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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

Ethylaluminum dichloride

Cas:563-43-9

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Hebei yanxi chemical co.,LTD.

Hebei yanxi chemical co. LTD. has expanded a compositive entity from initially only as a small manufacturer. The company dedicated to the development, production and marketing of chemicals. After many years of efforts, we have established stable

Ethylaluminum dichloride

Cas:563-43-9

Min.Order:1 Metric Ton

FOB Price: $1.0 / 2.0

Type:Manufacturers

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Henan Allgreen Chemical Co.,Ltd

high quality Appearance:White or off-white Solid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai

ETHYLALUMINUM DICHLORIDE

Cas:563-43-9

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Ethylaluminium dichloride

Cas:563-43-9

Min.Order:1

Negotiable

Type:Other

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HANGZHOU YUNUO CHEMICAL CO.,LTD

superior quality moderate price & quick delivery Appearance:Clear colorless to yellow solution Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Applicat

Aluminum,dichloroethyl-

Cas:563-43-9

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung, LG, Merck, Thermo Fisher Scientific and so o

ETHYLALUMINUM DICHLORIDE,563-43-9

Cas:563-43-9

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Lab/Research institutions

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Henan Sinotech Import&Export Corporation

No. Test item Index 1 performance transparent liquid 2 aluminum (Wt%) 20.2

Aluminium ethyl dichloride (EADC),Ethylaluminum dichloride

Cas:563-43-9

Min.Order:1600 Kilogram

FOB Price: $1.0

Type:Other

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Hangzhou Dingyan Chem Co., Ltd

Ethylaluminum dichloride solution 563-43-9 Appearance:Colorless liquid Assay(TiTration by EDTA):1.03M Appearance:Colorless liquid Package:drum Application:industral Transportation:by sea Port:Shanghai, Ningbo

Ethylaluminum dichloride solution 563-43-9

Cas:563-43-9

Min.Order:1 Liter

Negotiable

Type:Lab/Research institutions

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Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

Aluminium ethyl dichloride

Cas:563-43-9

Min.Order:0

Negotiable

Type:Other

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Wuhan Fortuna Chemical Co.,Ltd

1.High quality : the purity is 99% min . through multiple producing procedures. 2.Competitive price : low price because of our skilled production technolpgy ,save the production cost at most , and give big profit room to our customers507.Safe and fa

Aluminium ethyl dichloride

Cas:563-43-9

Min.Order:0

Negotiable

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard

factory directly supply CAS 563-43-9 with competitive price

Cas:563-43-9

Min.Order:1 Kilogram

FOB Price: $112.0

Type:Trading Company

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Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

EthylaluMinuM dichloride, 1.6 M solution in hexanes, J&KSeal

Cas:563-43-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Amadis Chemical Co., Ltd.

1.Professional synthesis laboratory and production base. 2.Strong synthesis team and service team. 3.Professional data management system. 4.We provide the professional test date and product information ,ex. HNMR ,CNMR,FNMR, HPLC/G

Amadis Chemical offer CAS#563-43-9;CAT#A831008

Cas:563-43-9

Min.Order:10 Milligram

Negotiable

Type:Lab/Research institutions

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HENAN SUNLAKE ENTERPRISE CORPORATION

ETHYLALUMINUM DICHLORIDE

Cas:563-43-9

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Changzhou Extraordinary Pharmatech co.,LTD

Changzhou Extraordinary Pharmatech co., LTD. As a leading chemical manufacturer and supplier in China.DAS authentication is passed.We can provide the popular precursor chemicals, we have our own strong R & D team, have our own laboratories and fa

Ethylaluminum dichloride

Cas:563-43-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Shaanxi Mingqi Chemical Co., Ltd

Known for its best quality and competitve price, this chemicals we offered is widely appreciated by our customers.1) Standard:BP/USP/EP/Enterprise standard2) All Purity≥99%3) We are manufacturer and can provide high quality products with factory pric

Manufacturer Supply Top quality Ethylaluminum dichloride

Cas:563-43-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

ShangHai YanDiNew Material Science Technology CO.,LTD

Index: No. Test item Index 1 perfo

ETHYLALUMINIUMDICHOLRIDE(EADC)

Cas:563-43-9

Min.Order:6 Metric Ton

FOB Price: $8000.0

Type:Other

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Shandong Bolode Bio-Technology Co., LTD

