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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

delta-2-carene

Cas:4497-92-1

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply (1S-cis)-3,7,7-trimethylbicyclo[4.1.0]hept-2-ene

Cas:4497-92-1

Min.Order:1

Negotiable

Type:Other

inquiry

Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

High Content Natural Extract 2-Carene 95+% HACCP manufacturer

Cas:4497-92-1

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

(+)-2-CARENE

Cas:4497-92-1

Min.Order:1 Kilogram

FOB Price: $9.0 / 99.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Professional Manufacturer CAS 4497-92-1 with high quality products

Cas:4497-92-1

Min.Order:10 Gram

FOB Price: $146.0 / 176.0

Type:Trading Company

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Bicyclo[4.1.0]hept-2-ene,3,7,7-trimethyl-, (1S,6R)- 4497-92-1

Cas:4497-92-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

(+)-2-CARENE CAS:4497-92-1 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermediates

(+)-2-CARENE CAS:4497-92-1

Cas:4497-92-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Bicyclo[4.1.0]hept-2-ene,3,7,7-trimethyl-, (1S,6R)-

Cas:4497-92-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Bicyclo[4.1.0]hept-2-ene,3,7,7-trimethyl-, (1S,6R)-

Cas:4497-92-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

(+)-2-Carene

Cas:4497-92-1

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

(+)-2-Carene

Cas:4497-92-1

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

(+)-2-Carene

Cas:4497-92-1

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

(+)-2-Carene

Cas:4497-92-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

(+)-2-Carene

Cas:4497-92-1

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

(+)-2-Carene

Cas:4497-92-1

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, higher purity,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthesis of various pesticides, medicines, s

(+)-2-Carene

Cas:4497-92-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Dingyan Chem Co., Ltd

R & D enterprises have their own stock in stock Package:1kg Application:pharmaceutical intermediates

Bicyclo[4.1.0]hept-2-ene,3,7,7-trimethyl-, (1S,6R)-

Cas:4497-92-1

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

(+)-2-Carene

Cas:4497-92-1

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM is one of China's leading providers of integrated fine chemical services including offering, research and development, Custom manufacturing business, as well as other Value-added customer services, for diversified range products of chemicals

(+)-2-CARENE

Cas:4497-92-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Henan Tianfu Chemical Co., Ltd.

1.Our services:A.Supply sampleB.The packing also can be according the customers` requirmentC.Any inquiries will be replied within 24 hoursD.we provide Commerical Invoice, Packing List, Bill of loading, COA , Health certificate and Origin certificate.

Bicyclo[4.1.0]hept-2-ene,3,7,7-trimethyl-, (1S,6R)-

Cas:4497-92-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xian Changyue Biological Technology Co., Ltd.

best seller Application:API

(+)-2-CARENE

Cas:4497-92-1

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Bicyclo[4.1.0]hept-2-ene,3,7,7-trimethyl-, (1S,6R)-

Cas:4497-92-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hubei Langyou International Trading Co., Ltd

(+)-2-Carene Application:(+)-2-Carene

(+)-2-Carene

Cas:4497-92-1

Min.Order:0

Negotiable

Type:Other

inquiry

DB BIOTECH CO., LTD

best seller Application:API

(+)-2-CARENE

Cas:4497-92-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

(+)-2-CARENE

Cas:4497-92-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers2. Produce products of different specifications and sizes according to your requirements.3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures sta

(+)-2-CARENE

Cas:4497-92-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou ZeErRui Chemical Co., Ltd.

