we provide Commerical Invoice, Packing List, Bill of loading, COA , Health certificate and Origin certificate.

1H-Pyrrole, 2-phenyl-

Cas:3042-22-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Antimex Chemical Limied

1H-Pyrrole, 2-phenyl-Appearance:detailed see specifications Storage:Keep away of light, cool place Package:25kg/drum;200kg/drum Application:It is an important raw material and intermediate used in Organic Synthesis, Pharmaceuticals, Agrochemicals and

1H-Pyrrole, 2-phenyl-

Cas:3042-22-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hubei Langyou International Trading Co., Ltd

2-phenyl-1H-Pyrrole Application:2-phenyl-1H-Pyrrole

2-phenyl-1H-Pyrrole

Cas:3042-22-6

Min.Order:0

Negotiable

Type:Other

inquiry

Hangzhou Fandachem Co.,Ltd

1H-Pyrrole, 2-phenyl- cas 3042-22-6Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

1H-Pyrrole, 2-phenyl- cas 3042-22-6

Cas:3042-22-6

Min.Order:0

Negotiable

Type:Other

inquiry

Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

2-PHENYLPYRROLE

Cas:3042-22-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Sartort Biopharma Co., Ltd

Best quality with low price Storage:ln stock Package:25kg/Barrel Application:Chemicals Transportation:Express/Sea/Air Port:Shanghai

1H-Pyrrole,2-phenyl-

Cas:3042-22-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou ZeErRui Chemical Co., Ltd.

Hangzhou ZeErRui Chemical Co., Ltd. is focused on customization, research and development and production of APIs and advanced intermediates, which can effectively compensate for the deficiencies of traditional CRO and CMO. Priority of high-tech barri

2-phenyl-1H-Pyrrole

Cas:3042-22-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Newgreat Chemical Co., Ltd

Wuhan Xinweiye Chemical Co., Ltd. is mainly engaged in the process development and production of customized synthesis and pharmaceutical intermediates. We have professional researchers in organic synthesis, analytical chemistry and production process

2-phenyl-1H-Pyrrole

Cas:3042-22-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hunan Longxianng Runhui Trading Co.,Ltd

2-phenyl-1H-PyrroleAppearance:white crystalline powder Storage:Shading, sealed, dry place. Package:aluminous bag Application:API Transportation:By express (Door to door) such as FEDEX, DHL, EMS for small amount. By air(airport to airport) or by sea L

2-phenyl-1H-Pyrrole

Cas:3042-22-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

AstaTech ( Chengdu) BioPharmaceutical Corp.

Quality assurance, stable process and affordable priceAppearance:detailed see specifications Storage:enquiry Package:according to the clients requirement Application:Pharmaceutical intermediates Transportation:Normal Port:chengdu

2-phenyl-1H-pyrrole

Cas:3042-22-6

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Saiwante (shanghai) New Material Technology Co., Ltd.

Stable supply of goods and provision of high-quality services Application:As raw materials in the field of medicine and biology

2-phenyl-1H-Pyrrole

Cas:3042-22-6

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Chemlyte Solutions

factory?direct?sale Application:Fine chemical intermediates, used as the main raw material for the synthesis of various pesticides, medicines, surfactants, polymer monomers, and antifungal agents

2-phenyl-1H-Pyrrole

Cas:3042-22-6

Min.Order:0

Negotiable

Type:Other

inquiry

ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

2-PHENYLPYRROLE

Cas:3042-22-6

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Bide Pharmatech Ltd

Our mission is to provide high-quality and innovative products to our customers. By offering a broad range of products, custom synthesis and personalized services, Bide can help scientists speeding up their research in the chemical and pharmaceutical

2-Phenyl-1H-pyrrole

Cas:3042-22-6

Min.Order:0

Negotiable

Type:Other

inquiry

Synthetic route

(4-azidobut-1-yn-1-yl)benzene
199276-69-2

(4-azidobut-1-yn-1-yl)benzene

2-phenyl-1H-pyrrole
3042-22-6

2-phenyl-1H-pyrrole

Conditions
ConditionsYield
With trifluorormethanesulfonic acid; phenylmercuric acetate In nitromethane at 20℃; for 0.0833333h; Inert atmosphere;99%
With 2,6-di-tert-butyl-4-methylpyridine; platinum(IV) chloride In ethanol for 6h; Heating;74%
With silver hexafluoroantimonate; (bis(diphenylphosphino)methane)bis(chlorogold(I)) In dichloromethane at 35℃; Schmidt reaction;68%
4-oxo-4-phenyl-butyraldehyde
56139-59-4