Known for its best quality and competitve price, this chemicals we offered is widely appreciated by our customers. 1) All Purity≥95% 2) We are manufacturer and can provide high quality products with factory price. 2, Fast and s

Ethyl aluminium dichloride

Cas:563-43-9

Min.Order:1 Gram

Negotiable

Type:Trading Company

inquiry

Cerametek Materials(ShenZhen)Co., Ltd.

sub/micron to mesh powders (near/spheres, whiskers, flake, fiber, porous) and grain/ball, thin/ thick metal / alloys pieces / parts, thin and thick (particle) film materials /target, and custom-made crystals, substrates/parts. In the industries and a

Aluminum diethyl chloride (DEAC)

Cas:563-43-9

Min.Order:0

Negotiable

Type:Other

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Hangzhou Share Chemical Co., Ltd

At Share Chemical Company, we scrupulously abide by our policy of “Excellent Quality at a Reasonable Price”. We strive to satisfy all of our customers by providing the finest quality products supported by the finest in customer servi

EthylaluMinuM dichloride, 1M in h

Cas:563-43-9

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

ORCHID CHEMICAL SUPPLIES LTD

Ethylaluminum dichloride CAS#563-43-9 Storage:Keep container tightly closed in a dry, cool and well-ventilated place. Package:25Kg/drum, 150Kg/drum, 200kg/drum, According to request. Transportation:By sea, by air.

Ethylaluminum dichloride

Cas:563-43-9

Min.Order:0

Negotiable

Type:Other

inquiry

Skyrun Industrial Co.,Ltd

Good Price, prompt shipment Application:Catalytic agent; Petrochemical additive; Used in organic synthesis

Aluminium ethyl dichloride

Cas:563-43-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Changzhou Foreign Trade Corp

CFTC?PharmaChem?is?a?service?based?company?in?China,?a?pharmachem?division?of?Changzhou?Foreign?Trade?Corp.,supplying?raw?materials,?intermediates,?APIs?and?fine?chemicals?for?the?pharmaceutical?and?specialty?chemical?industries?worldwide. Applicatio

Ethylaluminium dichloride

Cas:563-43-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

NovaChemistry

High purity Application:Pharmaceutical intermediates, Material synthesis and analyzing the expectant ingredients

ethylaluminum dichloride, 1.8m in toluene (24-26 wt%)

Cas:563-43-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Sigma-Aldrich Chemie GmbH

Package:100, 800 g in Sure/Seal(TM)

Ethylaluminum dichloride solution

Cas:563-43-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Pfaltz & Bauer, Inc.

Ethylaluminum dichloride

Cas:563-43-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

ADVANCED TECH. & IND. CO., LTD.

Ethylaluminum dichloride

Cas:563-43-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

chloroethane
75-00-3

chloroethane

ethylaluminum dichloride
563-43-9

ethylaluminum dichloride

Conditions
ConditionsYield
With aluminium und anschliessend mit AlCl3;
With aluminium trichloride; aluminium
diethyl aluminium chloride

diethyl aluminium chloride

AlCl3

AlCl3

ethylaluminum dichloride
563-43-9

ethylaluminum dichloride

Conditions
ConditionsYield
at 180 - 190℃;
chloroethane
75-00-3

chloroethane

aluminium

aluminium

A

ethylaluminum dichloride
563-43-9

ethylaluminum dichloride

B

diethyl aluminium chloride

diethyl aluminium chloride

Conditions
ConditionsYield
With iodine bei Ausschluss von Feuchtigkeit und Sauerstoff;
With aluminium trichloride bei Ausschluss von Feuchtigkeit und Sauerstoff;
chloroethane
75-00-3

chloroethane

copper containing aluminium

copper containing aluminium

A

ethylaluminum dichloride
563-43-9

ethylaluminum dichloride

B

diethyl aluminium chloride

diethyl aluminium chloride

Conditions
ConditionsYield
With iodine bei Ausschluss von Feuchtigkeit und Sauerstoff;
With aluminium trichloride bei Ausschluss von Feuchtigkeit und Sauerstoff;
gem-1,1-bis(dichloroalumino)ethane
95465-40-0