Hangzhou ZeErRui Chemical Co., Ltd. is focused on customization, research and development and production of APIs and advanced intermediates, which can effectively compensate for the deficiencies of traditional CRO and CMO. Priority of high-tech barri

(+)-2-Carene

Cas:4497-92-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Newgreat Chemical Co., Ltd

Wuhan Xinweiye Chemical Co., Ltd. is mainly engaged in the process development and production of customized synthesis and pharmaceutical intermediates. We have professional researchers in organic synthesis, analytical chemistry and production process

(+)-2-Carene

Cas:4497-92-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Bright Chemical Co., Ltd.

best seller Application:API

(+)-2-CARENE

Cas:4497-92-1

Min.Order:0

Negotiable

Type:Other

inquiry

Hunan Longxianng Runhui Trading Co.,Ltd

(+)-2-CareneAppearance:white crystalline powder Storage:Shading, sealed, dry place. Package:aluminous bag Application:API Transportation:By express (Door to door) such as FEDEX, DHL, EMS for small amount. By air(airport to airport) or by sea LCL/FCL

(+)-2-Carene

Cas:4497-92-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

C30H45BO

C30H45BO

A

(R)-1-Phenylbut-3-en-1-ol
85551-57-1

(R)-1-Phenylbut-3-en-1-ol

B

2-carene
4497-92-1

2-carene

Conditions
ConditionsYield
With boron trifluoride diethyl etherate; isobutyraldehyde at 65℃; for 48h;A 76%
B 83%
(+)-Δ3-carene
498-15-7

(+)-Δ3-carene

2-carene
4497-92-1

2-carene

Conditions
ConditionsYield
With potassium tert-butylate In dimethyl sulfoxide at 100℃; for 4h;15%
With titanic acid at 140℃;
With sulfuric acid at 110℃;
((1S,6R)-7,7-Dimethyl-bicyclo[4.1.0]hept-2-en-3-yl)-methanol
6909-19-9

((1S,6R)-7,7-Dimethyl-bicyclo[4.1.0]hept-2-en-3-yl)-methanol

2-carene
4497-92-1

2-carene

Conditions
ConditionsYield
(i) Py*SO3, THF, (ii) LiAlH4; Multistep reaction;
(-)-trans-Caran-2-on-tosylhydrazon
15372-79-9, 15372-81-3, 18767-55-0

(-)-trans-Caran-2-on-tosylhydrazon

2-carene
4497-92-1

2-carene

Conditions
ConditionsYield
With methyllithium In diethyl ether
(+)(1R:4R:6S)-Caran-trans-4-ol-benzoat

(+)(1R:4R:6S)-Caran-trans-4-ol-benzoat

A

(+)-Δ3-carene
498-15-7

(+)-Δ3-carene

B

2-carene
4497-92-1

2-carene

Conditions
ConditionsYield
at 320℃;
(+)(1R:4R:6S)-Caran-trans-4-ol-acetat

(+)(1R:4R:6S)-Caran-trans-4-ol-acetat

2-carene
4497-92-1

2-carene

Conditions
ConditionsYield
at 180℃;
(+)-Δ3-carene
498-15-7

(+)-Δ3-carene

A

4-methylisopropylbenzene
99-87-6

4-methylisopropylbenzene

B

2-carene
4497-92-1

2-carene

C

(-)-(1S)-3,8,8-trimethylbicyclo<4.1.1.>oct-3-ene-7-one
97763-43-4

(-)-(1S)-3,8,8-trimethylbicyclo<4.1.1.>oct-3-ene-7-one

Conditions
ConditionsYield
With iron pentacarbonyl In dibutyl ether for 72h; Heating; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
With iron pentacarbonyl In dibutyl ether for 72h; Heating; Yield given. Yields of byproduct given;
α-terpinylphenylsulphide
82470-87-9

α-terpinylphenylsulphide

A

p-menth-1-ene
61585-35-1

p-menth-1-ene

B

(+)-Δ3-carene
498-15-7

(+)-Δ3-carene

C

4-methylisopropylbenzene
99-87-6

4-methylisopropylbenzene

D

2-carene
4497-92-1

2-carene

Conditions
ConditionsYield
With lithium diethylamide In N,N,N,N,N,N-hexamethylphosphoric triamide; diethyl ether at 20℃; for 3h; Product distribution; Various reagents/solvents was used for the cyclisation (n-BuLi/TMEDA, K-t-butoxide/DMSO).;
(+)-Δ3-carene
498-15-7

