1178513-99-9

Basic information

• Product Name: 2’-deuteriol-phenylnaphthalen-2-ol
• Synonyms: 2’-deuteriol-phenylnaphthalen-2-ol
• CAS NO: 1178513-99-9
• Molecular Weight: 221.263
• Mol File: 1178513-99-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2’-deuteriol-phenylnaphthalen-2-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 2’-deuteriol-phenylnaphthalen-2-ol(1178513-99-9)
• EPA Substance Registry System: 2’-deuteriol-phenylnaphthalen-2-ol(1178513-99-9)

Safety Data

• Hazardous Substances Data: 1178513-99-9(Hazardous Substances Data)

Upstream product

• 142095-77-0 1-(2-bromophenyl)naphthalen-2-ol 
• 1178513-94-4 5-tert-butyl-5-phenyl-5H-benzo[c]naphtho[1,2-e][1,2]oxasiline 

Relevant articles and documents

RuII-catalyzed vinylative dearomatization of naphthols via a C(sp2)-H bond activation approach

Intermolecular annulation reactions of 1-aryl-2-naphthols with internal alkynes proceed efficiently in the presence of a Ru catalyst and a Cu oxidant to generate spirocyclic compounds by sequential cleavage of the C(sp 2)-H bond, migratory insertion of the alkyne, and dearomatization of the naphthyl ring. Various spirocyclic molecules bearing an all-carbon quaternary stereocenter could be obtained by this novel method with good yields and excellent regioselectivity, and the current process tolerates a variety of synthetically important functional groups.