4-oxo-4-phenyl-butyraldehyde

benzylamine
100-46-9

benzylamine

2-phenyl-1H-pyrrole
3042-22-6

2-phenyl-1H-pyrrole

Conditions
ConditionsYield
With acetic acid In methanol at 20℃; for 2h; Inert atmosphere; Molecular sieve;99%
3-iodo-2-phenylpyrrole

3-iodo-2-phenylpyrrole

2-phenyl-1H-pyrrole
3042-22-6

2-phenyl-1H-pyrrole

Conditions
ConditionsYield
With zinc In ethanol for 16h; Inert atmosphere; Reflux;99%
6-Phenoxy-3-phenyl-5,6-dihydro-4H-[1,2]oxazine
132868-20-3

6-Phenoxy-3-phenyl-5,6-dihydro-4H-[1,2]oxazine

2-phenyl-1H-pyrrole
3042-22-6

2-phenyl-1H-pyrrole

Conditions
ConditionsYield
With triiron dodecarbonyl In 1,2-dichloro-ethane at 80℃; for 20h;98%
O-Vinylacetophenonoxime
85868-20-8

O-Vinylacetophenonoxime

2-phenyl-1H-pyrrole
3042-22-6

2-phenyl-1H-pyrrole

Conditions
ConditionsYield
With potassium hydroxide; dimethyl sulfoxide at 95℃; for 1.33333h;96%
2-(2-phenyl-1H-pyrrol-1-yl)pyrimidine

2-(2-phenyl-1H-pyrrol-1-yl)pyrimidine

2-phenyl-1H-pyrrole
3042-22-6

2-phenyl-1H-pyrrole

Conditions
ConditionsYield
With sodium ethanolate In dimethyl sulfoxide at 100℃; for 24h;94%
iodobenzene
591-50-4

iodobenzene

2-(Methoxy-dimethyl-silanyl)-1-methyl-1H-pyrrole

2-(Methoxy-dimethyl-silanyl)-1-methyl-1H-pyrrole

2-phenyl-1H-pyrrole
3042-22-6

2-phenyl-1H-pyrrole

Conditions
ConditionsYield
With copper(l) iodide; sodium pentafluorophenolate In various solvent(s) at 130℃; for 12h;93%
((1E,3E)-4-azidobuta-1,3-dien-1-yl)benzene

((1E,3E)-4-azidobuta-1,3-dien-1-yl)benzene

2-phenyl-1H-pyrrole
3042-22-6

2-phenyl-1H-pyrrole

Conditions
ConditionsYield
With tris-(4,4’-di-tert-butyl-2,2’-bipyridine)ruthenium(II) hexafluorophosphate In chloroform at 20℃; for 3h; Concentration; Schlenk technique; Inert atmosphere; Irradiation;93%
6-butoxy-3-phenyl-1,2-oxazine
132868-21-4

6-butoxy-3-phenyl-1,2-oxazine

2-phenyl-1H-pyrrole
3042-22-6

2-phenyl-1H-pyrrole

Conditions
ConditionsYield
With triiron dodecarbonyl In 1,2-dichloro-ethane at 80℃; for 20h;91%
pyrrole
109-97-7

pyrrole

iodobenzene
591-50-4

iodobenzene

A

2-phenyl-1H-pyrrole
3042-22-6

2-phenyl-1H-pyrrole

B

3-phenyl-1H-pyrrole
27649-43-0

3-phenyl-1H-pyrrole

Conditions
ConditionsYield
Stage #1: pyrrole With sodium hydride In tetrahydrofuran
Stage #2: iodobenzene With zinc(II) chloride; johnphos; palladium diacetate In tetrahydrofuran at 100℃; for 21h;
A 91%
B n/a
With potassium tert-butylate In dimethyl sulfoxide at 80℃; for 22h; Sealed tube; Inert atmosphere; regioselective reaction;
2-phenyl-1-pyrroline
700-91-4

