1403266-85-2

Basic information

• Product Name: 1-bromo-4-((6-iodohexyl)oxy)benzene
• Synonyms: 1-bromo-4-((6-iodohexyl)oxy)benzene
• CAS NO: 1403266-85-2
• Molecular Weight: 383.067
• Mol File: 1403266-85-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1-bromo-4-((6-iodohexyl)oxy)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-bromo-4-((6-iodohexyl)oxy)benzene(1403266-85-2)
• EPA Substance Registry System: 1-bromo-4-((6-iodohexyl)oxy)benzene(1403266-85-2)

Safety Data

• Hazardous Substances Data: 1403266-85-2(Hazardous Substances Data)

Upstream product

• 629-03-8 1 ,6-dibromohexane 
• 106-41-2 4-bromo-phenol 
• 75612-73-6 1-bromo-4-(6-bromohexyloxy)benzene 
• 133080-87-2 4-Bromo-1-(6-hydroxyhexan-1-yloxy)benzene 

Downstream Products

• 30752-19-3 1-bromo-4-hexyloxylbenzene 

Relevant articles and documents

Cu-Catalyzed Hydroxymethylation of Unactivated Alkyl Iodides with CO To Provide One-Carbon-Extended Alcohols

We have developed a reductive carbonylation method by which unactivated alkyl iodides can be hydroxymethylated to provide one-carbon-extended alcohol products under Cu-catalyzed conditions. The method is tolerant of alkyl β-hydrogen atoms, is robust towards a wide variety of functional groups, and was applied to primary, secondary, and tertiary alkyl iodide substrates. Mechanistic experiments indicate that the transformation proceeds by atom-transfer carbonylation (ATC) of the alkyl iodide followed in tandem by two CuH-mediated reductions in rapid succession. This radical mechanism renders the Cu-catalyzed system complementary to precious-metal-catalyzed reductive carbonylation reactions.

Copper-catalyzed reduction of alkyl triflates and iodides: An efficient method for the deoxygenation of primary and secondary alcohols

We describe an effective method for catalytic reduction of 1°alkyl sulfonates, and 1°and 2°iodides in the presence of a wide range of functional groups. This Cu-catalyzed reaction provides a means for the effective deoxygenation of alcohols, as demonstrated by the highly selective reduction of 1°alcohols using a triflation/reduction sequence. A preliminary study of the reaction mechanism suggests that the reduction does not involve free-radical intermediates. Primarily reduced: The copper-catalyzed reduction of 1°alkyl sulfonates, and 1°and 2°iodides, which is effective in the presence of a wide range of functional groups, provides a means for the effective deoxygenation of alcohols. A preliminary study of the reaction mechanism suggests that the reduction does not involve free-radical intermediates. Copyright