130164-89-5

Basic information

• Product Name: (S)-1,1'-binaphthalene-2,2'-diylbis(diphenylphosphine oxide)
• CAS NO: 130164-89-5
• Molecular Weight: 654.684
• Mol File: 130164-89-5.mol
• Article Data: 42

Chemical Properties

• CAS DataBase Reference: (S)-1,1'-binaphthalene-2,2'-diylbis(diphenylphosphine oxide)(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-1,1'-binaphthalene-2,2'-diylbis(diphenylphosphine oxide)(130164-89-5)
• EPA Substance Registry System: (S)-1,1'-binaphthalene-2,2'-diylbis(diphenylphosphine oxide)(130164-89-5)

Safety Data

• Hazardous Substances Data: 130164-89-5(Hazardous Substances Data)

Upstream product

• 76144-87-1 (R)-2,2'-bis(diphenylphosphanyl)-1,1'-binaphthyl 
• 76144-87-1 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl 
• 602-09-5 1,1'-bi-2-naphthol 
• 1499-21-4 Diphenylphosphinic chloride 
• 74866-28-7 2,2'-dibromo-1,1'-binaphthyl 
• 130164-89-5 2,2’-bis(diphenylphosphinooxide)-1,1’-binaphthalene 
• 2743-38-6 O,O'-dibenzoyl-L-tartaric acid 
• 18531-94-7 (R)-1,1'-Bi-2-naphthol 
• 76144-87-1 (S)-(1,1'-binaphthalene)-2,2'-diylbis(diphenylphosphine) 

Downstream Products

• 76144-87-1 (R)-2,2'-bis(diphenylphosphanyl)-1,1'-binaphthyl 
• 86632-33-9 (R)-2,2’-bis(1,1-diphenyl-1,1’-phosphine oxide)-1,1’-binaphthyl 
• 86632-33-9 (S)-1,1'-binaphthalene-2,2'-diylbis(diphenylphosphine oxide) 
• 76144-87-1 (S)-(1,1'-binaphthalene)-2,2'-diylbis(diphenylphosphine) 
• 597578-38-6 11-phenylbenzo[b]dinaphtho[2,1-d:1’,2’-f]phosphepine-1 1-oxide 
• 597578-44-4 2,2'-bis[phenyl(2-trimethylsilylphenyl)phosphinoyl]-1,1'-binaphthyl 
• 76144-87-1 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl 

Relevant articles and documents

New perfluoroalkylated BINAP usable as a ligand in homogeneous and supercritical carbon dioxide asymmetric hydrogenation

New (R)- or (S)-4,4′- and 5,5′- perfluoroalkylated BINAP have been synthesized in four steps from enantiomerically pure BINAP. These new ligands were used in the homogeneous asymmetric hydrogenation of ethyl acetoacetate in ethanol and in the asymmetric hydrogenation of methyl-2-acetamidoacrylate in supercritical carbon dioxide. In the supercritical media, the addition and nature of a co-solvent have been discussed. Very good conversion and selectivity were obtained in each case.

NIR and CT luminescence spectra of [Yb(TFN)(S-BINAPO)] and [Yb(HFA)(S-BINAPO)] complexes

The complexes [Yb(TFN)3(S-BINAPO)](TFN = 4,4,4-trifluoro-1(2- napthyl)-1,3-butanedione) (complex 1) and [Yb(HFA)3(S-BINAPO)](HFA = hexafluoroacetylacetonate) (complex 2) were synthesized, characterized. The absorption as well as PL s

Circularly polarized luminescence of Sm (III) and Eu (III) complexes with chiral ligand (R/S)-BINAPO

Luminescent lanthanide (III) ions have been exploited for circularly polarized luminescence (CPL) for decades. However, very few of these studies have involved chiral samarium (III) complexes. Complexes are prepared by mixing axial chiral ligands (R/S))-2

The preparation of bi-functional organophosphine oxides as potential antitumor agents

Following our previously reported pyridinyl phosphine oxides as antitumor agents, we targeted the commercially available C2-axial chiral organophosphine ligand catalysts, such as 2,2′-bis(diphenylphosphino)-1, 1′-binaphthyl (BINAP) 1 and 2,2′,6

Sequential Catalysis of Phosphine Oxide for Stereoselective Synthesis of Stereopentads

An efficient method for accessing enantiomerically pure stereopentads via a catalytic asymmetric sequential aldol reaction has been developed for the first time. The enantioselective sequential aldol reaction produces a wide range of chiral stereopentad precursors in good yields with excellent enantioselectivities. The key to success is the use of the sequential catalytic system involving a chiral phosphine oxide catalyst and trichlorosilyl triflate.

Highly regioselective bromination of BINAP in [Hmim]PF6 ionic liquid

Bromination of (R)-2,2′-(diphenylphospnino)-1,1′-binaphthyl (BINAP) in [Hmim]PF6 ionic liquid was performed with N-halosuccinimides at 110°C during 12 h, affording the 4,4′-dibromoBINAP in high yield. The ionic liquid was recycled four times without modif

Photoresponsive Propeller-like Chiral AIE Copper(I) Clusters

A pair of propeller-like chiral trinuclear CuI clusters (R/S-Cu3) with unique photoinduced fluorescence enhancement were prepared. R/S-Cu3 showed intense variable luminescence after UV light irradiation, which was attributed to the stepwise oxidation of ligand in the clusters. It exhibited typical aggregation-induced emission (AIE) (αAIE=17.3). Mechanism studies showed that metal cluster-centered (MCC) and triplet metal-to-ligand charge-transfer (3MLCT) processes are the origin of the luminescence; the processes are regulated by a restriction of intramolecular motions mechanism in a different state. The chiral structure and AIE feature endow R/S-Cu3 with remarkable circularly polarized luminescence (glum=2×10?2) in the aggregated state. It shows good capability for producing reactive oxygen species. This work enriches the kinds of atomically precise AIE clusters, gains insight into their luminescence mechanism, and offers the prospect of application in multifunctional materials.

Chiral Recognition of in Situ-Oxidized Phosphine Oxides with Octahedral Indium Complexes by 31P NMR Spectroscopy

Herein, efficient chiral recognition of phosphine oxides with octahedral indium complexes was demonstrated. Direct chiral analysis of in situ-prepared phosphine oxides formed using phosphines and hydrogen peroxide was conducted effectively via 31P nuclear magnetic resonance spectroscopy. Sufficient peak resolution of chiral phosphines was obtained consistently, thereby enabling the reliable determination of absolute chirality. Rational 1:1 binding models based on experiments and density functional theory calculations have been proposed.

Evaluation of bifunctional chiral phosphine oxide catalysts for the asymmetric hydrosilylation of ketimines

A series of bifunctional phosphine oxides have been prepared and evaluated as catalysts for the trichlorosilane mediated asymmetric hydrosilylation of ketimines. bis-Phosphine oxides, hydroxy-phosphine oxides, and biaryl phosphine oxides all demonstrated good catalytic activity, but poor to moderate enantioselectivity. A bis-P-chiral phosphine oxide displayed the highest enantioselectivity of 60%.