Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new ap
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inquiryDayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities
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inquiryWelcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our
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inquiryProduct Description Product website: http://www.finerchem.com/pro01en/id/1091.html Product Name 1,3-Dimethyladamantane CAS No. 702-79-4 Appearance Colorless transparent liquid Assay
Cas:702-79-4
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inquiryProduct Name: 1,3-Dimethyladamantane CAS RN.: 702-79-4 EINECS: 211-870-8
Cas:702-79-4
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inquiryThe above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi
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inquiry1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s
Cas:702-79-4
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inquiryOur main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block
Cas:702-79-4
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inquiryHebei Yanxi Chemical Co., Ltd. is a professional research, development and production of lead acetate benzene acetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low car
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inquiryAbout Product Details Item Specification Test Results Appearance White crystalline powder Conform
Cas:702-79-4
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inquiryOur company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O
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inquiryWith our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin
Cas:702-79-4
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inquiryWITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et
Cas:702-79-4
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inquiryOur Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We
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inquiryHello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by email in t
Cas:702-79-4
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inquiryProduct name: 1,3-Dimethyladamantane English name: 1,3-Dimethyladamantane Alias: 1,3-Dimethyltricyclo(3.3.1.13,7)decane; 1,3-Dimethylasamantane; 1,3-dimethyltricyclo[3.3.1.1~3,7~]decane Molecular formula: C12H20 Molecular weight: 164.29 CAS No
Cas:702-79-4
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inquiry1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized
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inquiryAdvantage : LIDE PHARMACEUTICALS LTD. is a mid-small manufacturing-type enterprise, engaged in pharmaceutical intermediates of R&D, custom-made and production, and also involving trading chemicals for export. We have established the
Cas:702-79-4
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inquiry★.Best quality according to requirement ★.Competitive price in China market ★.Mature Technical support ★.Professional logistic support ★.Shortest delivery time . Appearance:Refer to COA Storage:Store in dry, cool and ventilated place Package:Acc
Cas:702-79-4
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inquiry1,3-Dimethyladamantane CAS:702-79-4 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic inte
Cas:702-79-4
Min.Order:1 Gram
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Type:Lab/Research institutions
inquiryWe have overseas warehouses in California, New Laredo Mexico, Vancouver Canada, Amsterdam Netherlands, and Melbourne Australia. Overseas warehouses can provide some of the best-selling products. We look forward to the cooperation of local powerful