gem-1,1-bis(dichloroalumino)ethane

ethene
74-85-1

ethene

aluminium
7429-90-5

aluminium

A

ethylaluminum dichloride
563-43-9

ethylaluminum dichloride

B

diethylaluminium chloride
96-10-6

diethylaluminium chloride

Conditions
ConditionsYield
In n-heptane byproducts: (CH2CHCHCH2CH(CH3))x; High Pressure; (Ar); to a soln. of Al-compound and Al added ethylene (20 bar pressure) under stirring at 100-150°C for 16 h; distd. in vacuo at 50°C; elem. anal.;
gem-1,1-bis(dichloroalumino)ethane
95465-40-0

gem-1,1-bis(dichloroalumino)ethane

ethene
74-85-1

ethene

ethylaluminum dichloride
563-43-9

ethylaluminum dichloride

Conditions
ConditionsYield
In n-heptane byproducts: (CH2CHCHCH2CH(CH3))x; High Pressure; (Ar); to a soln. of Al-compound added ethylene (20 bar pressure) under stirring at 100°C for 24 h; distd. in vacuo at 50°C; elem. anal.;
aluminium trichloride
7446-70-0

aluminium trichloride

triisobutylaluminum
100-99-2

triisobutylaluminum

A

ethylaluminum dichloride
563-43-9

ethylaluminum dichloride

B

diisobutylaluminum chloride
1779-25-5

diisobutylaluminum chloride

Conditions
ConditionsYield
In diethyl ether; toluene all manipulations under dry, O2 free N2 atm.; AlCl3 dissolved in Et2O, soln. of iso-Bu3Al in toluene added at -78°C, allowed to warm to room temp., stirred and refluxed for for 3, stirred at room temp. for 48 h h;
bis(tetrachloroaluminato)(η(6)-benzene)titanium(II)

bis(tetrachloroaluminato)(η(6)-benzene)titanium(II)

diethylaluminium chloride
96-10-6

diethylaluminium chloride

A

(η6-benzene)Ti(AlCl4)(AlCl3Et)

(η6-benzene)Ti(AlCl4)(AlCl3Et)

B

ethylaluminum dichloride
563-43-9

ethylaluminum dichloride

Conditions
ConditionsYield
In benzene Addn. of Et2AlCl to benzene soln. of Ti-compd. at 50°C.; Electronic absorption spectroscopy.;
hydrogenchloride
7647-01-0

hydrogenchloride

diethylaluminium chloride
96-10-6

diethylaluminium chloride

ethylaluminum dichloride
563-43-9

ethylaluminum dichloride

Conditions
ConditionsYield
In toluene byproducts: C2H6; (Ar); using Schlenk techniques; addn. of HCl saturated toluene to react. mixt. with Et2AlCl;
(η6-benzene)titanium(II)(AlCl2Et2)(AlCl3Et)

(η6-benzene)titanium(II)(AlCl2Et2)(AlCl3Et)

A

titanium chloride

titanium chloride

B

ethylaluminum dichloride
563-43-9

ethylaluminum dichloride

C

diethylaluminium chloride
96-10-6

diethylaluminium chloride

Conditions
ConditionsYield
In benzene Decompn. of Ti-compd.; Slow pptn. of TiCl2 from the soln. on a time scale of days-to-months obsd. by elecronic absorption spectroscopy.;
bis(tetrachloroaluminato)(η(6)-benzene)titanium(II)

bis(tetrachloroaluminato)(η(6)-benzene)titanium(II)

triethylaluminum
97-93-8

triethylaluminum

A

(η6-benzene)Ti(AlCl4)(AlCl3Et)

(η6-benzene)Ti(AlCl4)(AlCl3Et)

B

ethylaluminum dichloride
563-43-9

ethylaluminum dichloride

Conditions
ConditionsYield
In benzene Addn. of Et3Al to benzene soln. of Ti-compd. at 50°C.; Electronic absorption spectroscopy.;
triethylaluminum
97-93-8

triethylaluminum

trityl chloride
76-83-5

trityl chloride

ethylaluminum dichloride
563-43-9

ethylaluminum dichloride

Conditions
ConditionsYield
In toluene Kinetics; 25°C; UV/VIS monitoring;
gem-1,1-bis(dichloroalumino)ethane
95465-40-0

gem-1,1-bis(dichloroalumino)ethane

A

aluminium trichloride
7446-70-0

aluminium trichloride

B

ethylaluminum dichloride
563-43-9

ethylaluminum dichloride

Conditions
ConditionsYield
With HCl In methyl cyclohexane byproducts: ethane; passing of dry HCl into stirred soln. of Al-compnd. (1 h); solvent removal, anal.;
1-(chloroethylaluminum)-2-(dichloroaluminum)ethane
98351-23-6

