1033-71-2

Basic information

• Product Name: Hydrazine, 1,2-bis(2-ethoxyphenyl)-
• CAS NO: 1033-71-2
• Molecular Formula: C16H20N2O2
• Molecular Weight: 272.347
• Mol File: 1033-71-2.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Hydrazine, 1,2-bis(2-ethoxyphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Hydrazine, 1,2-bis(2-ethoxyphenyl)-(1033-71-2)
• EPA Substance Registry System: Hydrazine, 1,2-bis(2-ethoxyphenyl)-(1033-71-2)

Safety Data

• Hazardous Substances Data: 1033-71-2(Hazardous Substances Data)

Upstream product

• 88-73-3 2-Chloronitrobenzene 
• 613-43-4 2,2'-diethoxyazobenzene 
• 62167-96-8 bis-(2-ethoxy-phenyl)-diazene-N-oxide 
• 610-67-3 1-ethoxy-2-nitrobenzene 

Downstream Products

• 613-43-4 2,2'-diethoxyazobenzene 
• 6264-77-3 4,4'-diamino-3,3'-diethoxybiphenyl 

Relevant articles and documents

Facile, product-selective reduction of azoxyarenes into azoarenes or hydrazoarenes by aluminium/hydrazine hydrate

Azoxyarenes, on treatment with hydrazine hydrate in presence of aluminium powder in methanol, undergo reduction. The reactions have been carried under microwave irradiation as well at reflux to get the corresponding hydrazoarenes and azoarenes as reduced products. The reaction is very fast, which gives excellent yield of the product. Substituents such as OCH3, OC 2H5, and Cl are unaffected. Copyright Taylor & Francis, Inc.

Mg/Triethylammonium formate: A useful system for reductive dimerization of araldehydes into pinacols; Nitroarenes into azoarenes and azoarenes into hydrazoarenes

Studies are reported which describes the effectiveness of triethylammonium formate in the presence of magnesium for the efficient intermolecular pinacol coupling using MeOH as solvent, Various aromatic carbonyls underwent smooth reductive coupling to give the corresponding I ,2-diols. A series of azo compounds were obtained by the reductive coupling of nitroaromatics while azo compounds were reduced to the corresponding hydrazoarenes by this system. There was no adverse effect on the other reducible and hydrogenolysable groups such as ether linkage, hydroxy and halogens. The reactions are clean, high yielding and inexpensive. All the reactions proceeded smoothly at ambient temperature.

A facile reduction of azoxyarenes with hydrazine hydrate/magnesium: Formation of different products under different reaction conditions

Azoxyarenes on treatment with hydrazine hydrate in presence of magnesium turnings in methanol undergo reduction. The reactions have been carried under microwave irradiation as well as at reflux to give the corresponding hydrazoarenes and azoarenes as reduced products. The reactions are very fast and give excellent yields of the products. Substituents like OCH3, OC2H5 and Cl are unaffected.