Cas:702-79-4
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Type:Trading Company
inquiry1.high quality: quality is life. quality is the most important element for all goods. we have a lab doing research in wuhan china. hplc and nmr is available if needed. 2.reasonable price: we provide high quality products wi
Cas:702-79-4
Min.Order:10 Gram
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inquiryCompany information: Hebei Mojin Biotechnology Co., Ltd, Our company is a professional in chemical raw materials and chemical reagents research and development production enterprises. Our business covers more than 30 countries, most of the big cust
Cas:702-79-4
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FOB Price: $7.0 / 10.0
Type:Trading Company
inquiryHenan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod
Appearance:white or light yellow crystalline powder Storage:Store in a cool,dry place and keep away from direct strong light Package:As customer request Application:Used for research and industrial manufacture. Transportation:By
Cas:702-79-4
Min.Order:100 Gram
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inquiry1. Well-equipped, stable and high-quality raw material supply chain, to provide customers with the best quality products. 2.Strict quality inspection process and professional certificate testing to ensure the quality level of the final product. 3.E
Cas:702-79-4
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inquirySpecification:USP/EP Month production ablity:50kg/Month Low price& High quality Manufacturer Appearance:white powder Storage:Room Temperature Application:702-79-4
Hubei Lidu New Materials Technology Co. , Ltd. is located in No. 12,3C Industrial Park, Zhongxiang Economic Development Zone, Hubei Province. The company is committed to fine chemical raw materials, pharmaceutical intermediates and other production,
Cas:702-79-4
Min.Order:1 Gram
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Type:Lab/Research institutions
inquiry1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highly qualifie
Cas:702-79-4
Min.Order:1 Kilogram
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Type:Lab/Research institutions
inquiryHangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det
Cas:702-79-4
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inquiryConditions | Yield |
---|---|
With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride at 90℃; for 1h; Solvent; Barton-McCombie Deoxygenation; Inert atmosphere; | 100% |
With decane; 2,2’-azobis(4-methoxy-2,4-dimethyl)valeronitrile; tri-n-butyl-tin hydride In toluene at 80℃; for 0.0166667h; | 99 % Chromat. |
Multi-step reaction with 2 steps 1: 98 percent / aq. HCl / dimethylformamide / 1.5 h 2: H2SO4 (91.5percent) / 72 h / Ambient temperature; var. of conc.of H2SO4, and var. of reaction time View Scheme |
1-bromo-3-methyladamantane
methylmagnesium bromide
A
1,3-dimethyladamantane
1-methyl-adamantane
Conditions | Yield |
---|---|
In dibutyl ether at 85℃; | A 99% B 1% |
3,5-dimethyl-1-bromoadamantane
methylmagnesium bromide
A
1,3-dimethyladamantane
B
1,3,5-trimethyladamantane
Conditions | Yield |
---|---|
In dibutyl ether at 95℃; | A 2% B 98% |
Conditions | Yield |
---|---|
With aluminium trichloride at 69.85℃; for 50h; | 90% |
With hydrogen fluoride; boron trifluoride Temperature; Autoclave; | 75% |
With Y-zeolite(Na/H 0.97) In hexane at 300℃; for 10h; Concentration; Temperature; Time; Autoclave; Sealed tube; | 65% |
adamantane