1-(chloroethylaluminum)-2-(dichloroaluminum)ethane

ethene
74-85-1

ethene

ethylaluminum dichloride
563-43-9

ethylaluminum dichloride

Conditions
ConditionsYield
In further solvent(s) (Ar); ethylene bubbled through a soln. of Al-compound in a mixture of hydrocarbons (C10-C14) at 150°C for 48 h; distd.; elem. anal.;
1-(chloroethylaluminum)-2-(dichloroaluminum)ethane
98351-23-6

1-(chloroethylaluminum)-2-(dichloroaluminum)ethane

A

AlCl2CH2CH2Al(Cl)C2H4Al(Cl)C2H5
98351-24-7

AlCl2CH2CH2Al(Cl)C2H4Al(Cl)C2H5

B

ethylaluminum dichloride
563-43-9

ethylaluminum dichloride

C

diethylaluminium chloride
96-10-6

diethylaluminium chloride

Conditions
ConditionsYield
heated to 100°C;
gallium(III) trichloride

gallium(III) trichloride

diethylaluminium chloride
96-10-6

diethylaluminium chloride

A

ethylaluminum dichloride
563-43-9

ethylaluminum dichloride

B

ethylgallium dichloride
6917-79-9

ethylgallium dichloride

Conditions
ConditionsYield
Heating;A 50 %Spectr.
B 50 %Spectr.
gallium(III) trichloride

gallium(III) trichloride

triethylaluminum
97-93-8

triethylaluminum

A

ethylaluminum dichloride
563-43-9

ethylaluminum dichloride

B

ethylgallium dichloride
6917-79-9

ethylgallium dichloride

Conditions
ConditionsYield
Heating;A 33 %Spectr.
B 66 %Spectr.
bis(cyclopentadienyl)titanium dichloride
1271-19-8

bis(cyclopentadienyl)titanium dichloride

ethylaluminum dichloride
563-43-9

ethylaluminum dichloride

Cp2Ti(AlCl4)

Cp2Ti(AlCl4)

Conditions
ConditionsYield
In benzene at 25°C, after 4 days were warmed to 70°C for 20h; evapn.;100%
dichlorobis(η5-methylcyclopentadienyl)titanium(IV)
1282-40-2

dichlorobis(η5-methylcyclopentadienyl)titanium(IV)

ethylaluminum dichloride
563-43-9

ethylaluminum dichloride

(MeCp)2Ti(AlCl4)

(MeCp)2Ti(AlCl4)

Conditions
ConditionsYield
In benzene react. at room temp. for 4 days, warmed to 70°C for 20h; evapn.;100%
(η6-benzene)titanium(II)(Al2Cl8)

(η6-benzene)titanium(II)(Al2Cl8)

1,2,3,4,5-pentamethylcyclopentadiene
4045-44-7

1,2,3,4,5-pentamethylcyclopentadiene

ethylaluminum dichloride
563-43-9

ethylaluminum dichloride

(pentamethylcyclopentadiene)titanium(Al2Cl5.9(C2H5)2.1)

(pentamethylcyclopentadiene)titanium(Al2Cl5.9(C2H5)2.1)

Conditions
ConditionsYield
With triphenylphosphine In benzene mixing of Ti-compd. in benzene with cyclopentadiene, then addn. of Al-compd. and phosphine (molar ratio of Ti/Al/PPh3 = 1/2/2); monitored by ESR;100%
With triphenylphosphine In benzene mixing of Ti-compd. in benzene with cyclopentadiene, then addn. of Al-compd. and phosphine (molar ratio of Ti/Al/PPh3 = 1/3/2); monitored by ESR;100%
(η6-benzene)titanium(II)(Al2Cl8)

(η6-benzene)titanium(II)(Al2Cl8)

1,2,3,4,5-pentamethylcyclopentadiene
4045-44-7

1,2,3,4,5-pentamethylcyclopentadiene

ethylaluminum dichloride
563-43-9

ethylaluminum dichloride

(pentamethylcyclopentadiene)titanium(Al2Cl6.1(C2H5)1.9)