2-phenyl-1-pyrroline

A

2-phenyl-1H-pyrrole
3042-22-6

2-phenyl-1H-pyrrole

B

4-phenyl-1-butylamine
13214-66-9

4-phenyl-1-butylamine

Conditions
ConditionsYield
With [10%-Pd/Al2O3] In 5,5-dimethyl-1,3-cyclohexadiene at 150℃; for 1.5h; Kinetics; Reagent/catalyst; Time; Concentration; Inert atmosphere;A 90%
B n/a
With [10%-Pd/Al2O3] In 5,5-dimethyl-1,3-cyclohexadiene at 150℃; for 2h;A 79%
B n/a
acetophenone O-vinyloxime
161564-59-6

acetophenone O-vinyloxime

2-phenyl-1H-pyrrole
3042-22-6

2-phenyl-1H-pyrrole

Conditions
ConditionsYield
With potassium tert-butylate In tert-butyl alcohol for 5h; Heating;89%
pyrrole
109-97-7

pyrrole

iodobenzene
591-50-4

iodobenzene

2-phenyl-1H-pyrrole
3042-22-6

2-phenyl-1H-pyrrole

Conditions
ConditionsYield
With palladium diacetate; magnesium oxide; triphenylphosphine In 1,4-dioxane at 150℃;86%
With [Rh(coe)2Cl]2; tris(para-trifluoromethyl)phenyl phosphine In 1,4-dioxane at 120℃;78%
With C52H44CoN4O4; potassium hydroxide; tert-butyl alcohol at 200℃; for 0.5h; Inert atmosphere; Darkness; regioselective reaction;69%
iodobenzene
591-50-4

iodobenzene

N-boc-2-pyrroleboronic acid
135884-31-0

N-boc-2-pyrroleboronic acid

A

2-phenyl-1H-pyrrole
3042-22-6

2-phenyl-1H-pyrrole

B

tert-butyl 2-phenyl-1H-pyrrole-1-carboxylate
163525-97-1

tert-butyl 2-phenyl-1H-pyrrole-1-carboxylate

Conditions
ConditionsYield
With methanol; tetrakis(triphenylphosphine) palladium(0); caesium carbonate In toluene for 24h; Suzuki coupling; Reflux; Inert atmosphere;A 7%
B 86%
1-phenylbut-3-en-1-one acetyloxime
1616603-16-7

1-phenylbut-3-en-1-one acetyloxime

2-phenyl-1H-pyrrole
3042-22-6

2-phenyl-1H-pyrrole

Conditions
ConditionsYield
With copper(I) bromide In toluene at 120℃; Solvent; Reagent/catalyst; Inert atmosphere;86%
Dimethyl-(2-phenyl-pyrrol-1-yl)-amine
120256-08-8

Dimethyl-(2-phenyl-pyrrol-1-yl)-amine

2-phenyl-1H-pyrrole
3042-22-6

2-phenyl-1H-pyrrole

Conditions
ConditionsYield
With hydrogen; nickel In methanol; water under 3102.9 Torr; for 48h; Ambient temperature;85%
2-phenyl-1-vinyl-1H-pyrrole
58042-93-6

2-phenyl-1-vinyl-1H-pyrrole

butan-1-ol
71-36-3

butan-1-ol

A

2-phenyl-1H-pyrrole
3042-22-6

2-phenyl-1H-pyrrole

B

N-(α-butoxyethyl)-2-phenylpyrrole
76892-15-4

N-(α-butoxyethyl)-2-phenylpyrrole

Conditions
ConditionsYield
With ferric nitrate In water at 50℃; for 20h; Title compound not separated from byproducts;A 10%
B 85%
With ferric nitrate In water at 50℃; for 20h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
With ferric nitrate In water; butan-1-ol at 50℃; for 20h; Product distribution;A 10 % Chromat.
B 85 % Chromat.
ferric nitrate In water at 50℃; for 20h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
C13H15NO2
1616603-33-8

C13H15NO2

2-phenyl-1H-pyrrole
3042-22-6

2-phenyl-1H-pyrrole

Conditions
ConditionsYield
With copper(I) bromide In toluene at 120℃; Inert atmosphere;84%
C15H19NO2
1616603-34-9