methyl iodide
A
1,3-dimethyladamantane
1-methyl-adamantane
Conditions | Yield |
---|---|
With Rh(PPh3)3Cl In dichloromethane at 150℃; for 3h; | A 79% B 21% |
Conditions | Yield |
---|---|
With hydrogen fluoride; boron trifluoride at 100℃; for 4h; Temperature; Autoclave; | A 77% B 15% |
(3,5-dimethyl-adamantan-1-yl)-methanol
1,3-dimethyladamantane
Conditions | Yield |
---|---|
With cerium(III) chloride; 9,10-diphenylanthracene; 1,2-bis(2,4,6-triisopropylphenyl)disulfane; tetrabutyl-ammonium chloride In acetonitrile for 24h; Irradiation; Inert atmosphere; | 69% |
(1α,4α,4aβ,5α,8α,8aβ)-decahydro-1,4:5,8-dimethanonaphthalene
A
1,3-dimethyladamantane
B
1-ethyladamantane
C
1,4-dimethyladamantane
Conditions | Yield |
---|---|
With Y-zeolite(Na/H 0.97) In hexane at 300℃; for 10h; Autoclave; Sealed tube; | A 67% B 6% C 22% |
1,3-dibromoadamantane
methylmagnesium bromide
A
1,3-dimethyladamantane
B
adamantane
1-methyl-adamantane
Conditions | Yield |
---|---|
In dibutyl ether at 140℃; | A 52% B 4% C 44% |
1,3-dibromoadamantane
methylmagnesium bromide
A
1,3-dimethyladamantane
B
adamantane
C
1-bromo-3-methyladamantane
Conditions | Yield |
---|---|
In dibutyl ether at 140℃; | A 52% B 4% C 44% |
1,3-dibromoadamantane
A
1,3-dimethyladamantane
B
adamantane
1-methyl-adamantane
Conditions | Yield |
---|---|
With methylmagnesium bromide In dibutyl ether at 140℃; | A 52% B 4% C 44% |
(1α,4α,4aβ,5α,8α,8aβ)-decahydro-1,4:5,8-dimethanonaphthalene
A
1,3-dimethyladamantane
B
1,2-dimethyladamantane
C
1-ethyladamantane
D
1,4-dimethyladamantane
Conditions | Yield |
---|---|
With Y-zeolite(Na/H 0.4) In hexane at 300℃; for 30h; Concentration; Time; | A 49% B 9% C 11% D 24% |
With Y-zeolite(Na/H 0.4) In hexane at 300℃; for 10h; Concentration; Time; | A 18% B 8% C 10% D 21% |
tetramethylsilane
1-adamanthanol
A
1,3-dimethyladamantane
B
adamantane
C
1,3,5,7-tetramethyladamantane
D
1,3,5-trimethyladamantane
1-methyl-adamantane
Conditions | Yield |
---|---|
With aluminum tri-bromide In dichloromethane at 20℃; for 5h; Product distribution; other time;; | A 33% B n/a C 10% D 29% E 13% |
tetramethylsilane
1-adamanthanol
A
1,3-dimethyladamantane
B
1,3,5,7-tetramethyladamantane
C
1,3,5-trimethyladamantane
1-methyl-adamantane
Conditions | Yield |
---|---|
With aluminum tri-bromide In dichloromethane at 20℃; for 5h; | A 33% B 10% C 29% D 13% |
With aluminum tri-bromide |
ethyl-cyclohexane
A
1,3-dimethyladamantane
B
1,3,5,7-tetramethyladamantane
C
trans-Decalin
D
1-ethyladamantane
E
1,3,5-trimethyladamantane
1-methyl-adamantane
Conditions | Yield |
---|---|
With aluminium trichloride; tertiary butyl chloride at 160℃; for 15h; Product distribution; | A 18.76% B 6.3% C 1.25% D 3.46% E 15.01% F 2.76% |
methyl cyclohexane
A
1,3-dimethyladamantane
B
1,3,5,7-tetramethyladamantane
C
trans-Decalin
D
1-ethyladamantane
E
1,3,5-trimethyladamantane
1-methyl-adamantane
Conditions | Yield |
---|---|
With aluminium trichloride; tertiary butyl chloride at 160℃; for 15h; Product distribution; | A 10.78% B 7.79% C 4.7% D 4.25% E 17.49% F 1.5% |
(1α,4α,4aβ,5α,8α,8aβ)-decahydro-1,4:5,8-dimethanonaphthalene
A
1,3-dimethyladamantane
B
1,4-dimethyladamantane
Conditions | Yield |
---|---|
With Y-zeolite(Na/H 0.4) In hexane at 300℃; for 10h; Concentration; Time; | A 17% B 15% |
With Y-zeolite(Na/H 0.97) In hexane at 300℃; for 30h; Concentration; Time; | A 6% B 9% |
(1-methylethyl)-cyclohexane
A
1,3-dimethyladamantane
B
1,3,5,7-tetramethyladamantane
C
trans-Decalin
D
1-ethyladamantane
E
1,3,5-trimethyladamantane
1-methyl-adamantane
Conditions | Yield |
---|---|
With aluminium trichloride; tertiary butyl chloride at 160℃; for 15h; Product distribution; | A 8.98% B 7.37% C 7.47% D 2.04% E 13.24% F 1.59% |