(+)-Δ3-carene

A

4-methylisopropylbenzene
99-87-6

4-methylisopropylbenzene

B

2-carene
4497-92-1

2-carene

C

(-)-(1S)-3,8,8-trimethylbicyclo<4.1.1.>oct-3-ene-7-one
97763-43-4

(-)-(1S)-3,8,8-trimethylbicyclo<4.1.1.>oct-3-ene-7-one

D

iron-carbonyl-complexes

iron-carbonyl-complexes

Conditions
ConditionsYield
With iron pentacarbonyl 1) 150 deg C, 18 h, 2) 160 deg C, 24 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
3,7,7-trimethylbicyclo[4.1.0]heptan-3-ol
4017-79-2

3,7,7-trimethylbicyclo[4.1.0]heptan-3-ol

2-carene
4497-92-1

2-carene

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: PhNMe2 / acetic anhydride
2: 180 °C
View Scheme
(1S,6R)-2-Hydroxy-7,7-dimethyl-bicyclo[4.1.0]heptane-3-carboxylic acid methyl ester
58400-80-9

(1S,6R)-2-Hydroxy-7,7-dimethyl-bicyclo[4.1.0]heptane-3-carboxylic acid methyl ester

2-carene
4497-92-1

2-carene

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: Py
2: KOtBu / benzene
3: LiAlH4 / diethyl ether
4: (i) Py*SO3, THF, (ii) LiAlH4
View Scheme
(1S,6R)-7,7-Dimethyl-bicyclo[4.1.0]hept-2-ene-3-carboxylic acid methyl ester
58400-82-1

(1S,6R)-7,7-Dimethyl-bicyclo[4.1.0]hept-2-ene-3-carboxylic acid methyl ester

2-carene
4497-92-1

2-carene

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: LiAlH4 / diethyl ether
2: (i) Py*SO3, THF, (ii) LiAlH4
View Scheme
(1S,6R)-2-Benzoyloxy-7,7-dimethyl-bicyclo[4.1.0]heptane-3-carboxylic acid methyl ester
58400-81-0

(1S,6R)-2-Benzoyloxy-7,7-dimethyl-bicyclo[4.1.0]heptane-3-carboxylic acid methyl ester

2-carene
4497-92-1

2-carene

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: KOtBu / benzene
2: LiAlH4 / diethyl ether
3: (i) Py*SO3, THF, (ii) LiAlH4
View Scheme
(1S,3S,6R)-(-)-4-Caren-3α-ol
4017-81-6

(1S,3S,6R)-(-)-4-Caren-3α-ol

2-carene
4497-92-1

2-carene

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: (hydrogenation)
2: PhNMe2 / acetic anhydride
3: 180 °C
View Scheme
(1S,6R)-7,7-Dimethyl-2-oxo-bicyclo[4.1.0]heptane-3-carboxylic acid methyl ester

(1S,6R)-7,7-Dimethyl-2-oxo-bicyclo[4.1.0]heptane-3-carboxylic acid methyl ester

2-carene
4497-92-1

2-carene

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1: NaBH4 / ethanol
2: Py
3: KOtBu / benzene
4: LiAlH4 / diethyl ether
5: (i) Py*SO3, THF, (ii) LiAlH4
View Scheme
(1S,2S,6R)-(-)-7,7-Dimethylbicyclo<4.1.0>heptan-2-ol
58437-50-6

(1S,2S,6R)-(-)-7,7-Dimethylbicyclo<4.1.0>heptan-2-ol

2-carene
4497-92-1

2-carene

Conditions
ConditionsYield
Multi-step reaction with 6 steps
1: NaH / benzene
2: NaBH4 / ethanol
3: Py
4: KOtBu / benzene
5: LiAlH4 / diethyl ether
6: (i) Py*SO3, THF, (ii) LiAlH4
View Scheme
(2aR,2bR,5aS,5bS)-2a-Methyl-hexahydro-1-oxa-cyclopropa[cd]inden-2-one