C15H19NO2

2-phenyl-1H-pyrrole
3042-22-6

2-phenyl-1H-pyrrole

Conditions
ConditionsYield
With copper(I) bromide In toluene at 120℃; Inert atmosphere;82%
(2E,4Z)-6-Azido-3-phenyl-hexa-2,4-dienoic acid ethyl ester
80288-27-3

(2E,4Z)-6-Azido-3-phenyl-hexa-2,4-dienoic acid ethyl ester

A

2-phenyl-1H-pyrrole
3042-22-6

2-phenyl-1H-pyrrole

B

ethyl α-diazo-2-phenyl-2,5-dihydropyrrole-2-acetate
80288-31-9

ethyl α-diazo-2-phenyl-2,5-dihydropyrrole-2-acetate

Conditions
ConditionsYield
With acetic acid In diethyl ether for 36h; Ambient temperature;A 80%
B n/a
In benzene at 55℃; for 1.5h;A n/a
B 25%
trans-2-(tributylstannyl)-N,N-dibenzylcyclopropylamine

trans-2-(tributylstannyl)-N,N-dibenzylcyclopropylamine

benzonitrile
100-47-0

benzonitrile

2-phenyl-1H-pyrrole
3042-22-6

2-phenyl-1H-pyrrole

Conditions
ConditionsYield
Stage #1: trans-2-(tributylstannyl)-N,N-dibenzylcyclopropylamine; benzonitrile With n-butyllithium In tetrahydrofuran; hexane at -30 - 0℃; for 2.5h;
Stage #2: With acetic acid In tetrahydrofuran; hexane
80%
1-phenylbut-3-en-1-one O-benzoyl oxime
1616603-35-0

1-phenylbut-3-en-1-one O-benzoyl oxime

2-phenyl-1H-pyrrole
3042-22-6

2-phenyl-1H-pyrrole

Conditions
ConditionsYield
With copper(I) bromide In toluene at 120℃; Inert atmosphere;80%
acetophenone oxime
613-91-2

acetophenone oxime

acetylene
74-86-2

acetylene

2-phenyl-1H-pyrrole
3042-22-6

2-phenyl-1H-pyrrole

Conditions
ConditionsYield
With potassium hydroxide In dimethyl sulfoxide at 150℃; for 6h;79%
With potassium hydroxide In dimethyl sulfoxide at 150℃; for 4h;44%
Trofimov reaction;
In dimethyl sulfoxide Alkaline conditions;
pyrrole
109-97-7

pyrrole

Diphenyliodonium triflate
66003-76-7

Diphenyliodonium triflate

2-phenyl-1H-pyrrole
3042-22-6

2-phenyl-1H-pyrrole

Conditions
ConditionsYield
With sodium hydroxide at 80℃; for 10h; under air;78%
Inert atmosphere; Schlenk technique;74%
With sodium hydroxide at 80℃; for 10h; Inert atmosphere; Schlenk technique;70%
With sodium hydroxide at 80℃; Schlenk technique; Inert atmosphere;69%
With palladium diacetate; acetic acid at 20℃; for 15h;
pyrrole
109-97-7

pyrrole

diphenyliodonium tetrafluoroborate

diphenyliodonium tetrafluoroborate

A

2-phenyl-1H-pyrrole
3042-22-6

2-phenyl-1H-pyrrole

B

iodobenzene
591-50-4

iodobenzene

Conditions
ConditionsYield
With sodium hydroxide at 80℃; for 10h; under air; regioselective reaction;A 78%
B n/a
pyrrole
109-97-7

pyrrole

Diphenyliodonium triflate
66003-76-7

Diphenyliodonium triflate

A

2-phenyl-1H-pyrrole
3042-22-6

2-phenyl-1H-pyrrole

B

iodobenzene
591-50-4

iodobenzene

Conditions
ConditionsYield
With sodium hydroxide at 80℃; for 10h; under air; regioselective reaction;A 78%
B n/a
pyrrole
109-97-7

pyrrole

diphenyliodonium bromide
1483-73-4

diphenyliodonium bromide

A

2-phenyl-1H-pyrrole
3042-22-6

2-phenyl-1H-pyrrole

B

iodobenzene
591-50-4

iodobenzene

Conditions
ConditionsYield
With sodium hydroxide at 80℃; for 10h; under air; regioselective reaction;A 77%
B n/a
2-bromo-pyrrole-1-carboxylic acid tert-butyl ester
117657-37-1