isobutylcyclohexane
A
1,3-dimethyladamantane
B
1,3,5,7-tetramethyladamantane
C
trans-Decalin
D
1-ethyladamantane
E
1,3,5-trimethyladamantane
1-methyl-adamantane
Conditions | Yield |
---|---|
With aluminium trichloride; tertiary butyl chloride at 160℃; for 15h; Product distribution; | A 8.23% B 8.26% C 9.82% D 0.59% E 10.13% F 1.33% |
1-Adamantyl bromide
tetramethylsilane
A
1,3-dimethyladamantane
B
adamantane
1-methyl-adamantane
Conditions | Yield |
---|---|
With aluminium trichloride In dichloromethane at 20℃; for 0.166667h; Further byproducts given; | A 32 % Chromat. B 21 % Chromat. C 39 % Chromat. |
With aluminum tri-bromide In dichloromethane at 20℃; for 1h; Further byproducts given; | A 35 % Chromat. B 13 % Chromat. C 37 % Chromat. |
1-Adamantyl bromide
tetramethylsilane
A
1,3-dimethyladamantane
B
adamantane
C
1,3,5,7-tetramethyladamantane
D
1,3,5-trimethyladamantane
1-methyl-adamantane
Conditions | Yield |
---|---|
With aluminum tri-bromide In dichloromethane at 20℃; for 0.166667h; Product distribution; other time; various ratios of the educts and AlBr3; AlCl3 instead AlBr3; |
1-Adamantyl bromide
tetramethylsilane
A
1,3-dimethyladamantane
B
adamantane
C
1,3,5-trimethyladamantane
1-methyl-adamantane
Conditions | Yield |
---|---|
With aluminium trichloride In dichloromethane at 20℃; for 0.166667h; Yield given. Yields of byproduct given; |
1-Adamantyl bromide
tetramethylsilane
A
1,3-dimethyladamantane
B
1,3,5,7-tetramethyladamantane
C
1,3,5-trimethyladamantane
1-methyl-adamantane
Conditions | Yield |
---|---|
With aluminum tri-bromide In dichloromethane at 20℃; for 1h; Yield given. Further byproducts given. Yields of byproduct given; | |
With aluminum tri-bromide In dichloromethane at 40℃; for 1.5h; Yield given. Further byproducts given. Yields of byproduct given; |
Conditions | Yield |
---|---|
With magnesium 1.) n-butyl ether, 2.) n-butyl ether, 70 deg C; Yield given. Multistep reaction; |
tetramethylsilane
1-chloroadamantane
A
1,3-dimethyladamantane
B
adamantane
1-methyl-adamantane
Conditions | Yield |
---|---|
With aluminum tri-bromide In dichloromethane at 20℃; for 0.166667h; Further byproducts given; | A 37 % Chromat. B 12 % Chromat. C 38 % Chromat. |
With aluminum tri-bromide In dichloromethane at 20℃; for 1h; Further byproducts given; | A 35 % Chromat. B 12 % Chromat. C 34 % Chromat. |
tetramethylsilane
1-chloroadamantane
A
1,3-dimethyladamantane
B
adamantane
C
1,3,5,7-tetramethyladamantane
D
1,3,5-trimethyladamantane
1-methyl-adamantane
Conditions | Yield |
---|---|
With aluminum tri-bromide In dichloromethane at 20℃; for 0.166667h; Product distribution; other time; various ratios of the educts and AlBr3; |
tetramethylsilane
1-chloroadamantane
A
1,3-dimethyladamantane
B
1,3,5,7-tetramethyladamantane
C
1,3,5-trimethyladamantane
1-methyl-adamantane
Conditions | Yield |
---|---|
With aluminum tri-bromide In dichloromethane at 20℃; for 0.166667h; Yield given. Further byproducts given. Yields of byproduct given; | |
With aluminum tri-bromide In dichloromethane at 20℃; for 1h; Yield given. Further byproducts given. Yields of byproduct given; |
tetramethylsilane
adamantane
A
1,3-dimethyladamantane
1-methyl-adamantane
Conditions | Yield |
---|---|
With aluminum tri-bromide In dichloromethane at 20℃; for 3h; Yield given. Yields of byproduct given; |
tetramethylsilane
adamantane
A
1,3-dimethyladamantane
B
1,3,5,7-tetramethyladamantane
C
1,3,5-trimethyladamantane
1-methyl-adamantane
E
1,3,5-Trimethyl-7-ethyladamantane
F
1,2,3,5,7-pentamethyladamantane
Conditions | Yield |
---|---|