(pentamethylcyclopentadiene)titanium(Al2Cl6.1(C2H5)1.9)

Conditions
ConditionsYield
With triphenylphosphine In benzene mixing of Ti-compd. in benzene with cyclopentadiene, then addn. of Al-compd. (molar ratio of Ti/Al/PPh3 = 1/4/4); monitored by ESR;100%
methanol
67-56-1

methanol

ethylaluminum dichloride
563-43-9

ethylaluminum dichloride

succinoyl dichloride
543-20-4

succinoyl dichloride

methyl 4-oxohexanoate
2955-62-6

methyl 4-oxohexanoate

Conditions
ConditionsYield
In dichloromethane at -40℃; for 3.5h;99%
Stage #1: ethylaluminum dichloride; succinoyl dichloride In dichloromethane at -40℃; for 3.5h;
Stage #2: methanol In dichloromethane at -40℃;
99%
ethylaluminum dichloride
563-43-9

ethylaluminum dichloride

(1Z,1'Z)-N',N''-(1,3-phenylenebis(methylene))bis(N-(2,6-diisopropyl-phenyl)- 2,2-dimethylpropanimidamide)

(1Z,1'Z)-N',N''-(1,3-phenylenebis(methylene))bis(N-(2,6-diisopropyl-phenyl)- 2,2-dimethylpropanimidamide)

C42H60Al2Cl4N4

C42H60Al2Cl4N4

Conditions
ConditionsYield
In toluene at 100℃; for 16h; Schlenk technique; Inert atmosphere;98%
Tris(trimethylsilyl)phosphane
15573-38-3

Tris(trimethylsilyl)phosphane

ethylaluminum dichloride
563-43-9

ethylaluminum dichloride

C2H5Cl2AlP(Si(CH3)3)3

C2H5Cl2AlP(Si(CH3)3)3

Conditions
ConditionsYield
In pentane Ar-atmosphere; addn. of equimolar amt. of EtAlCl2 in pentane to P(SiMe3)3 in pentane; stirring (room temp., 24 h); decantation, evapn. of residual solvent from the solid; elem. anal.;97.6%
ethylaluminum dichloride
563-43-9

ethylaluminum dichloride

diethylaluminium chloride
96-10-6

diethylaluminium chloride

barium(II) chloride

barium(II) chloride

BaCl2*3C2H5AlCl2

BaCl2*3C2H5AlCl2

Conditions
ConditionsYield
In neat (no solvent) anhyd. BaCl2 and C2H5AlCl2 heated at 50°C for 5 h with stirring,soln. cooled to 0°C, (C2H5)2AlCl added under N2 atm.; mixt. cooled to 0°C, n-heptane added, ppt. filtered off, washed with n-hexane and dried in vacuo; elem. anal.;97%
ethylaluminum dichloride
563-43-9

ethylaluminum dichloride

calcium chloride

calcium chloride

CaCl2*2C2H5AlCl2

CaCl2*2C2H5AlCl2

Conditions
ConditionsYield
In neat (no solvent) anhyd. CaCl2 added to C2H5AlCl2 and mixt. heated with stirring at 110°C for 5 h under N2 atm.; soln. cooled to room temp., n-heptane added, ppt. filtered off, washed with n-hexane and dried in vacuo; elem. anal.;96.7%
N-{4-[(2,6-diisopropylphenyl)imino]pent-2-en-2-yl}pyridin-2-amine

N-{4-[(2,6-diisopropylphenyl)imino]pent-2-en-2-yl}pyridin-2-amine

ethylaluminum dichloride
563-43-9

ethylaluminum dichloride

Al(N-{4-[(2,6-diisopropylphenyl)imino]pent-2-en-2-yl}pyridin-2-amino)Cl2

Al(N-{4-[(2,6-diisopropylphenyl)imino]pent-2-en-2-yl}pyridin-2-amino)Cl2

Conditions
ConditionsYield
In tetrahydrofuran; dichloromethane at -35 - 20℃; Inert atmosphere; Glovebox;96%
ethylaluminum dichloride
563-43-9

