1214320-65-6

Basic information

• Product Name: (E)-triethyl(4-(4-fluorophenyl)but-1-enyl)silane
• CAS NO: 1214320-65-6
• Molecular Weight: 264.458
• Mol File: 1214320-65-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-triethyl(4-(4-fluorophenyl)but-1-enyl)silane(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-triethyl(4-(4-fluorophenyl)but-1-enyl)silane(1214320-65-6)
• EPA Substance Registry System: (E)-triethyl(4-(4-fluorophenyl)but-1-enyl)silane(1214320-65-6)

Safety Data

• Hazardous Substances Data: 1214320-65-6(Hazardous Substances Data)

Upstream product

• 617-86-7 triethylsilane 
• 2248-13-7 1-(but-3-en-1-yl)-4-fluorobenzene 

Relevant articles and documents

Iridium-catalyzed (Z)-trialkylsilylation of terminal olefins

(Chemical equation presented) A complex of commercial [Ir(OMe)(cod)] 2 and 4,4-di-tert-butyl-2,2-bipyridine (dtbpy) catalyzes the Z-selective, dehydrative silylation of terminal alkenes, but not 1,2-disubstituted alkenes, with triethylsilane or benzyldimethylsilane in THF at 40 °C. Yields and Z-stereoselectivity were significantly improved by 2-norbornene, in contrast with other sacrificial alkenes. The reaction is compatible with many functional groups including epoxides, ketones, amides, alcohols, esters, halides, ketals, and silanes. α, β-Unsaturated esters were unreactive. The reaction probably proceeds through a Heck-type mechanism.