2-bromo-pyrrole-1-carboxylic acid tert-butyl ester

phenylboronic acid
98-80-6

phenylboronic acid

2-phenyl-1H-pyrrole
3042-22-6

2-phenyl-1H-pyrrole

Conditions
ConditionsYield
Stage #1: 2-bromo-pyrrole-1-carboxylic acid tert-butyl ester; phenylboronic acid With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium carbonate In ethanol; water; toluene at 110℃; for 12h; Sealed tube; Inert atmosphere;
Stage #2: With potassium carbonate In methanol for 12h; Inert atmosphere; Reflux;
77%
2-phenyl-1H-pyrrole-4-carboxylic acid
161958-62-9

2-phenyl-1H-pyrrole-4-carboxylic acid

2-phenyl-1H-pyrrole
3042-22-6

2-phenyl-1H-pyrrole

Conditions
ConditionsYield
With ethanolamine for 2h; Heating;75%
N-(4-chlorophenyl)-2-phenyl-5-(2-phenyl-1H-pyrrol-1-yl)isoxazolidine-3-carboxamide

N-(4-chlorophenyl)-2-phenyl-5-(2-phenyl-1H-pyrrol-1-yl)isoxazolidine-3-carboxamide

A

2-phenyl-1H-pyrrole
3042-22-6

2-phenyl-1H-pyrrole

B

1-(4-chlorophenyl)-5-hydroxy-3-(phenylamino)-1,5-dihydro-2H-pyrrol-2-one

1-(4-chlorophenyl)-5-hydroxy-3-(phenylamino)-1,5-dihydro-2H-pyrrol-2-one

Conditions
ConditionsYield
With tetrabutyl ammonium fluoride In tetrahydrofuran at 20℃; for 4h; Inert atmosphere;A n/a
B 75%
2-phenyl-1H-pyrrole
3042-22-6

2-phenyl-1H-pyrrole

2,3-dihydro-3-methylene-4H-benzopyran-4-one
78115-49-8

2,3-dihydro-3-methylene-4H-benzopyran-4-one

C20H17NO2

C20H17NO2

Conditions
ConditionsYield
With C45H55O4P In dichloromethane at -65℃; for 12h; Inert atmosphere; enantioselective reaction;99%
2-phenyl-1H-pyrrole
3042-22-6

2-phenyl-1H-pyrrole

1-p-hydroxyphenyl-1-phenyl-1-ethanol
126597-34-0

1-p-hydroxyphenyl-1-phenyl-1-ethanol

(S)-4-(1-phenyl-1-(5-phenyl-1H-pyrrol-2-yl)ethyl)phenol

(S)-4-(1-phenyl-1-(5-phenyl-1H-pyrrol-2-yl)ethyl)phenol

Conditions
ConditionsYield
With (11aS)-3,7-di-9-anthracenyl-10,11,12,13-tetrahydro-5-hydroxy-5-oxide diindeno[7,1de:10,70-fg][1,3,2] dioxaphosphocin In chloroform at 0 - 20℃; for 48h; Molecular sieve; enantioselective reaction;97%
2-phenyl-1H-pyrrole
3042-22-6

2-phenyl-1H-pyrrole

2,6-dimethyl-4-(2,2,2-trifluoro-1-phenylethylidene)cyclohexa-2,5-dienone

2,6-dimethyl-4-(2,2,2-trifluoro-1-phenylethylidene)cyclohexa-2,5-dienone

2,6-dimethyl-4-(2,2,2-trifluoro-1-phenyl-1-(5-phenyl-1H-pyrrol-2-yl)ethyl)phenol

2,6-dimethyl-4-(2,2,2-trifluoro-1-phenyl-1-(5-phenyl-1H-pyrrol-2-yl)ethyl)phenol

Conditions
ConditionsYield
With bismuth(lll) trifluoromethanesulfonate In dichloromethane at 20℃; for 0.0333333h;97%
2-phenyl-1H-pyrrole
3042-22-6

