1239569-26-6

Basic information

• Product Name: 2-(2-(benzyloxy)phenyl)-5,5-dimethyl-1,3,2-dioxaborinane
• Synonyms: 2-(2-(benzyloxy)phenyl)-5,5-dimethyl-1,3,2-dioxaborinane
• CAS NO: 1239569-26-6
• Molecular Weight: 296.174
• Mol File: 1239569-26-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-(2-(benzyloxy)phenyl)-5,5-dimethyl-1,3,2-dioxaborinane(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(2-(benzyloxy)phenyl)-5,5-dimethyl-1,3,2-dioxaborinane(1239569-26-6)
• EPA Substance Registry System: 2-(2-(benzyloxy)phenyl)-5,5-dimethyl-1,3,2-dioxaborinane(1239569-26-6)

Safety Data

• Hazardous Substances Data: 1239569-26-6(Hazardous Substances Data)

Upstream product

• 949-38-2 1-(benzyloxy)-2-chlorobenzene 
• 668987-38-0 5,5-dimethyl-1,3,2-dioxaborinane 

Relevant articles and documents

Neopentylglycolborylation of ortho -substituted aryl halides catalyzed by NiCl2-Based mixed-ligand systems

NiCl2-based mixed-ligand systems were shown to be very effective catalysts for the neopentylglycolborylation of aryl iodides, bromides, and chlorides bearing electron-rich and electron-deficient ortho-substituents. Although NiCl2-based single-ligand catalytic systems were able to mediate neopentylglycolborylation of selected substrates, they were not as effective for all substrates, highlighting the value of the mixed-ligand concept. Optimization of the Ni(II)-catalyzed neopentylglycolborylation of 2-iodoanisole and methyl 2-iodobenzoate demonstrated that, while the role of ligand and coligand in the conversion of Ni(II) precatalyst to Ni(0) active catalyst cannot be ignored, a mixed-ligand complex is likely present throughout the catalytic cycle. In addition, protodeborylation and hydrodehalogenation were demonstrated to be the predominant side reactions of Ni(II)-catalyzed borylation of ortho-substituted aryl halides containing the electron-deficient carboxylate substituents. Ni(II) complexes in the presence of H2O and Ni(0) are responsible for the catalysis of these side reactions.