140160-62-9

Basic information

• Product Name: 1H-Pyrrolo[1,2-c]imidazole-1,3(2H)-dione, tetrahydro-2-(phenylmethoxy)-, (S)-
• CAS NO: 140160-62-9
• Molecular Formula: C13H14N2O3
• Molecular Weight: 246.266
• Mol File: 140160-62-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1H-Pyrrolo[1,2-c]imidazole-1,3(2H)-dione, tetrahydro-2-(phenylmethoxy)-, (S)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1H-Pyrrolo[1,2-c]imidazole-1,3(2H)-dione, tetrahydro-2-(phenylmethoxy)-, (S)-(140160-62-9)
• EPA Substance Registry System: 1H-Pyrrolo[1,2-c]imidazole-1,3(2H)-dione, tetrahydro-2-(phenylmethoxy)-, (S)-(140160-62-9)

Safety Data

• Hazardous Substances Data: 140160-62-9(Hazardous Substances Data)

Upstream product

• 128252-48-2 (-)-(S)-methyl 1-<<(benzyloxy)amino>carbonyl>pyrrolidine-2-carboxylate 
• 85665-59-4 (S)-methyl 1-(chlorocarbonyl)pyrrolidine-2-carboxylate 
• 622-33-3 N-benzyloxyamine 

Downstream Products

• 140160-63-0 (5S)-3-hydroxy-1,3-diazabicyclo<3.3.0>octane-2,4-dione 

Relevant articles and documents

Asymmetric Diels-Alder Cycloadditions with Chiral Carbamoyl Dienophiles

Chiral acylnitroso dienophiles 14, which were obtained from L-proline and from D-mandelic acid, reacted with cyclohexa-1,3-diene to give the expected diastereoisomers 15 and 16 (Scheme 2 and Table 1).The d.e. values for these Diels-Alder reactions were moderate; they are related to the molecular stiffness of the dienophiles.The absolute configuration of the major cycloadducts was interpreted in terms of HOMO/LUMO interactions, the approach being 'endo' and the acylnitroso dienophiles reacting from their s-cis-conformation.