123027-99-6

Basic information

• Product Name: 2'-Bromo-5'-methoxyacetanilide
• Synonyms: 2'-Bromo-5'-methoxyacetanilide
• CAS NO: 123027-99-6
• Molecular Formula: C₉H₁₀BrNO₂
• Molecular Weight: 244.09
• Product Categories: Anilines, Amides & Amines;Anisoles, Alkyloxy Compounds & Phenylacetates;Bromine Compounds
• Mol File: 123027-99-6.mol
• Article Data: 6

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2'-Bromo-5'-methoxyacetanilide(CAS DataBase Reference)
• NIST Chemistry Reference: 2'-Bromo-5'-methoxyacetanilide(123027-99-6)
• EPA Substance Registry System: 2'-Bromo-5'-methoxyacetanilide(123027-99-6)

Safety Data

• Hazardous Substances Data: 123027-99-6(Hazardous Substances Data)

Upstream product

• 59557-92-5 2-bromo-5-methoxyaniline 
• 108-24-7 acetic anhydride 
• 75-36-5 acetyl chloride 
• 5344-78-5 4-bromo-3-nitroanizole 
• 96-96-8 4-methoxy-2-nitroaniline 
• 64-19-7 acetic acid 
• 577-72-0 4-methoxy-3-nitroaniline 

Downstream Products

• 143879-46-3 5-methoxy-2-styrylacetanilide 
• 126759-54-4 2-ethenyl-5-methoxyacetanilide 
• 123028-10-4 N-acetyl-2-pentyn-1-yl-5-methoxyaniline 
• 123028-13-7 N-acetyl-2-(phenylethynyl)-5-methoxyaniline 
• 123028-12-6 N-acetyl-2-hexyn-1-yl-5-methoxyaniline 
• 123028-11-5 N-acetyl-2-(3-methylbutyn-1-yl)-5-methoxyaniline 
• 444995-66-8 N-(2-bromo-5-methoxy-phenyl)-thioacetamide 
• 50591-24-7 1,2-dimethyl-5-methoxybenzimidazole 
• 111055-39-1 1-Benzyl-5-methoxy-2-methyl-1H-benzimidazole 
• 444995-74-8 N-(2-bromo-5-methoxy-phenyl)-N'-methyl-acetamidine 
• 444995-75-9 N-benzyl-N'-(2-bromo-5-methoxy-phenyl)-acetamidine 
• 143879-55-4 1-N-acetyl-6-methoxy-2-phenyl-3-(phenylseleno)indole 
• 2941-69-7 5-methoxy-2-methylbenzo[d]thiazole 
• 61822-18-2 2,7-dimethoxycarbazole 

Relevant articles and documents

A synthetic approach to carbazoles using electrochemically generated hypervalent iodine oxidant

Carbazoles were successfully synthesized by oxidative cyclization of the corresponding diaryl derivatives using electrochemically generated hypervalent iodine oxidant. Electron-withdrawing nitro and donating methoxy groups at the para position of the acetamide group interfered with cyclization. Glycozoline (8) was successfully synthesized in five steps with 50% overall yield.

Iridium-catalyzed intramolecular C–N and C–O/S cross-coupling reactions: Preparation of benzoazole derivatives

The irdium-catalyzed intramolecular arylcarbon-hetero cross-coupling reactions with o-haloarylamides or o-haloarylamidine have been effectively achieved using KOAc and just 1 mol% catalyst. The [Ir(cod)Cl]2 was proved to be more potential for smoothly assembling functional structures benzimidazoles, benzoxazoles and benzothiazoles, which was superior to Cu- and Pd-catalyzed systems. Simultaneously, a concise and efficient synthesis of tafamidis was developed in 5-g scale.

An intramolecular palladium-catalysed aryl amination reaction to produce benzimidazoles

A novel synthesis of benzimidazoles by a palladium-catalysed intramolecular N-arylation reaction from (o-bromophenyl)amidine precursors is described.