135507-97-0

Basic information

• Product Name: 2,2-bis(4-chlorophenyl)-2-hydroxyethyl acetate
• Synonyms: 2,2-bis(4-chlorophenyl)-2-hydroxyethyl acetate
• CAS NO: 135507-97-0
• Molecular Weight: 325.191
• Mol File: 135507-97-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2,2-bis(4-chlorophenyl)-2-hydroxyethyl acetate(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2-bis(4-chlorophenyl)-2-hydroxyethyl acetate(135507-97-0)
• EPA Substance Registry System: 2,2-bis(4-chlorophenyl)-2-hydroxyethyl acetate(135507-97-0)

Safety Data

• Hazardous Substances Data: 135507-97-0(Hazardous Substances Data)

Upstream product

• 2642-81-1 1,1-bis(p-chlorophenyl)ethene 
• 33840-74-3 1-(phenylsulfinyl)propan-2-one 
• 14284-89-0 manganese(III) acetylacetonate 
• 64-19-7 acetic acid 
• 5000-44-2 1-phenylsulfonyl-2-propanone 
• 3240-34-4 [bis(acetoxy)iodo]benzene 
• 80-06-8 chlorfenethol 

Relevant articles and documents

Synthesis of β-acetoxy alcohols by PhI(OAc)2-mediated metal-free diastereoselective β-acetoxylation of alcohols

β-Acetoxy alcohols can be synthesized in good yields with excellent diastereoselectivity from tertiary alcohols through PhI(OAc)2-mediated metal-free β-acetoxylation. Mechanistic studies showed that the β-acetoxylation process might undergo dehydration and sequential highly regioselective and diastereoseletive dioxygenation. Gram scale and diverse useful scaffolds could be prepared via this β-acetoxylation process.

Formation of 1,2-Dioxanes by the Use of Tris(2,4-pentanedionato)manganese(III) or Manganese(III) Acetate

The reactions of 1,1-diphenylethene, 1,1-bis(4-chlorophenyl)ethene, 1,1-bis(4-methoxyphenyl)ethene, 1,1-bis(4-methylphenyl)ethene, 1,1-bis(4-fluorophenyl)ethene, styrene, 1-octene, cyclohexene, and cyclooctene with tris(2,4-pentanedionato)manganese(III) () in acetic acid at room temperature give 4-acetyl-3-methyl-1,2-dioxan-3-ol in 8-92percent yields, together with 3-acetyl-4-hydroxy-3-hexene-2,5-dione.The similar reactions of 1,1-diphenylethene with 2,4-pentanedione, 3-methyl-2,4-pentanedione, 3-ethyl-2,4-pentanedione, 1-phenyl-1,3-butanedione, acetoacetanilide, and 1,3-cyclohexanedione in the presence of manganese(III) acetate also give the corresponding cyclic peroxide in good to moderate yields.The mechanisms of manganese(III)-induced 1,2-dioxane ring formation and concomitant radical side reaction are discussed.