With aluminum tri-bromide In dichloromethane at 20℃; for 6h; Product distribution; other time; other temperature; AlCl3 instead AlBr3; |
tetramethylsilane
adamantane
A
1,3-dimethyladamantane
B
1,3,5-trimethyladamantane
1-methyl-adamantane
Conditions | Yield |
---|---|
With aluminum tri-bromide In dichloromethane at 20℃; for 6h; Yield given. Yields of byproduct given; |
1,3-dimethyladamantane
Conditions | Yield |
---|---|
With aluminum (III) chloride; phosphorus trichloride for 5h; Inert atmosphere; Reflux; | 99% |
1,3-dimethyladamantane
formamide
1-formamido-3,5-dimethyltricyclo[3.3.1.13,7]decane
Conditions | Yield |
---|---|
Stage #1: 1,3-dimethyladamantane With sulfuric acid; nitric acid at 20 - 25℃; for 6.5h; Stage #2: formamide at 30 - 35℃; for 3h; | 96.96% |
Stage #1: 1,3-dimethyladamantane With sulfuric acid; nitric acid at 0 - 5℃; Stage #2: formamide at 55 - 60℃; for 2h; Stage #3: With ammonia In dichloromethane; water at 0 - 25℃; | 95% |
Stage #1: 1,3-dimethyladamantane With sulfuric acid; nitric acid at 0℃; for 6h; Stage #2: formamide at 0 - 20℃; for 2.5h; Ritter-type reaction; Further stages.; | 89% |
Stage #1: 1,3-dimethyladamantane With sulfuric acid; nitric acid at 0℃; Stage #2: formamide at 0 - 20℃; | 89.3% |
Stage #1: 1,3-dimethyladamantane With sulfuric acid; nitric acid at 0℃; Stage #2: formamide at 0 - 20℃; for 2h; |
Conditions | Yield |
---|---|
Stage #1: 1,3-dimethyladamantane; trifluoroacetic acid With oxygen; sodium nitrite at 20℃; for 3h; Stage #2: With hydrogenchloride Further stages.; | 96% |
Conditions | Yield |
---|---|
In benzene at 23℃; Kinetics; | 96% |
Conditions | Yield |
---|---|
With water; bromine at 25℃; Reflux; | 95% |
With oxygen; cobalt acetylacetonate In acetic acid at 80℃; under 760.051 Torr; for 15h; | 90% |
With water; bromine for 2h; Ambient temperature; | 87% |
1,3-dimethyladamantane
bis(3,5-dimethyl-1-adamantyl)phosphinic chloride
Conditions | Yield |
---|---|
With aluminium trichloride; phosphorus trichloride at 75 - 85℃; for 5h; | 94.7% |
N-[(1S)-amino(4-tolyl)oxido-λ4-sulfanylidene]tosylamide
1,3-dimethyladamantane
(S)-N-[[(3,5-dimethyl-1-adamantyl)amino](4-tolyl)oxido-λ4-sulfanylidene]tosylamide
Conditions | Yield |
---|---|
With dirhodium tetrakis{(2S)-2-(1,3-dioxo-1H-benzo[de]isoquinolin-2(3H)-yl)propanoic acid}; bis(tertbutylcarbonyloxy)iodobenzene In methanol; 1,2-dichloro-ethane at -35℃; for 72h; Molecular sieve; diastereoselective reaction; | 94% |
Conditions | Yield |
---|---|
With aluminum (III) chloride; bromine In 1,2-dichloro-ethane at 15℃; Reagent/catalyst; Temperature; Solvent; | 92% |
With bromine for 12h; Reflux; | 91.5% |
With iron(III)-acetylacetonate; carbon tetrabromide at 150℃; for 3h; Sealed tube; Inert atmosphere; | 85% |
2-amino-3-pyridinecarbonitrile
1,3-dimethyladamantane
2-(((1r,3R,5S,7r)-3,5-dimethyladamantan-1-yl)amino)nicotinonitrile
Conditions | Yield |
---|---|
With aluminum tri-bromide; carbon tetrabromide In neat (no solvent) at 15 - 20℃; for 0.0833333h; Green chemistry; chemoselective reaction; | 92% |
1,3-dimethyladamantane
acetonitrile
1,3‑diacetamido‑5,7‑dimethyladamantane
Conditions | Yield |
---|---|
Stage #1: 1,3-dimethyladamantane With nitric acid at 25℃; for 1h; Stage #2: acetonitrile for 0.5h; Stage #3: acetonitrile With sulfuric acid at 20℃; for 4h; Ritter Amidation; | 92% |
Trifluoromethanesulfonamide
1,3-dimethyladamantane
N-((1,3,5,7)-3,5-dimethyladamantan-1-yl)-1,1,1-trifluoromethanesulfonamide
Conditions | Yield |
---|---|
With bis(4-bromobenzoyloxy)iodobenzene; iodine In dichloromethane at 20℃; for 14h; Schlenk technique; Inert atmosphere; Irradiation; | 92% |
methanol
