101694-79-5

Basic information

• Product Name: (-)-menthyl (1'R,2S)-2-benzoylamino-2-(4-oxotetrahydrothiopyran-3-yl)acetate
• CAS NO: 101694-79-5
• Molecular Weight: 431.596
• Mol File: 101694-79-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (-)-menthyl (1'R,2S)-2-benzoylamino-2-(4-oxotetrahydrothiopyran-3-yl)acetate(CAS DataBase Reference)
• NIST Chemistry Reference: (-)-menthyl (1'R,2S)-2-benzoylamino-2-(4-oxotetrahydrothiopyran-3-yl)acetate(101694-79-5)
• EPA Substance Registry System: (-)-menthyl (1'R,2S)-2-benzoylamino-2-(4-oxotetrahydrothiopyran-3-yl)acetate(101694-79-5)

Safety Data

• Hazardous Substances Data: 101694-79-5(Hazardous Substances Data)

Upstream product

• 93273-86-0 (-)-menthyl-2-benzoylamoniacetate 
• 2216-51-5 (-)-menthol 
• 495-69-2 Hippuric Acid 
• 1072-72-6 Tetrahydrothiopyran-4-one 
• 101649-96-1 (S)-4-(2-methoxymethyl)pyrrolidino-5,6-dihydro-2H-thiopyran 
• 101649-84-7 (-)-menthyl 2-benzoylamino-2-bromoacetate 

Relevant articles and documents

SYNTHESIS OF DIASTEREO- AND ENANTIOMERICALLY PURE α-AMINO-γ-OXO ACID ESTERS BY REACTION OF ACYLIMINOACETATES WITH ENAMINES DERIVED FROM 6-MEMBERED KETONES

A new efficient diastereo- and enantioselective synthesis of α-amino-γ-oxo acid esters by reaction of acyliminoacetates with enamines is described.By employing the concept of double stereodifferentiation, complete asymmetric induction (de=ee >/= 99.9 percent) for the C-C bond formation is obtained.Desulphurization of a sulphur containing product leads to the corresponding acyclic amino acid derivatives.The virtually complete anti-diastereo- and enantioselectivities are interpreted by a Diels-Alder like transition state.