4316-37-4

Basic information

• Product Name: Acetophenone diethyl ketal
• Synonyms: Acetophenone diethyl ketal;Benzene, (1,1-diethoxyethyl)-
• CAS NO: 4316-37-4
• Molecular Formula: C₁₂H₁₈O₂
• Molecular Weight: 194.27012
• Mol File: 4316-37-4.mol
• Article Data: 31

Chemical Properties

• Boiling Point: 231.7°Cat760mmHg
• Flash Point: 71.2°C
• Appearance: /
• Density: 0.962g/cm³
• Vapor Pressure: 0.0934mmHg at 25°C
• Refractive Index: 1.48
• CAS DataBase Reference: Acetophenone diethyl ketal(CAS DataBase Reference)
• NIST Chemistry Reference: Acetophenone diethyl ketal(4316-37-4)
• EPA Substance Registry System: Acetophenone diethyl ketal(4316-37-4)

Safety Data

• Hazardous Substances Data: 4316-37-4(Hazardous Substances Data)

Usage

InChI:InChI=1/C12H18O2/c1-4-13-12(3,14-5-2)11-9-7-6-8-10-11/h6-10H,4-5H2,1-3H3

Upstream product

• 64-17-5 ethanol 
• 24154-16-3 α,α‐dibromoethybenzene 
• 141-52-6 sodium ethanolate 
• 122-51-0 orthoformic acid triethyl ester 
• 98-86-2 acetophenone 
• 16694-46-5 ethyl formimidate hydrochloride 
• 536-74-3 phenylacetylene 
• 7647-01-0 hydrogenchloride 
• 5684-32-2 2-methyl-2-phenyl-[1,3]oxathiolane 
• 6230-62-2 (1-ethoxyvinyl)benzene 
• 2914-19-4 barium diethanolate 
• 100-52-7 benzaldehyde 
• 78-39-7 Triethyl orthoacetate 

Downstream Products

• 6230-62-2 (1-ethoxyvinyl)benzene 
• 120810-61-9 (E)-N-(1-phenylethylidene)pyridin-2-amine 
• 4105-21-9 2-phenylimidazo[1,2-a]pyridine 
• 2288-18-8 2-phenyl-1,3-butadiene 
• 110802-16-9 4-hydroxy-7-chloro-2-phenylquinoline 
• 10557-03-6 (Z)-N-(1-phenylethylidene)methanamine N-oxide 
• 64-17-5 ethanol 
• 612-71-5 1,3,5-triphenylbenzene 
• 3299-05-6 1-ethoxy-1-phenylethane 
• 57818-33-4 N-ethyl-N-(1-phenylethenyl)aniline 
• 130597-97-6 (E)-4-(N,N-dimethylamino)-N-(1-phenylethylidene)aniline 
• 101448-09-3 1,1,3-triethoxy-3-phenylbutane 
• 109559-33-3 5-ethoxy-5-phenyl-hex-2-enal-diethylacetal 
• 102315-16-2 (+/-)-7-ethoxy-7-phenyl-octa-2ξ,4ξ-dienal-diethylacetal 

Relevant articles and documents

Conjugate addition of acetal-derived benzyl radicals generated from low-valent titanium-mediated CO bond cleavage

A new method for the generation of benzyl radicals from acetals via low-valent titanium-mediated homolytic CO bond cleavage is presented. The low cost and availability of the developed titanium reagent enable efficient access to α-alkoxy carbon radical species via the developed reaction.

A fluorinated cobalt(III) porphyrin complex for hydroalkoxylation of alkynes

A fluorinated cobalt(III) porphyrin complex [Co(TPFPP)-NTf2·2C2H5OH, where TPFPP=5,10,15,20-tetrakis(penta-fluorophenyl)porphyrin, Tf=CF3SO2] promotes hydroalkoxylation of alkynes to give acetals in good to excellent yields. The acetals can be directly functionalized with nucleophiles in a one-pot procedure.

Precursor and solvent effects in the nonhydrolytic synthesis of complex oxide nanoparticles for bioimaging applications by the ether elimination (Bradley) reaction

Investigation of the solvent and alkoxide precursor effect on the nonhydrolytic sol-gel synthesis of oxide nanoparticles by means of an ether elimination (Bradley) reaction indicates that the best crystallinity of the resulting oxide particles is achieved