1,3-dimethyladamantane
carbon monoxide
dimethyl 5,7-dimethyladamantane-1,3-dicarboxylate
Conditions | Yield |
---|---|
Stage #1: 1,3-dimethyladamantane; carbon monoxide With Al2Br7(1-)*CBr3(1+) In 1,2-dibromomethane at 0℃; under 760.051 Torr; for 3h; Stage #2: methanol In 1,2-dibromomethane at 0 - 20℃; chemoselective reaction; | 91% |
1,3-dimethyladamantane
3,5-dimethyladamantan-1-yl nitrate
Conditions | Yield |
---|---|
With nitric acid at 10℃; | 90.3% |
With nitric acid In acetic acid at 20℃; for 1h; | |
With nitric acid for 3h; Cooling; | |
With nitric acid In acetic acid at 15 - 20℃; for 1h; |
Conditions | Yield |
---|---|
Stage #1: 1,3-dimethyladamantane With sulfuric acid; nitric acid at 0℃; for 6h; Stage #2: acetonitrile at 0 - 20℃; for 3.5h; Ritter-type reaction; Further stages.; | 90.3% |
With sulfuric acid In tert-butyl alcohol at 60 - 65℃; for 18h; Ritter Amidation; Large scale; | 90% |
With sulfuric acid at 60 - 80℃; for 10h; Ritter Amidation; | 73.5% |
1,3-dimethyladamantane
1,3‑dibromo‑5,7‑dimethyladamantane
Conditions | Yield |
---|---|
With bromine; iron In 1,2-dichloro-ethane at 25℃; Temperature; Reagent/catalyst; Solvent; | 90% |
With bromine; iron at 20℃; for 1.5h; Bromination; | 83% |
formic acid
1,3-dimethyladamantane
5,7-dimethyl-1,3-adamantanedicarboxylic acid
Conditions | Yield |
---|---|
With sulfuric acid at 20 - 28℃; for 5h; | 90% |
1,2,3-Benzotriazole
1,3-dimethyladamantane
1-((1r,3R,5S,7r)-3,5-dimethyladamantan-1-yl)-1H-benzo[d][1,2,3]triazole
Conditions | Yield |
---|---|
With aluminum tri-bromide; carbon tetrabromide In neat (no solvent) at 15 - 20℃; for 0.0833333h; Green chemistry; chemoselective reaction; | 89% |
1,3-dimethyladamantane
anthranilic acid nitrile
2-(((1r,3R,5S,7r)-3,5-dimethyladamantan-1-yl)amino)benzonitrile
Conditions | Yield |
---|---|
With aluminum tri-bromide; carbon tetrabromide In neat (no solvent) at 15 - 20℃; for 0.0833333h; Green chemistry; chemoselective reaction; | 87% |
maleic anhydride
1,3-dimethyladamantane
3-(3,5-Dimethyl-adamantan-1-yl)-dihydro-furan-2,5-dione
Conditions | Yield |
---|---|
With di-tert-butyl peroxide In chlorobenzene at 150℃; for 5h; | 86% |
1,3-dimethyladamantane
1,3-difluoro-5,7-dimethyladamantane
Conditions | Yield |
---|---|
With iodine pentafluoride In 1,2-dichloro-ethane at 80℃; for 12h; regioselective reaction; | 86% |
1,3-dimethyladamantane
urethane
1-ethoxycarbonylamino-3,5-dimethyladamantane
Conditions | Yield |
---|---|
With nitric acid at 30℃; for 1h; | 85% |
With nitric acid 1.) 25 deg C, 15 min, 2.) RT, 1 h; Yield given. Multistep reaction; |
1,3-dimethyladamantane
1-fluoro-3,5-dimethyladamantane
Conditions | Yield |
---|---|
With iodine pentafluoride In dichloromethane at 10℃; for 12h; regioselective reaction; | 85% |
Conditions | Yield |
---|---|
With bis{rhodium[3,3'-(1,3-phenylene)bis(2,2-dimethylpropanoic acid)]}; [bis(acetoxy)iodo]benzene; sodium hydrogencarbonate for 2h; | 85% |
N-[(1S)-amino(4-tolyl)oxido-λ4-sulfanylidene]tosylamide
1,3-dimethyladamantane
Conditions | Yield |
---|---|
With Rh2(S-N-(1,8-naphthoyl)alanine)4; bis(tertbutylcarbonyloxy)iodobenzene In methanol; 1,1,2,2-tetrachloroethane at -78 - -35℃; for 72h; Molecular sieve; Inert atmosphere; | 83% |
Conditions | Yield |
---|---|
With bis{rhodium[3,3'-(1,3-phenylene)bis(2,2-dimethylpropanoic acid)]}; [bis(acetoxy)iodo]benzene; sodium hydrogencarbonate for 2.5h; | 81% |
Conditions | Yield |
---|---|
With bis{rhodium[3,3'-(1,3-phenylene)bis(2,2-dimethylpropanoic acid)]}; [bis(acetoxy)iodo]benzene; sodium hydrogencarbonate for 2.5h; | 80% |
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