2-phenyl-1H-pyrrole

acetylene
74-86-2

acetylene

2-phenyl-1-vinyl-1H-pyrrole
58042-93-6

2-phenyl-1-vinyl-1H-pyrrole

Conditions
ConditionsYield
With potassium hydroxide In dimethyl sulfoxide at 110℃; under 735.5 Torr; for 4.5h; Product distribution; different temperature and time;96%
With potassium hydroxide In dimethyl sulfoxide at 120℃; under 735.5 Torr; for 6h;96%
With potassium hydroxide In dimethyl sulfoxide at 100℃; Product distribution; various 2-, 2,3-, and 2,5-substituted pyrroles; various times;
With potassium hydroxide; benzophenone In dimethyl sulfoxide at 100℃; Product distribution; Mechanism; other pyrrole; other reagents;
With potassium hydroxide; t-butylnitrite at 20℃; Mechanism; other 2-arylpyrroles; other acetylenes;
2-phenyl-1H-pyrrole
3042-22-6

2-phenyl-1H-pyrrole

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

5-phenyl-1H-pyrrole-2-carbaldehyde
52179-74-5

5-phenyl-1H-pyrrole-2-carbaldehyde

Conditions
ConditionsYield
Stage #1: 2-phenyl-1H-pyrrole; N,N-dimethyl-formamide With trichlorophosphate In toluene at 20℃; Vilsmeier-Haack Formylation; Cooling with ice; Inert atmosphere;
Stage #2: With water; sodium hydrogencarbonate; sodium hydroxide In toluene at 0℃; for 3h; pH=7 - 12; Vilsmeier-Haack Formylation; Inert atmosphere;
96%
Stage #1: 2-phenyl-1H-pyrrole; N,N-dimethyl-formamide With trichlorophosphate at 0 - 40℃; for 1.16667h; Inert atmosphere;
Stage #2: With water; sodium hydroxide for 0.5h; Reflux;
Stage #1: N,N-dimethyl-formamide With trichlorophosphate In dichloromethane for 0.0833333h; Vilsmeier-Haack Formylation; Inert atmosphere;
Stage #2: 2-phenyl-1H-pyrrole In dichloromethane Vilsmeier-Haack Formylation; Inert atmosphere;
Stage #3: With sodium hydroxide In tetrahydrofuran at 23℃; Vilsmeier-Haack Formylation; Inert atmosphere; regioselective reaction;
139 mg
2-phenyl-1H-pyrrole
3042-22-6

2-phenyl-1H-pyrrole

1-(5-[1,1-biphenyl]-4-yl-1H-pyrrol-2-yl)-2,2,2-trifluoro-1-ethanol
1447004-26-3

1-(5-[1,1-biphenyl]-4-yl-1H-pyrrol-2-yl)-2,2,2-trifluoro-1-ethanol

2-[1,1-biphenyl]-4-yl-5-[2,2,2-trifluoro-1-(5-phenyl-1H-pyrrol-2-yl)-ethyl]-1H-pyrrole
1447031-59-5

2-[1,1-biphenyl]-4-yl-5-[2,2,2-trifluoro-1-(5-phenyl-1H-pyrrol-2-yl)-ethyl]-1H-pyrrole

Conditions
ConditionsYield
With phosphorus pentoxide In dichloromethane at 20℃; for 16h; Inert atmosphere;96%
2-phenyl-1H-pyrrole
3042-22-6

2-phenyl-1H-pyrrole

perfluorobenzaldehyde
653-37-2

perfluorobenzaldehyde

5-pentafluorophenyl-1,9-diphenyldipyrrin

5-pentafluorophenyl-1,9-diphenyldipyrrin

Conditions
ConditionsYield
Stage #1: 2-phenyl-1H-pyrrole; perfluorobenzaldehyde With trifluoroacetic acid In dichloromethane at 20℃; for 3h;
Stage #2: With 2,3-dicyano-5,6-dichloro-p-benzoquinone In dichloromethane at 20℃; for 0.5h; Inert atmosphere;
95%
methyl-3-pyridylketone
350-03-8

methyl-3-pyridylketone

2-phenyl-1H-pyrrole
3042-22-6

2-phenyl-1H-pyrrole

diethyl 2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate
1149-23-1

diethyl 2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate

C17H18N2O
1604834-30-1

C17H18N2O

Conditions
ConditionsYield
With (11aR)-10,11,12,13-tetrahydro-5-hydroxy-3,7-bis[2,4,6-triisopropylphenyl]-5-oxide-diindeno[7,1-de:1',7’-fg][1,3,2]dioxaphosphocin In dichloromethane at 20℃; for 72h; Inert atmosphere; Schlenk technique; Molecular sieve; enantioselective reaction;94%
2-phenyl-1H-pyrrole
3042-22-6

2-phenyl-1H-pyrrole

C11H14F3NO

C11H14F3NO

C21H21F3N2

C21H21F3N2

Conditions
ConditionsYield
With phosphorus pentoxide In dichloromethane at 20℃; for 16h;94%
2-phenyl-1H-pyrrole
3042-22-6

2-phenyl-1H-pyrrole

(S)-4-(2-chlorophenyl)-4-(5-phenyl-1H-pyrrol-2-yl)butan-2-one

(S)-4-(2-chlorophenyl)-4-(5-phenyl-1H-pyrrol-2-yl)butan-2-one

Conditions
ConditionsYield
With 9-amino-9-deoxy-epi-cinchonidine; trifluoroacetic acid In chlorobenzene at 20℃; for 24h; Michael Addition; enantioselective reaction;93%
2-phenyl-1H-pyrrole
3042-22-6

2-phenyl-1H-pyrrole

(4-bromophenyl)(pyridin-3-yl)methanone
14548-45-9

(4-bromophenyl)(pyridin-3-yl)methanone

diethyl 2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate
1149-23-1

diethyl 2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate

C22H19BrN2O
1604834-22-1

C22H19BrN2O

Conditions
ConditionsYield
With (11aR)-10,11,12,13-tetrahydro-5-hydroxy-3,7-bis[2,4,6-triisopropylphenyl]-5-oxide-diindeno[7,1-de:1',7’-fg][1,3,2]dioxaphosphocin In dichloromethane at 20℃; for 60h; Inert atmosphere; Schlenk technique; Molecular sieve; enantioselective reaction;93%
2-phenyl-1H-pyrrole
3042-22-6

2-phenyl-1H-pyrrole

3-(trifluoromethyl)-2H-benzo[b][1,4]oxazin-2-one
64995-46-6

3-(trifluoromethyl)-2H-benzo[b][1,4]oxazin-2-one

C19H13F3N2O2

C19H13F3N2O2

Conditions
ConditionsYield
With (11aR)-10,11,12,13-tetrahydro-5-hydroxy-3,7-bis[2,4,6-triisopropylphenyl]-5-oxide-diindeno[7,1-de:1',7’-fg][1,3,2]dioxaphosphocin In toluene at 20℃; for 12h; Friedel-Crafts Alkylation; enantioselective reaction;93%
2-phenyl-1H-pyrrole
3042-22-6

2-phenyl-1H-pyrrole

acridine hydrochloride
17784-47-3

acridine hydrochloride

9-(5-phenyl-1H-pyrrol-2-yl)acridinium chloride

9-(5-phenyl-1H-pyrrol-2-yl)acridinium chloride

Conditions
ConditionsYield
With CdS/TiO2; oxygen In butan-1-ol at 20℃; for 5h; Irradiation;92%
2-phenyl-1H-pyrrole
3042-22-6

2-phenyl-1H-pyrrole

C10H6F3NO2

C10H6F3NO2

(R)-7-methyl-3-(5-phenyl-1H-pyrrol-2-yl)-3-(trifluoromethyl)-3,4-dihydro-2H-benzo[b][1,4]oxazin-2-one

(R)-7-methyl-3-(5-phenyl-1H-pyrrol-2-yl)-3-(trifluoromethyl)-3,4-dihydro-2H-benzo[b][1,4]oxazin-2-one

Conditions
ConditionsYield
With (R)-6,6'-bis(2,4,6-triisopropylphenyl)-1,1'-spirobiindanyl-7,7'-diyl hydrogen phosphate In toluene at 20℃; for 18h; Friedel-Crafts Alkylation; Inert atmosphere; enantioselective reaction;91%
2-phenyl-1H-pyrrole
3042-22-6

2-phenyl-1H-pyrrole

(2-nitroethenyl)benzene
102-96-5

(2-nitroethenyl)benzene

3-(2-nitro-1-phenylethyl)-2-phenyl-1H-pyrrole

3-(2-nitro-1-phenylethyl)-2-phenyl-1H-pyrrole

Conditions
ConditionsYield
With 2,2,2-trifluoroacetic acid ammonia In ethanol; water at 115℃;91%
2-phenyl-1H-pyrrole
3042-22-6

2-phenyl-1H-pyrrole

6-fluoro-3-trifluoromethyl-benzoxazinone

6-fluoro-3-trifluoromethyl-benzoxazinone

(R)-6-fluoro-3-(5-phenyl-1H-pyrrol-2-yl)-3-(trifluoromethyl)-3,4-dihydro-2H-benzo[b][1,4]oxazin-2-one

(R)-6-fluoro-3-(5-phenyl-1H-pyrrol-2-yl)-3-(trifluoromethyl)-3,4-dihydro-2H-benzo[b][1,4]oxazin-2-one

Conditions
ConditionsYield
With (R)-6,6'-bis(2,4,6-triisopropylphenyl)-1,1'-spirobiindanyl-7,7'-diyl hydrogen phosphate In toluene at 20℃; for 18h; Friedel-Crafts Alkylation; Inert atmosphere; enantioselective reaction;90%
2-phenyl-1H-pyrrole
3042-22-6

2-phenyl-1H-pyrrole

6-chloro-3-trifluoromethyl-benzoxazinone
64995-54-6

6-chloro-3-trifluoromethyl-benzoxazinone

(R)-6-chloro-3-(5-phenyl-1H-pyrrol-2-yl)-3-(trifluoromethyl)-3,4-dihydro-2H-benzo[b][1,4]oxazin-2-one

(R)-6-chloro-3-(5-phenyl-1H-pyrrol-2-yl)-3-(trifluoromethyl)-3,4-dihydro-2H-benzo[b][1,4]oxazin-2-one

Conditions
ConditionsYield
With (S)-3,3'-bis(2,4,6-tri-iso-propylphenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate In toluene at 20℃; for 18h; Friedel-Crafts Alkylation; Inert atmosphere; enantioselective reaction;90%
2-phenyl-1H-pyrrole
3042-22-6

2-phenyl-1H-pyrrole

(E)-2-((6-chlorohex-2-en-1-yl)oxy)tetrahydro-2H-pyran

(E)-2-((6-chlorohex-2-en-1-yl)oxy)tetrahydro-2H-pyran

(E)-2-phenyl-1-(6-((tetrahydro-2H-pyran-2-yl)oxy)hex-4-en-1-yl)-1H-pyrrole

(E)-2-phenyl-1-(6-((tetrahydro-2H-pyran-2-yl)oxy)hex-4-en-1-yl)-1H-pyrrole

Conditions
ConditionsYield
Stage #1: 2-phenyl-1H-pyrrole With sodium hydride In N,N-dimethyl-formamide; paraffin oil at 25 - 28℃; for 0.5h;
Stage #2: (E)-2-((6-chlorohex-2-en-1-yl)oxy)tetrahydro-2H-pyran In N,N-dimethyl-formamide; paraffin oil at 0 - 28℃; for 24h;
90%
2-phenyl-1H-pyrrole
3042-22-6

2-phenyl-1H-pyrrole

2-(4-oxocyclohexa-2,5-dien-1-ylidene)-2-phenylacetonitrile

2-(4-oxocyclohexa-2,5-dien-1-ylidene)-2-phenylacetonitrile

2-(4-hydroxyphenyl)-2-phenyl-2-(5-phenyl-1H-pyrrol-2-yl)acetonitrile

2-(4-hydroxyphenyl)-2-phenyl-2-(5-phenyl-1H-pyrrol-2-yl)acetonitrile

Conditions
ConditionsYield
With bismuth(lll) trifluoromethanesulfonate In dichloromethane at 20℃; for 12h;90%

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