ethylaluminum dichloride

calcium chloride

calcium chloride

CaCl2*4C2H5AlCl2

CaCl2*4C2H5AlCl2

Conditions
ConditionsYield
In neat (no solvent) anhyd. CaCl2 added to C2H5AlCl2 and mixt. heated with stirring at 110°C for 5 h under N2 atm.; soln. cooled to -10°C, n-heptane added, ppt. filtered off, washed with n-hexane and dried in vacuo; elem. anal.;95.8%
ethylaluminum dichloride
563-43-9

ethylaluminum dichloride

diethylaluminium chloride
96-10-6

diethylaluminium chloride

strontium chloride

strontium chloride

SrCl2*3C2H5AlCl2

SrCl2*3C2H5AlCl2

Conditions
ConditionsYield
In neat (no solvent) anhyd. SrCl2 and C2H5AlCl2 heated at 100°C for 18 h with stirring, (C2H5)2AlCl added to soln. under N2 atm.; mixt. cooled to 0°C, n-heptane added, ppt. filtered off, washed with n-hexane and dried in vacuo; elem. anal.;95.7%
allyl 2-(4-methoxyphenylimino)-2-(4-methoxyphenyl)acetate
1367074-92-7

allyl 2-(4-methoxyphenylimino)-2-(4-methoxyphenyl)acetate

ethylaluminum dichloride
563-43-9

ethylaluminum dichloride

diethylaluminium chloride
96-10-6

diethylaluminium chloride

4-methoxy-N-ethylaniline
104-48-3

4-methoxy-N-ethylaniline

Conditions
ConditionsYield
Stage #1: allyl 2-(4-methoxyphenylimino)-2-(4-methoxyphenyl)acetate; ethylaluminum dichloride; diethylaluminium chloride In 1,2-dimethoxyethane; hexane at 40℃; Inert atmosphere;
Stage #2: With water; Rochelle's salt In 1,2-dimethoxyethane; hexane at 20℃; for 0.5h;
95%
ethylaluminum dichloride
563-43-9

ethylaluminum dichloride

N-phenyl-S-(4-methylphenyl)sulfoximidoyl chloride
123552-85-2

N-phenyl-S-(4-methylphenyl)sulfoximidoyl chloride

S-ethyl-S-(4-methylphenyl)-N-phenylsulfoximine
123552-91-0

S-ethyl-S-(4-methylphenyl)-N-phenylsulfoximine

Conditions
ConditionsYield
In dichloromethane at -78℃; for 1h;94%
(CH2CH(CH2)2CHMeCH2)Ti(η5-C5H5)2Cl

(CH2CH(CH2)2CHMeCH2)Ti(η5-C5H5)2Cl

ethylaluminum dichloride
563-43-9

ethylaluminum dichloride

(CH2(CHCH2CHMe(CH2)2-cyclic))Ti(η5-C5H5)2Cl

(CH2(CHCH2CHMe(CH2)2-cyclic))Ti(η5-C5H5)2Cl

Conditions
ConditionsYield
In toluene inert atmosphere; cooling soln. of Ti-compd. in toluene (-78°C)addn. of AlCl2Et in toluene, stirring (-78°C, 30 min); not isolated, quenched with HCl isolation of org. compds.;94%
1-tert-butoxy-2-propanol
57018-52-7

1-tert-butoxy-2-propanol

ethylaluminum dichloride
563-43-9

ethylaluminum dichloride

[Cl2Al(OCH(CH3)CH2OC(CH3)3)]2
463966-50-9

[Cl2Al(OCH(CH3)CH2OC(CH3)3)]2

Conditions
ConditionsYield
In hexane (Ar); addn. of a soln. of alcohol in hexane to a soln. of aluminium compd. in hexane at 0°C; evapn., drying in vac., recrystn. (hexane); elem. anal.;94%
(CH2CHCH2CHMe(CH2)2)Ti(η5-C5H5)2Cl

(CH2CHCH2CHMe(CH2)2)Ti(η5-C5H5)2Cl

ethylaluminum dichloride
563-43-9

ethylaluminum dichloride

(CH2(CHCH2CHMe(CH2)2-cyclic))Ti(η5-C5H5)2Cl

(CH2(CHCH2CHMe(CH2)2-cyclic))Ti(η5-C5H5)2Cl

Conditions
ConditionsYield
In toluene inert atmosphere; cooling soln. of Ti-compd. in toluene (-78°C)addn. of AlCl2Et in toluene, stirring (-78°C, 30 min); not isolated, quenched with HCl isolation of org. compds.;93%
(CH2CHCHMe(CH2)3)Ti(η5-C5H5)2Cl

