10557-03-6

Basic information

• Product Name: Methanamine, N-(1-phenylethylidene)-, N-oxide
• CAS NO: 10557-03-6
• Molecular Formula: C9H11NO
• Molecular Weight: 149.192
• Mol File: 10557-03-6.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Methanamine, N-(1-phenylethylidene)-, N-oxide(CAS DataBase Reference)
• NIST Chemistry Reference: Methanamine, N-(1-phenylethylidene)-, N-oxide(10557-03-6)
• EPA Substance Registry System: Methanamine, N-(1-phenylethylidene)-, N-oxide(10557-03-6)

Safety Data

• Hazardous Substances Data: 10557-03-6(Hazardous Substances Data)

Upstream product

• 613-91-2 acetophenone oxime 
• 64-17-5 ethanol 
• 74-88-4 methyl iodide 
• 124-41-4 sodium methylate 
• 4229-44-1 N-methylhydroxyamine hydrochloride 
• 536-74-3 phenylacetylene 
• 98-86-2 acetophenone 
• 77-78-1 dimethyl sulfate 
• 64948-39-6 C₁₁H₁₇NOSi 
• 420-37-1 trimethoxonium tetrafluoroborate 
• 4316-37-4 1,1,-diethoxy-1-phenylethane 

Downstream Products

• 3376-23-6 C-phenyl-N-methylnitrone 
• 909900-42-1 C₂₅H₂₉NOSi 
• 39626-50-1 (E) ethyl 2-benzoyl-3-methyl-cinnamate 
• 39626-49-8 (Z) ethyl 2-benzoyl-3-methyl-cinnamate 
• 139286-59-2 2,3-dimethyl-3-phenyl-4-ethoxycarbonyl-4-isoxazoline 
• 139286-69-4 2,3-dimethyl-3-phenyl-4-ethoxycarbonyl-4-isoxazoline 
• 139286-60-5 2,3-dimethyl-3,5-diphenyl-4-ethoxycarbonyl-4-isoxazoline 
• 65708-59-0 2,3-dimethyl-3-phenyl-isoxazolidin-5-one 
• 593-77-1 N-Methylhydroxylamine 
• 98-86-2 acetophenone 

Relevant articles and documents

Enantioselective Synthesis of Cα-Tetrasubstituted N-Hydroxyl-α-amino Nitriles via Cyanation of Ketonitrones Using Me2(CH2Cl)SiCN

Here, we report an unprecedented catalytic enantioselective cyanation of ketonitrones enabled by the bifunctional cyanating reagent Me2(CH2Cl)SiCN. This approach allows facile access to optically active N-hydroxyl-α-amino nitriles that are of high synthet

Synthesis of Novel N-methanamine

The synthesis and configurational purity of a series of novel N-methanamine N-oxides 9a-q and 10a, b is reported.Directly after the synthesis, ketonitrones 9, 10 were found to exist exclusively in the (E) form, although

A CONVENIENT SYNTHESIS OF NITRONES BY N-ALKYLATION OF O-TRIMETHYLSILYLOXIMES

Aldoxime and ketoxime-O-trimethylsilyl ethers can be alkylated with trialkyl-oxonium tetrafluoroborates and alkyl triflates at or below room temperature to produce nitrones in good yields.