101532-23-4

Basic information

• Product Name: propynyl 4-methoxybenzoate
• Synonyms: propynyl 4-methoxybenzoate;2-propyn-1-yl 4-methoxybenzoate
• CAS NO: 101532-23-4
• Molecular Formula: C₁₁H₁₀O₃
• Molecular Weight: 190.2
• Mol File: 101532-23-4.mol
• Article Data: 23

Chemical Properties

• Boiling Point: 309.6°Cat760mmHg
• Flash Point: 126.4°C
• Appearance: /
• Density: 1.131g/cm³
• Vapor Pressure: 0.000632mmHg at 25°C
• Refractive Index: 1.528
• CAS DataBase Reference: propynyl 4-methoxybenzoate(CAS DataBase Reference)
• NIST Chemistry Reference: propynyl 4-methoxybenzoate(101532-23-4)
• EPA Substance Registry System: propynyl 4-methoxybenzoate(101532-23-4)

Safety Data

• Hazardous Substances Data: 101532-23-4(Hazardous Substances Data)

Usage

InChI:InChI=1/C11H10O3/c1-3-8-14-11(12)9-4-6-10(13-2)7-5-9/h1,4-7H,8H2,2H3

Upstream product

• 107-19-7 propargyl alcohol 
• 100-09-4 4-methoxybenzoic acid 
• 123-11-5 4-methoxy-benzaldehyde 
• 1236063-60-7 2-bromoallyl 4-methoxybenzoate 
• 99859-53-7 4-methoxy-benzoic acid-(2,3-dibromo-propyl ester) 
• 6712-20-5 2-(4-methoxyphenyl)-[1,3]dithiolane 
• 100-07-2 4-methoxy-benzoyl chloride 
• 106-96-7 propargyl bromide 
• 201230-82-2 carbon monoxide 
• 459-64-3 4-methoxybenzenediazonium tetrafluoroborate 
• 6941-68-0 allyl 4-methoxybenzoate 
• 696-62-8 para-iodoanisole 

Downstream Products

• 100-09-4 4-methoxybenzoic acid 
• 82225-33-0 4-methoxy-N-(prop-2-yn-1-yl)benzamide 
• 200411-41-2 4-methoxy-N-methyl-N-(prop-2-yn-1-yl)benzamide 
• 750624-40-9 4-hydroxy-N-(prop-2-ynyl)benzamide 
• 888328-53-8 (4-methoxy-C₆H₄)C(O)OCH₂C(phenyl)CHSn(butyl)3 
• 1240483-52-6 1,4,5,6,7,7-hexachlorobicyclo[2.2.1]hepta-2,5-dien-2-ylmethyl 4-methoxybenzoate 
• 1236835-57-6 C₁₈H₁₆Cl₄O₅ 
• 1421060-32-3 (3,3-dimethyl-3H-pyrazol-5-yl)methyl 4-methoxybenzoate 
• 1567324-87-1 (1-(7-chloroquinolin-4-yl)-1H-1,2,3-triazol-4-yl)methyl-4-(methoxy) benzoate 
• 1613140-76-3 benzyl 3β-{2-[4-(4-methoxybenzoyloxy)methyl-1H-1,2,3-triazol-1-yl]acetoxy}olean-12-en-28-oate 
• 1613140-78-5 3β-{2-[4-(4-methoxybenzoyloxy)methyl-1H-1,2,3-triazol-1-yl]acetoxy}olean-12-en-28-oic acid 
• 101395-49-7 2-oxopropyl 4-methoxybenzoate 

Relevant articles and documents

Synthesis, antimicrobial activity, and QSAR studies of amide-ester linked 1,4-disubstituted 1,2,3-triazoles

Abstract: Synthesis of some amide-ester linked 1,4-disubstituted 1,2,3-triazoles was carried out by employing copper(I)-catalyzed 1,3-dipolar cycloaddition of 2-azido-N-substituted acetamides and benzoic acid prop-2-ynyl esters. All the synthesized 28 1,4-disubstituted 1,2,3-triazoles are new. The synthesized triazoles were characterized by IR, 1H NMR, 13C NMR, HRMS and evaluated for their antimicrobial activity against Staphylococcus aureus, Bacillus subtilis, Escherichia coli, Candida albicans, and Aspergillus niger. Compounds displaying potent antimicrobial activity against each of these microorganisms were found. Quantitative structure activity relationship studies for the synthesized compounds were also carried out to check the effect of various substituents in parent compound on antimicrobial activity. Graphical abstract: [Figure not available: see fulltext.]

Synthesis, characterization, and antimicrobial potential of some 1,4-disubstituted 1,2,3-bistriazoles

A convenient synthesis of some new 1,4-disubstituted 1,2,3-bistriazoles (3a-3f, 4a-4f, 6a-6b, 7a-7b) is reported via copper(I)-catalyzed Huisgen 1,3-dipolar cycloaddition of various terminal alkynes with 1,4-bis(azidomethyl)benzene and 1,6-diazidohexane.

Synthesis of Cyclopenta[b]indoles via a Formal [3+2] Cyclization of N-Sulfonyl-1,2,3-triazoles and Indoles

Annulation of benzoxy-tethered N-sulfonyl-1,2,3-triazoles and indoles has been developed in this paper, providing an efficient and convenient access to valuable cyclopenta[b]indoles in moderate to good yields. α,β-Unsaturated imine, which generated in situ from denitrogenation and 1,2-OBz migration of triazole, provided three carbons for the formal [3+2] cyclization reaction for the first time. (Figure presented.).

Tris(2,4,6-trifluorophenyl)borane: An Efficient Hydroboration Catalyst

The metal-free catalyst tris(2,4,6-trifluorophenyl)borane has demonstrated its extensive applications in the 1,2-hydroboration of numerous unsaturated reagents, namely alkynes, aldehydes and imines, consisting of a wide array of electron-withdrawing and donating functionalities. A range of over 50 borylated products are reported, with many reactions proceeding with low catalyst loading under ambient conditions. These pinacol boronate esters, in the case of aldehydes and imines, can be readily hydrolyzed to leave the respective alcohol and amine, whereas alkynyl substrates result in vinyl boranes. This is of great synthetic use to the organic chemist.