142095-77-0

Basic information

• Product Name: 2-Naphthalenol, 1-(2-bromophenyl)-
• CAS NO: 142095-77-0
• Molecular Formula: C16H11BrO
• Molecular Weight: 299.167
• Mol File: 142095-77-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-Naphthalenol, 1-(2-bromophenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Naphthalenol, 1-(2-bromophenyl)-(142095-77-0)
• EPA Substance Registry System: 2-Naphthalenol, 1-(2-bromophenyl)-(142095-77-0)

Safety Data

• Hazardous Substances Data: 142095-77-0(Hazardous Substances Data)

Upstream product

• 583-55-1 1-Bromo-2-iodobenzene 
• 15147-55-4 2-naphtholate 
• 104116-17-8 2-methoxynaphthalene-1-boronic acid 
• 1432486-44-6 1-(2-bromophenyl)-2-methoxynaphthalene 
• 135-19-3 β-naphthol 

Downstream Products

• 205-39-0 benzo[b]naphtho[1,2-d]furan 
• 1178513-99-9 2’-deuteriol-phenylnaphthalen-2-ol 

Relevant articles and documents

Pd(0)-catalyzed chemoselective construction of spirocarbocycles via an alkyne insertion/β-naphthol dearomatization cascade

A microwave-assisted Pd(0)-catalyzed alkyne migratory insertion/β-naphthol dearomatization cascade process has been accomplished to access a variety of spirocyclic compounds bearing all-carbon quaternary stereogenic centers in high yields with excellent chemoselectivities.

The reactivity of oxygen nucleophiles with aryl radicals in the S(RN)1 mechanism

The photostimulated reaction of 2-naphthoxide ions 1 with o-dihalobenzenes in liquid ammonia gives the halosubstituted product 4 and the cyclized substituted product 5. This is the first report about the coupling of an aromatic σ radical with an oxygen functionality in the chain propagation cycle of the S(RN)1 mechanism.