(CH2CHCHMe(CH2)3)Ti(η5-C5H5)2Cl

ethylaluminum dichloride
563-43-9

ethylaluminum dichloride

(CH2(CHCHMe(CH2)3-cyclic))Ti(η5-C5H5)2Cl

(CH2(CHCHMe(CH2)3-cyclic))Ti(η5-C5H5)2Cl

Conditions
ConditionsYield
In toluene byproducts: 1,2-dimethylcyclopentane; inert atmosphere; cooling soln. of Ti-compd. in toluene (-78°C)addn. of AlCl2Et in toluene, stirring (-78°C, 30 min); not isolated, quenched with HCl isolation of org. compds.;93%
dipotassium pentacarbonylchromate

dipotassium pentacarbonylchromate

N,N,N,N,-tetramethylethylenediamine
110-18-9

N,N,N,N,-tetramethylethylenediamine

ethylaluminum dichloride
563-43-9

ethylaluminum dichloride

(CO)5CrAl[(CH2CH3)(N(CH3)2CH2)2]

(CO)5CrAl[(CH2CH3)(N(CH3)2CH2)2]

Conditions
ConditionsYield
In tetrahydrofuran byproducts: KCl; (N2 or Ar); pptn. of carbonyl dianion in situ, cooling (-78°C), addn. of CH3CH2AlCl2 (-78°C), warming (room temp.), stirring (1 h), addn. of Lewis base ligand, stirring (30 min, 25°C); solvent removing (vac.), extn. (CH2Cl2), graphite sedimentation, filtn. (cannula), concn., storing (-30°C), decantation, concn.;92%
In tetrahydrofuran; dichloromethane byproducts: KCl; molar ratio Cr complex:AlCl2R:TMEDA 2:2:1, cooling (-78°C), stirring (3 h, 25°C); solvent exchange, filtn., concn., crystn. (-30°C);90%
dipotassium pentacarbonyltungstate(-II)

dipotassium pentacarbonyltungstate(-II)

N,N,N,N,-tetramethylethylenediamine
110-18-9

N,N,N,N,-tetramethylethylenediamine

ethylaluminum dichloride
563-43-9

ethylaluminum dichloride

(CO)5WAl[(CH2CH3)(N(CH3)2CH2)2]

(CO)5WAl[(CH2CH3)(N(CH3)2CH2)2]

Conditions
ConditionsYield
In tetrahydrofuran byproducts: KCl; (N2 or Ar); pptn. of carbonyl dianion in situ, cooling (-78°C), addn. of CH3CH2AlCl2 (-78°C), warming (room temp.), stirring (1 h), addn. of Lewis base ligand, stirring (30 min, 25°C); solvent removing (vac.), extn. (CH2Cl2), graphite sedimentation, filtn. (cannula), concn., storing (-30°C), decantation, concn.;92%
dipotassium pentacarbonylmolybdate(-II)

dipotassium pentacarbonylmolybdate(-II)

N,N,N,N,-tetramethylethylenediamine
110-18-9

N,N,N,N,-tetramethylethylenediamine

ethylaluminum dichloride
563-43-9

ethylaluminum dichloride

(CO)5MoAl[(CH2CH3)(N(CH3)2CH2)2]

(CO)5MoAl[(CH2CH3)(N(CH3)2CH2)2]

Conditions
ConditionsYield
In tetrahydrofuran byproducts: KCl; (N2 or Ar); pptn. of carbonyl dianion in situ, cooling (-78°C), addn. of CH3CH2AlCl2 (-78°C), warming (room temp.), stirring (1 h), addn. of Lewis base ligand, stirring (30 min, 25°C); solvent removing (vac.), extn. (CH2Cl2), graphite sedimentation, filtn. (cannula), concn., storing (-30°C), decantation, concn.;92%
ethylaluminum dichloride
563-43-9

ethylaluminum dichloride

3,6-endomethylene-1,2,3,6-tetrahydrophthalic anhydride
129-64-6

3,6-endomethylene-1,2,3,6-tetrahydrophthalic anhydride

(+/-)-(2,3-endo)-3-(1-oxopropyl)bicyclo<2.2.1>hept-5-ene-2-carboxylic acid
100058-98-8, 106924-58-7, 113352-73-1, 113429-13-3, 113429-14-4

