130625-81-9

Basic information

• Product Name: Methyl 2,4-dimethoxy-6-(E-prop-1-enyl)benzoate
• Synonyms: Methyl 2,4-dimethoxy-6-(E-prop-1-enyl)benzoate
• CAS NO: 130625-81-9
• Molecular Weight: 236.268
• Mol File: 130625-81-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Methyl 2,4-dimethoxy-6-(E-prop-1-enyl)benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: Methyl 2,4-dimethoxy-6-(E-prop-1-enyl)benzoate(130625-81-9)
• EPA Substance Registry System: Methyl 2,4-dimethoxy-6-(E-prop-1-enyl)benzoate(130625-81-9)

Safety Data

• Hazardous Substances Data: 130625-81-9(Hazardous Substances Data)

Upstream product

• 77844-97-4 3,4-dihydro-6,8-dimethoxy-3-methyl-1H-2-benzopyran-1-one 
• 4111-54-0 lithium diisopropyl amide 
• 74-88-4 methyl iodide 
• 70719-51-6 methyl 2,4-dimethoxy-6-<(phenylthio) methyl>-benzoate 
• 130625-80-8 Methyl 2,4-dimethoxy-6-<1-(phenylthio)propyl>benzoate 

Downstream Products

• 142913-71-1 3-Bromo-4,6-dimethoxy-2-((E)-propenyl)-benzoic acid (S)-1-methyl-5-oxo-hept-6-enyl ester 
• 17924-92-4 zearalenone 
• 130625-83-1 (2S)-5-(Dithian-2-yl)pentan-2-yl 2,4-dimethoxy-6-(E-prop-1-enyl)benzoate 
• 130625-87-5 (2S)-6-Oxooct-7-en-2-yl 2,4-dimethoxy-6-<3-bromoprop-1-(E)-enyl>benzoate 
• 130625-85-3 (2S,6RS)-6-Hydroxyoct-7-en-2-yl 2,4-dimethoxy-6-(E-prop-1-enyl)benzoate 
• 130625-86-4 (2S)-6-Oxooct-7-en-2-yl 2,4-dimethoxy-6-(E-prop-1-enyl)benzoate 
• 130625-84-2 (2S)-6-Oxohexan-2-yl 2,4-dimethoxy-6-(E-prop-1-enyl)benzoate 
• 130625-82-0 2,4-Dimethoxy-6-((E)-propenyl)-benzoyl chloride 
• 10497-40-2 2,4-Dimethoxy-zearalenone 
• 17924-91-3 2,4-Dimethoxy-6-(E-prop-1-enyl)benzoic acid 

Relevant articles and documents

Total Synthesis of the Mycotoxin (-)-Zearalenone based on Macrocyclisation using a Cinnamyl Radical Intermediate

A concise synthesis of optically active (-)-zearalenone, which uses a novel 14-endo-trig macrocyclisation from a cinnamyl radical intermediate onto an α,β-enone electrophore as a key feature, is described.

A Diastereoselective Synthesis of the Polyketide Antibiotic Citrinin using Toluate Anion Chemistry

The diastereoselectivity of various synthetic approaches to (+/-)-threo-3-(3,5-dihydroxy-2-methylphenyl)butan-2-ol ('Phenol B') (4), based on reactions of benzyl anions with electrophiles, has been investigated.The anion (9) derived from ethyl 2,4-dimethoxy-6-ethylbenzoate reacted with acetaldehyde to give mainly an erythro-product isolated as the lactone (12); acetylation with acetyl chloride to give a ketone, followed by reduction, gave mainly the required threo-lactone (11).An alternative route was frustrated by decomposition of the benzyl anion derived from 3,4-dihydro-6,8-dimethoxy-3-methyl-1H-2-benzopyran-1-one (17).Reduction of the carbonyl group of the threo-lactone (11) to a methyl gave the dimethyl ether of 'Phenol B', which was converted into (+/-)-citrinin (1).