1075252-15-1Relevant articles and documents
Efficient RAFT polymerization of N-(3-aminopropyl)methacrylamide hydrochloride using unprotected "clickable" chain transfer agents
Mendon?a, Patrícia V.,Serra, Arménio C.,Popov, Anatoliy V.,Guliashvili, Tamaz,Coelho, Jorge F.J.
, p. 1 - 7 (2014)
The reversible addition fragmentation chain transfer (RAFT) of N-(3-aminopropyl)methacrylamide hydrochloride (APMA) using unprotected "clickable" chain transfer agents in water/dioxane mixtures is reported. The controlled character of the polymerization was confirmed by the linear increase of the polymer molecular weight with monomer conversion, the narrow molecular weight distribution (≤ 1.1) and by chain extension experiments. The alkyne-terminated PAPMA was further functionalized by "click" chemistry with an azido-functionalized coumarin derivative. The method reported here will be useful for the preparation of novel PAPMA based materials for biomedical applications using a strategy that does not require challenging protection/deprotection steps.
Synthesis of block copolymer brush by RAFT and click chemistry and its self-assembly as a thin film
Bouyer, Denis,Chang, Yung,Li, Suming,Quemener, Damien,Semsarilar, Mona,Thankappan, Hajeeth
, (2020)
A well-defined block copolymer brush poly(glycidyl methacrylate)-graft-(poly(methyl methacrylate)-block-poly(oligo(ethylene glycol) methyl ether methacrylate)) (PGMA-g-(PMMA-b-POEGMA)) is synthesized via grafting from an approach based on a combination of
High density cationic polymer brushes from combined "click chemistry" and RAFT-mediated polymerization
Demirci, Serkan,Caykara, Tuncer
, p. 2999 - 3007 (2012)
A simple method for preparing cationic poly[(ar-vinylbenzyl) trimethylammonium chloride)] [poly(VBTAC)] brushes was used by combined technology of "click chemistry" and reversible addition-fragmentation chain transfer (RAFT) polymerization. Initially, sil
