1446518-30-4Relevant articles and documents
Regioswitchable Palladium-Catalyzed Decarboxylative Coupling of 1,3-Dicarbonyl Compounds
Kenny, Miles,Christensen, Jeppe,Coles, Simon J.,Franckeviius, Vilius
supporting information, p. 3926 - 3929 (2015/08/19)
A palladium-catalyzed chemo- and regioselective coupling of 1,3-dicarbonyl compounds via an allylic linker has been developed. This reaction, which displays broad substrate scope, forms two C-C bonds and installs two all-carbon quaternary centers. The regioselectivity of the reaction can be predictably controlled by utilizing an enol carbonate of one of the coupling partners.