107536-32-3

Basic information

• Product Name: tris(4-methylphenyl)bismuth diacetate
• Synonyms: tris(4-methylphenyl)bismuth diacetate
• CAS NO: 107536-32-3
• Molecular Weight: 600.467
• Mol File: 107536-32-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: tris(4-methylphenyl)bismuth diacetate(CAS DataBase Reference)
• NIST Chemistry Reference: tris(4-methylphenyl)bismuth diacetate(107536-32-3)
• EPA Substance Registry System: tris(4-methylphenyl)bismuth diacetate(107536-32-3)

Safety Data

• Hazardous Substances Data: 107536-32-3(Hazardous Substances Data)

Upstream product

• 858520-08-8 μ-oxobis[(2,4-dimethylbenzenesulfonato)tri-p-tolylbismuth] 
• 127-09-3 sodium acetate 
• 121882-74-4 tris(p‐tolyl)bismuth dibromide 
• 301-04-2 lead acetate 
• 5142-75-6 tri(p-tolyl)bismuth 
• 858520-14-6 p-Tol₃Bi(OSO₂C₆H₃Me₂-2,4)2 
• 532-31-0 silver benzoate 
• 6729-64-2 tri(p-tolyl)bismuth dichloride 
• 532-32-1 sodium benzoate 

Downstream Products

• 73791-19-2 4-hydroxy-3-(p-tolyl)-1-benzopyran-2-one 
• 121884-66-0 4-hydroxy-7-methoxy-3-p-tolylcoumarin 
• 104-93-8 p-methylanizole 
• 64-19-7 acetic acid 
• 108-88-3 toluene 
• 10519-06-9 1-butoxy-4-methylbenzene 
• 773893-07-5 tert-butyl 2-(4-methylphenyl)azocarboxylate 
• 93138-89-7 tert-butyl 2-(p-tolyl)hydrazine-1-carboxylate 
• 155890-16-7 (C₆H₄CH₃)3Bi(CF₃COO)2 
• 192327-41-6 di(O,O-tropolonato)tri(p-tolyl)bismuth(V) 
• 5142-75-6 tri(p-tolyl)bismuth 
• 1370712-59-6 C₁₈H₂₀O₃ 
• 16939-04-1 2-p-tolylthiophene 
• 17113-32-5 2-(4-methylphenyl)furan 

Relevant articles and documents

Unexpected Formation of Triarylbismuth Diformates in the Oxidation of Triarylbismuthines with Ozone at Low Temperatures

Oxidation of triphenylbismuthine 1 with ozone in toluene at -78 deg C gave, unexpectedly, a high yield of triphenylbismuth diformate 3, which was also obtainable as a minor product by a similar oxidation in ethyl acetate and acetone.An X-ray crystallographic study revealed that compound 3 has C2 symmetry, the geometry around the bismuth atom being best described as a distorted trigonal bipyramid as a result of strong intramolecular interaction between the bismuth and carbonyl oxygen atoms.Treatment of compound 3 with aqueous sodium acetate or halides readily converted it into the corresponding triphenylbismuth diacetate 5 or dihalides 7 - 9.