70719-51-6Relevant articles and documents
Enantioselective synthesis of the 3C-protease inhibitor (-)-thysanone by a Staunton-Weinreb annulation strategy
Sperry, Jonathan,Tsz, Ying Yuen,Brimble, Margaret A.
experimental part, p. 2561 - 2569 (2009/12/25)
The total synthesis of (-)-thysanone is described. The key step involves the addition of an o-toluate anion to a lactone to create the naphthopyran framework (Staunton-Weinreb annulation). This synthesis further confirms the absolute stereochemistry of th
ortho-Toluate Carboanion Chemistry: Sulfenylation and Selenation
Hauser, Frank M.,Rhee, Richard P.,Prasanna, Subbarao,Weinreb, Steven M.,Dodd, John H.
, p. 72 - 74 (2007/10/02)
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