(2aR,2bR,5aS,5bS)-2a-Methyl-hexahydro-1-oxa-cyclopropa[cd]inden-2-one

2-carene
4497-92-1

2-carene

Conditions
ConditionsYield
Multi-step reaction with 8 steps
1: (i) iBu2AlH, toluene, hexane, (ii) /BRN= 610130/, AcOH, EtOH
2: LiAlH4 / tetrahydrofuran
3: NaH / benzene
4: NaBH4 / ethanol
5: Py
6: KOtBu / benzene
7: LiAlH4 / diethyl ether
8: (i) Py*SO3, THF, (ii) LiAlH4
View Scheme
C16H22N2O3S

C16H22N2O3S

2-carene
4497-92-1

2-carene

Conditions
ConditionsYield
Multi-step reaction with 7 steps
1: LiAlH4 / tetrahydrofuran
2: NaH / benzene
3: NaBH4 / ethanol
4: Py
5: KOtBu / benzene
6: LiAlH4 / diethyl ether
7: (i) Py*SO3, THF, (ii) LiAlH4
View Scheme
2-carene
4497-92-1

2-carene

(1S,2S,3R,6R)-(+)-trans-car-2-ene epoxide
20053-58-1

(1S,2S,3R,6R)-(+)-trans-car-2-ene epoxide

Conditions
ConditionsYield
With 3,3-dimethyldioxirane In dichloromethane; acetone at -5℃; for 1h;100%
With sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid In dichloromethane at 20℃; Product distribution / selectivity;95%
With sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid In dichloromethane; water at 17 - 24℃; for 2h; Product distribution / selectivity;90%
2-carene
4497-92-1

2-carene

(1S)-di-2-isocaranylborane
114533-27-6

(1S)-di-2-isocaranylborane

Conditions
ConditionsYield
With borane N-ethyl-N-isopropylaniline complex In 1,4-dioxane at 0 - 20℃; hydroboration;99%
2-carene
4497-92-1

2-carene

(1S,2S,3R,6R)-3,7,7-trimethylbicyclo[4.1.0]heptane-2,3-diol

(1S,2S,3R,6R)-3,7,7-trimethylbicyclo[4.1.0]heptane-2,3-diol

Conditions
ConditionsYield
With potassium permanganate; sodium hydroxide In water; tert-butyl alcohol at 0℃; for 0.75h; Inert atmosphere;98%
With osmium(VIII) oxide; 4-methylmorpholine N-oxide In tert-butyl alcohol Reflux;86%
2-carene
4497-92-1

2-carene

Trichloroacetyl chloride
76-02-8

Trichloroacetyl chloride

(2R,4R,7R)-8,8-Dichloro-3,3,7-trimethyl-tricyclo[5.2.0.02,4]nonan-9-one

(2R,4R,7R)-8,8-Dichloro-3,3,7-trimethyl-tricyclo[5.2.0.02,4]nonan-9-one

Conditions
ConditionsYield
With zinc In diethyl ether ultrasonication;95%
2-carene
4497-92-1

2-carene

1,3-dithiol-2,4,5-trithione
85931-57-3

1,3-dithiol-2,4,5-trithione

(4aR,7R,8S,8aS)-4a,5,6,7,8,8a-hexahydro-7,8-isopropano-4a-methyl-1,3-dithiolo[4,5-b][1,4]benzodithiin-2-thione
859911-72-1

(4aR,7R,8S,8aS)-4a,5,6,7,8,8a-hexahydro-7,8-isopropano-4a-methyl-1,3-dithiolo[4,5-b][1,4]benzodithiin-2-thione

Conditions
ConditionsYield
In toluene for 24h; Heating;90%
P-toluenesulfonyl cyanide
19158-51-1

P-toluenesulfonyl cyanide

2-carene
4497-92-1

2-carene

2-methyl-2-(4-methylcyclohex-2-enyl)propionitrile

2-methyl-2-(4-methylcyclohex-2-enyl)propionitrile

Conditions
ConditionsYield
Stage #1: 2-carene With N,N-dimethyl acetamide; benzo[1,3,2]dioxaborole In dichloromethane for 5h; Heating;
Stage #2: P-toluenesulfonyl cyanide With di-tert-butoxydiazene In dichloromethane at 40℃;
90%
chloroamine-T
127-65-1

chloroamine-T

2-carene
4497-92-1

2-carene

cyclopropropanecarbonitrile
5500-21-0

cyclopropropanecarbonitrile

C21H28N2O2S
1415046-69-3

C21H28N2O2S

Conditions
ConditionsYield
With phenyltrimethylammonium tribromide at 25℃;87%
N-chloro-N-sodio-tert-butylcarbamate
73210-14-7

