136773-71-2

Basic information

• Product Name: (2Z,4E)-2-Benzothiazol-2-yl-5-phenyl-penta-2,4-dienenitrile
• Synonyms: (2Z,4E)-2-Benzothiazol-2-yl-5-phenyl-penta-2,4-dienenitrile
• CAS NO: 136773-71-2
• Molecular Weight: 288.373
• Mol File: 136773-71-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (2Z,4E)-2-Benzothiazol-2-yl-5-phenyl-penta-2,4-dienenitrile(CAS DataBase Reference)
• NIST Chemistry Reference: (2Z,4E)-2-Benzothiazol-2-yl-5-phenyl-penta-2,4-dienenitrile(136773-71-2)
• EPA Substance Registry System: (2Z,4E)-2-Benzothiazol-2-yl-5-phenyl-penta-2,4-dienenitrile(136773-71-2)

Safety Data

• Hazardous Substances Data: 136773-71-2(Hazardous Substances Data)

Upstream product

• 56278-50-3 2-cyanomethylbenzothiazole 
• 104-55-2 3-phenyl-propenal 
• 137-07-5 2-amino-benzenethiol 
• 14371-10-9 (E)-3-phenylpropenal 

Relevant articles and documents

Highly diastereoselective synthesis of 3-methylenetetrahydropyrans by palladium-catalyzed oxa-[4 + 2] cycloaddition of 2-alkenylbenzothiazoles

A highly diastereoselective synthesis of 3-methylenetetrahydropyrans via palladium-catalyzed oxa-[4 + 2] cycloaddition of 2-alkenylbenzothiazoles with allyl carbonates bearing a nucleophilic alcohol side chain is presented. This synthetic methodology tolerates a wide variety of 2-alkenylbenzothiazoles and afforded the desired 3-methylenetetrahydropyrans in good yields and excellent dr. In addition, further derivatizations resulted in new scaffolds, making them useful synthetic precursors.

UNCATALYZED KNOEVENAGEL CONDENSATION OF 2-CYANOMETHYLBENZOTHIAZOLE WITH AROMATIC ALDEHYDES. PREPARATION OF 3-ARYL-2-(2-BENZOTHIAZOLYL)-ACRYLONITRILES AND 3-(2-BENZOTHIAZOLYL)-COUMARIN IMINES

A series of 3-aryl-2-(2-benzothiazolyl)-acrylonitriles (3a-n) and 3-(2-benzothiazolyl)-coumarin imines (5a-f) are prepared in good to high yields by refluxing solutions of 2-cyanomethylbenzothiazole (1) and aromatic aldehydes (2, 4) in ethanol. Key words: