13080-75-6

Basic information

• Product Name: 5-ACETYLIMINODIBENZYL 99
• Synonyms: 5-ACETYLIMINODIBENZYL 99;5-acetyliminodibenzyl;5-ACETYLIMINODIBENZYL 99%;5-ACETYLIMINODIBENYL;5-Acetyl-10,11-dihydro-5H-dibenz[b,f]azepine;1-(10,11-Dihydro-5H-dibenz[b,f]azepin-5-yl)ethanone;5-Acetyl-10,11-dihydro-5H-dibenzo[b,f]azepine
• CAS NO: 13080-75-6
• Molecular Formula: C₁₆H₁₅NO
• Molecular Weight: 239.31228
• Mol File: 13080-75-6.mol
• Article Data: 5

Chemical Properties

• Melting Point: 95-97 °C(lit.)
• Boiling Point: 446.7°Cat760mmHg
• Flash Point: 217.3°C
• Appearance: /
• Density: 1.151g/cm³
• Vapor Pressure: 3.56E-08mmHg at 25°C
• Refractive Index: 1.606
• Storage Temp.: Refrigerator
• Solubility: Chloroform (Slightly), DMSO (Slightly), Methanol (Slightly)
• Water Solubility: 105.16mg/L
• CAS DataBase Reference: 5-ACETYLIMINODIBENZYL 99(CAS DataBase Reference)
• NIST Chemistry Reference: 5-ACETYLIMINODIBENZYL 99(13080-75-6)
• EPA Substance Registry System: 5-ACETYLIMINODIBENZYL 99(13080-75-6)

Safety Data

• WGK Germany: 3
• Hazardous Substances Data: 13080-75-6(Hazardous Substances Data)

Usage

Uses

5-Acetyl-10,11-dihydro-5H-dibenzo[b,f]azepine, is Dibenz[b,f]azepine derivative, possessing antioxidant potentials. It is also an analogue of Imipramine (I465980), and Desipramine (D290050). Carbamazepine Impurity 2.

Synthesis Reference(s)

Tetrahedron Letters, 9, p. 3469, 1968 DOI: 10.1016/S0040-4039(01)99085-9

InChI:InChI=1/C16H15NO/c1-12(18)17-15-8-4-2-6-13(15)10-11-14-7-3-5-9-16(14)17/h2-9H,10-11H2,1H3

Upstream product

• 84803-67-8 3-amino-5-acetyl-10,11-dihydro-5H-dibenzazepine 
• 71-43-2 benzene 
• 256-96-2 dibenzoazepine 
• 64-19-7 acetic acid 
• 494-19-9 9,10-dihydrodibenzazepine 
• 75-36-5 acetyl chloride 
• 108-24-7 acetic anhydride 

Downstream Products

• 79752-03-7 3-nitro-5-acetyl-10,11-dihydro-5H-dibenzazepine 
• 494-19-9 9,10-dihydrodibenzazepine 
• 40583-88-8 11-ethyliminodibenzyl 
• 64-17-5 ethanol 
• 22965-11-3 4,5-Dioxo-4,5,11,12-tetrahydro-indolo<7,1-ab><1>benzazepin 
• 19579-83-0 5H-dibenzazepine-10(11H),11-dione 
• 84803-67-8 3-amino-5-acetyl-10,11-dihydro-5H-dibenzazepine 
• 10464-35-4 3-amino-10,11-dihydro-5H-dibenzazepine 
• 78816-40-7 3-carbethoxyamino-10,11-dihydro-5H-dibenzazepine 
• 134068-17-0 ethyl (5-(N-ethylglycyl)-10,11-dihydro-5H-dibenzo[b,f]azepin-3-yl)carbamate 
• 132900-42-6 3-carbethoxy-5-aminoacetyl-10,11-dihydro-5H-dibenzazepine 
• 83275-55-2 ethyl (5-(3-(N,N-diethylamino)propanoyl)-10,11-dihydro-5H-dibenzo[b,f]azepin-3-yl)carbamate 
• 78816-60-1 3-Carbisopropoxyamino-5-β-chlorpropionyl-iminodibenzyl 
• 25961-11-9 3-chloro-5-(3-dimethylaminopropyl)-10,11-dihydro-5H-dibenzo(6,5)azepine 

Relevant articles and documents

An improved method for the preparation of 3-substituted 10,11-dihydro-5H-[b,f] azepine derivatives

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A novel porphyrazine ligand tailored to homogeneous metal catalyzed transformations

A novel centrosymmetric porphyrazine (Pz) 1 decorated with pyrazino-dibenzo[b,f]azepine units have been prepared via Linstead macrocyclization reaction of a dinitrile precursor. Accordingly, the peripheral azepine nitrogen offers a chemical handle for sub

3-Cyano-N-(N,N-dimethylaminopropyl)-iminodibenzyl and salts thereof

3-Cyano-N-(N,N-dimethylaminopropyl)-iminodibenzyl, and its salts, prepared, inter alia, by heating 3-cyano-iminodibenzyl-5-carboxylic acid (N,N-dimethylaminopropyl ester) are described. The end product and its salts are useful as antidepressants.