N-chloro-N-sodio-tert-butylcarbamate

2-carene
4497-92-1

2-carene

acetonitrile
75-05-8

acetonitrile

C17H28N2O2
1415046-91-1

C17H28N2O2

Conditions
ConditionsYield
With phenyltrimethylammonium tribromide at 25℃; for 8h;86%
N-sulfinylbenzenesulfonamide
6536-23-8

N-sulfinylbenzenesulfonamide

2-carene
4497-92-1

2-carene

Conditions
ConditionsYield
In diethyl ether at 0℃; for 1h;85%
In diethyl ether at 0 - 20℃;
N-chloro-N-sodio-tert-butylcarbamate
73210-14-7

N-chloro-N-sodio-tert-butylcarbamate

2-carene
4497-92-1

2-carene

propiononitrile
107-12-0

propiononitrile

C18H30N2O2
1415046-92-2

C18H30N2O2

Conditions
ConditionsYield
With phenyltrimethylammonium tribromide at 25℃; for 8h;85%
osmium(VIII) oxide
20816-12-0

osmium(VIII) oxide

N,N,N,N,-tetramethylethylenediamine
110-18-9

N,N,N,N,-tetramethylethylenediamine

2-carene
4497-92-1

2-carene

C16H32N2O4Os

C16H32N2O4Os

Conditions
ConditionsYield
In dichloromethane at -78℃; Inert atmosphere;85%
N-sulfinylbenzenesulfonamide
6536-23-8

N-sulfinylbenzenesulfonamide

2-carene
4497-92-1

2-carene

Conditions
ConditionsYield
In diethyl ether at 0℃; for 0.5h; Yields of byproduct given;A 84%
B n/a
In diethyl ether at 0℃; for 0.5h; Yield given;A 84%
B n/a
chloroamine-T
127-65-1

chloroamine-T

2-carene
4497-92-1

2-carene

acetonitrile
75-05-8

acetonitrile

1,4,4a,5,6,8a-hexahydro-2,4,4,7-tetramethyl-1-tosylquinazoline
1314036-27-5

1,4,4a,5,6,8a-hexahydro-2,4,4,7-tetramethyl-1-tosylquinazoline

Conditions
ConditionsYield
With phenyltrimethylammonium tribromide at 25℃; for 5h;82%
With phenyltrimethylammonium tribromide at 25℃;82%
2-carene
4497-92-1

2-carene

A

<1S-(1α,2α,3α,4α)>-3,7,7-trimethylbicyclo<4.1.0>heptane-2,3-diol
55623-17-1, 55623-21-7, 71665-39-9, 71665-42-4, 73010-68-1

<1S-(1α,2α,3α,4α)>-3,7,7-trimethylbicyclo<4.1.0>heptane-2,3-diol

B

(-)-3-hydroxy-2-caranone
55623-18-2

(-)-3-hydroxy-2-caranone

Conditions
ConditionsYield
With sodium hydroxide; potassium permanganate In water; tert-butyl alcohol at 0℃; for 0.25h;A 79%
B 3.6%
2-carene
4497-92-1

2-carene

(3R,6S)-3-(2-azidopropan-2-yl)-6-methylcyclohex-1-ene
1329656-60-1

(3R,6S)-3-(2-azidopropan-2-yl)-6-methylcyclohex-1-ene

Conditions
ConditionsYield
Stage #1: 2-carene With N,N-dimethyl acetamide; benzo[1,3,2]dioxaborole In dichloromethane at 0℃; for 5h; Reflux; Inert atmosphere;
Stage #2: With phenylsulfonyl azide; trans-di-O-tert-butyl hyponitrite In N,N-dimethyl-formamide at 80℃; Inert atmosphere; regioselective reaction;
79%
chloroamine-T
127-65-1

chloroamine-T

2-carene
4497-92-1

2-carene

propiononitrile
107-12-0

propiononitrile

C20H28N2O2S
1314036-28-6

C20H28N2O2S

Conditions
ConditionsYield
With phenyltrimethylammonium tribromide at 25℃; for 5h;78%
2-carene
4497-92-1