(+/-)-(2,3-endo)-3-(1-oxopropyl)bicyclo<2.2.1>hept-5-ene-2-carboxylic acid

Conditions
ConditionsYield
In hexane; dichloromethane at -10℃; for 1h;91%
solfit
56539-66-3

solfit

ethylaluminum dichloride
563-43-9

ethylaluminum dichloride

[Cl2Al(OCH2CH2C(CH3)2OCH3)]2
463966-53-2

[Cl2Al(OCH2CH2C(CH3)2OCH3)]2

Conditions
ConditionsYield
In hexane (Ar); slow addn. of a soln. of alcohol in hexane to a soln. of aluminiumcompd. in hexane at 0°C, stirring for 0.5 h, slow warming to roo m temp.; evapn., drying in vac. crystn. (toluene, 5°C, 3 d); elem. anal.;91%
(η6-benzene)titanium(II)(Al2Cl8)

(η6-benzene)titanium(II)(Al2Cl8)

1,2,3,4,5-pentamethylcyclopentadiene
4045-44-7

1,2,3,4,5-pentamethylcyclopentadiene

ethylaluminum dichloride
563-43-9

ethylaluminum dichloride

(pentamethylcyclopentadiene)titanium(Al2Cl4.3(C2H5)3.7)

(pentamethylcyclopentadiene)titanium(Al2Cl4.3(C2H5)3.7)

Conditions
ConditionsYield
With triphenylphosphine In benzene mixing of Ti-compd. in benzene with cyclopentadiene, then addn. of Al-compd. and phosphine (molar ratio of Ti/Al/PPh3 = 1/5/5); monitored by ESR;90%
cobaltocenium chloride

cobaltocenium chloride

ethylaluminum dichloride
563-43-9

ethylaluminum dichloride

{(C5H5)2Co}(1+)*{(C2H5)AlCl3}(1-)={(C5H5)2Co}{(C2H5)AlCl3}

{(C5H5)2Co}(1+)*{(C2H5)AlCl3}(1-)={(C5H5)2Co}{(C2H5)AlCl3}

Conditions
ConditionsYield
In diethyl ether dropping of ethereal soln. of Al compd. into suspn. of Co complex at 20°C; elem. anal.;90%
ethylaluminum dichloride
563-43-9

ethylaluminum dichloride

(valeryloxy)quinoline
27037-38-3

(valeryloxy)quinoline

heptan-3-one
106-35-4

heptan-3-one

Conditions
ConditionsYield
In dichloromethane added at -70 deg C, then 7-13 h at room temperature;89%
ethylaluminum dichloride
563-43-9

ethylaluminum dichloride

8-heptanoyloxyquinoline
74010-58-5

8-heptanoyloxyquinoline

3-nonanone
925-78-0

3-nonanone

Conditions
ConditionsYield
In dichloromethane -70 deg C, then 20 deg C, 8 h;88%
In dichloromethane added at -70 deg C, then 7-13 h at room temperature;88%
ethylaluminum dichloride
563-43-9

ethylaluminum dichloride

(E)-But-2-enoic acid quinolin-8-yl ester

(E)-But-2-enoic acid quinolin-8-yl ester

Conditions
ConditionsYield
In dichloromethane added at -70 deg C, then 7-13 h at at room temperature. AlCl3 can be added as well.;87%
ethylaluminum dichloride
563-43-9

ethylaluminum dichloride

Cyclohex-3-enecarboxylic acid quinolin-8-yl ester

Cyclohex-3-enecarboxylic acid quinolin-8-yl ester

1-cyclohex-3-enyl-propan-1-one
14886-88-5

1-cyclohex-3-enyl-propan-1-one

Conditions
ConditionsYield
In dichloromethane added at -70 deg C, then 7-13 h at at room temperature.;87%
ethylaluminum dichloride
563-43-9

ethylaluminum dichloride

(S)-3-butyl-2-methanesulfonyloxy-3-heptanol
93827-09-9

(S)-3-butyl-2-methanesulfonyloxy-3-heptanol

(S)-6-methyl-5-decanone
93827-10-2

(S)-6-methyl-5-decanone

Conditions
ConditionsYield
In hexane; dichloromethane87%
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