113452-33-8

Basic information

• Product Name: {(PS,3R,4R,P'R)-3,4-bis(benzylphenylphosphino)-1-(tert-butoxycarbonyl)pyrrolidine-P,P'}diiodopalladium
• Synonyms: {(PS,3R,4R,P'R)-3,4-bis(benzylphenylphosphino)-1-(tert-butoxycarbonyl)pyrrolidine-P,P'}diiodopalladium
• CAS NO: 113452-33-8
• Molecular Weight: 927.877
• Mol File: 113452-33-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: {(PS,3R,4R,P'R)-3,4-bis(benzylphenylphosphino)-1-(tert-butoxycarbonyl)pyrrolidine-P,P'}diiodopalladium(CAS DataBase Reference)
• NIST Chemistry Reference: {(PS,3R,4R,P'R)-3,4-bis(benzylphenylphosphino)-1-(tert-butoxycarbonyl)pyrrolidine-P,P'}diiodopalladium(113452-33-8)
• EPA Substance Registry System: {(PS,3R,4R,P'R)-3,4-bis(benzylphenylphosphino)-1-(tert-butoxycarbonyl)pyrrolidine-P,P'}diiodopalladium(113452-33-8)

Safety Data

• Hazardous Substances Data: 113452-33-8(Hazardous Substances Data)

Upstream product

• 12107-56-1 dichloro(cycloocta-1,5-diene)palladium (II) 
• 113474-67-2 (PR,3R,4R,P'S)-3,4-bis(benzylphenylphosphino)-1-(tert-butoxycarbonyl)pyrrolidine 
• 7681-82-5 sodium iodide 
• 139609-61-3 {PS,3R,4R,P'S}-3,4-bis-((benzyl)phenylphosphanyl)-1-(t-butoxycarbonyl)pyrrolidine 
• 139609-60-2 {PR,3R,4R,P'R}-3,4-bis-((benzyl)phenylphosphanyl)-1-(t-butoxycarbonyl)pyrrolidine 
• 7790-38-7 palladium(II) iodide 

Downstream Products

• 7440-05-3 palladium 

Relevant articles and documents

Enantioselective Catalysis, VIII. - New 1,2-Bisphosphane Ligands with Four Stereogenic Centers and Additional Methoxy Groups for Asymmetric Catalytic Hydrogenation

The synthesis of N-acyl derivatives of all possible diastereomers of -3,4-bispyrrolidine and -3,4-bispyrrolidine in optical pure form is described.Palladium and rhodium complexes with these ligands were prepared.The enantioselective hydrogenation of acetamidocinnamic acid with these rhodium complexes was studied at H2 pressures between 1 and 75 bar.There is only a small influence of the 2-methoxy group in the ligand on the catalytic hydrogenation when compared with the respective unsubstituted diastereomer.Te structure of pyrrolidine-P,P'>diiodopalladium was determined by X-ray diffraction.Key Words: 3,4-Bis(phosphanyl)pyrrolidines / Palladium complexes / Rhodium complexes / Asymmetric hydrogenation