2-carene

(-)-2-isocaranol
219572-62-0

(-)-2-isocaranol

Conditions
ConditionsYield
Stage #1: 2-carene With C13H31BS In tetrahydrofuran at 20℃; for 2h;
Stage #2: With sodium hydroxide; dihydrogen peroxide at 20℃; for 8h;
77%
sodium [(benzyloxy)carbonyl]chloroamide
91174-01-5

sodium [(benzyloxy)carbonyl]chloroamide

2-carene
4497-92-1

2-carene

benzonitrile
100-47-0

benzonitrile

C25H28N2O2
1314036-48-0

C25H28N2O2

Conditions
ConditionsYield
With phenyltrimethylammonium tribromide at 25℃;76%
With phenyltrimethylammonium tribromide at 25℃; for 8h;69%
2-carene
4497-92-1

2-carene

diphenyldisulfane
882-33-7

diphenyldisulfane

C14H18OS

C14H18OS

Conditions
ConditionsYield
Stage #1: 2-carene With ozone In methanol at -78℃;
Stage #2: diphenyldisulfane In methanol at -78 - 0℃; for 0.166667h; Inert atmosphere;
Stage #3: With ferrous(II) sulfate heptahydrate In methanol; water at 0℃; for 0.0166667h; Inert atmosphere;
75%
propyl cyanide
109-74-0

propyl cyanide

chloroamine-T
127-65-1

chloroamine-T

2-carene
4497-92-1

2-carene

C21H30N2O2S
1314036-29-7

C21H30N2O2S

Conditions
ConditionsYield
With phenyltrimethylammonium tribromide at 25℃; for 5h;74%
With phenyltrimethylammonium tribromide at 25℃;74%
N-chloro-N-sodio-tert-butylcarbamate
73210-14-7

N-chloro-N-sodio-tert-butylcarbamate

2-carene
4497-92-1

2-carene

cyclopropropanecarbonitrile
5500-21-0

cyclopropropanecarbonitrile

C19H30N2O2
1415046-93-3

C19H30N2O2

Conditions
ConditionsYield
With phenyltrimethylammonium tribromide at 25℃; for 8h;74%
sodium [(benzyloxy)carbonyl]chloroamide
91174-01-5

sodium [(benzyloxy)carbonyl]chloroamide

2-carene
4497-92-1

2-carene

cyclopropropanecarbonitrile
5500-21-0

cyclopropropanecarbonitrile

C22H28N2O2
1415046-95-5

C22H28N2O2

Conditions
ConditionsYield
With phenyltrimethylammonium tribromide at 25℃; for 8h;73%
propyl cyanide
109-74-0

propyl cyanide

sodium [(benzyloxy)carbonyl]chloroamide
91174-01-5

sodium [(benzyloxy)carbonyl]chloroamide

2-carene
4497-92-1

2-carene

C22H30N2O2
1415046-97-7

C22H30N2O2

Conditions
ConditionsYield
With phenyltrimethylammonium tribromide at 25℃; for 8h;73%
2-carene
4497-92-1

2-carene

(1S,6R)-3,7,7-trimethylbicyclo[4.1.0]hept-3-ene-2,5-dione
67670-72-8

(1S,6R)-3,7,7-trimethylbicyclo[4.1.0]hept-3-ene-2,5-dione

Conditions
ConditionsYield
Stage #1: 2-carene With tert.-butylhydroperoxide; 3 A molecular sieve In decane; ethyl acetate at 20℃; for 0.5h;
Stage #2: With oxygen; manganese triacetate In decane; ethyl acetate at 20℃; for 48h;
65%
formaldehyd
50-00-0

formaldehyd

1,1'-(2,4,6-trihydroxy-1,3-phenylene)bis(3-methylbutan-1-one)
2999-10-2

1,1'-(2,4,6-trihydroxy-1,3-phenylene)bis(3-methylbutan-1-one)

