1446518-54-2Relevant articles and documents
Catalytic decarboxylative alkenylation of enolates
Schroeder, Sybrin P.,Taylor, Nicholas J.,Jackson, Paula,Franckevicius, Vilius
, p. 3778 - 3781 (2013/08/23)
A palladium-catalyzed decarboxylative alkenylation of stabilized enolates has been developed, which gives rise to alkenylated dicarbonyl products from enol carbonates regioselectively with concomitant installation of a quaternary all-carbon center. The broad scope of the reaction has been demonstrated by successfully utilizing a range of enolates and external phenol nucleophiles.