2-carene
4497-92-1

2-carene

5,7-dihydroxy-1,1,9a-trimethyl-6,8-bis(3-methylbutanoyl)-1,1a,2,3,3a,4,9a,9b-octahydro-9-oxacyclopropa[a]anthracene
1017239-34-7

5,7-dihydroxy-1,1,9a-trimethyl-6,8-bis(3-methylbutanoyl)-1,1a,2,3,3a,4,9a,9b-octahydro-9-oxacyclopropa[a]anthracene

Conditions
ConditionsYield
With sodium acetate; acetic acid at 60℃; for 0.0666667h; microwave irradiation;65%
2,2,6,6-Tetramethyl-1-piperidinyloxy free radical
2564-83-2, 45842-10-2

2,2,6,6-Tetramethyl-1-piperidinyloxy free radical

2-carene
4497-92-1

2-carene

2,2,6,6-Tetramethyl-1-<1-methyl-1-<(1R,4S)-4-methyl-2-cyclohexen-1-yl>ethoxy>piperidine

2,2,6,6-Tetramethyl-1-<1-methyl-1-<(1R,4S)-4-methyl-2-cyclohexen-1-yl>ethoxy>piperidine

Conditions
ConditionsYield
Stage #1: 2-carene With N,N-dimethyl acetamide; benzo[1,3,2]dioxaborole In dichloromethane for 3h; Heating;
Stage #2: 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical With 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone; ethanol In dichloromethane at 0 - 20℃; Further stages.;
63%
With 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone; ethanol; N,N-dimethyl acetamide; benzo[1,3,2]dioxaborole 1.) CH2Cl2, reflux, 3 h, 2.) CH2Cl2, overnight, r.t.; Yield given; Multistep reaction;
formaldehyd
50-00-0

formaldehyd

2,4-diformyl 2,4,6-trihydroxybenzene
4396-13-8

2,4-diformyl 2,4,6-trihydroxybenzene

2-carene
4497-92-1

2-carene

5,7-dihydroxy-1,1,9a-trimethyl-8-(3-methylbutanoyl)-1,1a,2,3,3a,4,9a,9b-octahydro-9-oxacyclopropa[a]anthracene-6,8-dicarbaldehyde
1017239-32-5

5,7-dihydroxy-1,1,9a-trimethyl-8-(3-methylbutanoyl)-1,1a,2,3,3a,4,9a,9b-octahydro-9-oxacyclopropa[a]anthracene-6,8-dicarbaldehyde

Conditions
ConditionsYield
With sodium acetate; acetic acid at 60℃; for 0.0666667h; microwave irradiation;62%
chloroamine-T
127-65-1

chloroamine-T

2-carene
4497-92-1

2-carene

benzonitrile
100-47-0

benzonitrile

C24H28N2O2S
1314036-30-0

C24H28N2O2S

Conditions
ConditionsYield
With phenyltrimethylammonium tribromide at 25℃; for 8h;62%
With phenyltrimethylammonium tribromide at 25℃;62%
S-Phenyl benzenethiosulfonate
1212-08-4

S-Phenyl benzenethiosulfonate

2-carene
4497-92-1

2-carene

1-methyl-1-[(1R,4S)-4-methyl-2-cyclohexen-1-yl]ethyl phenyl sulfide
1118071-56-9

1-methyl-1-[(1R,4S)-4-methyl-2-cyclohexen-1-yl]ethyl phenyl sulfide

Conditions
ConditionsYield
Stage #1: 2-carene With N,N-dimethyl acetamide; benzo[1,3,2]dioxaborole In dichloromethane for 5h; Inert atmosphere; Reflux;
Stage #2: S-Phenyl benzenethiosulfonate With di-tert-butoxydiazene In methanol; dichloromethane Reflux;
61%

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