1586-98-7Relevant articles and documents
Synthesis and extraction properties of oxathiacrown compounds containing benzyl groups
Rezekina,Rakhmanov,Lukovskaya,Bobylyova,Abramov,Chertkov,Khoroshutin,Anisimov
, p. 216 - 220 (2006)
8-Benzyl-1.4-dioxa-7,10-dithiacyclododecane and 11-benzyl-1,4,7-trioxa-10, 13-dithiacyclopentadecane were obtained by the interaction of (2,3-dibromo-1-propyl)benzene with 1,8-dimercapto-3,6-dioxaoctane and 1,11-dimercapto-3,6,9-trioxaundecane. The extrac
Dibrominated addition and substitution of alkenes catalyzed by Mn2(CO)10
Chan, Albert S. C.,Jiang, Yi,Meng, Shanshui,Song, Xianheng,Zhang, Hong,Zou, Yong
supporting information, p. 13385 - 13388 (2021/12/17)
A practical method for the dibromination of alkenes without using molecular bromine is consistently appealing in organic synthesis. Herein, we report Mn-catalyzed dibrominated addition and substitution of alkenes only with N-bromosuccinimide, producing a variety of synthetically valuable dibrominated compounds in moderate to high yields. This journal is
Closing the Gap: Structural Evidence for the Missing Hexabromide Dianion [Br6]2?
Sonnenberg, Karsten,Pr?hm, Patrick,Müller, Carsten,Beckers, Helmut,Steinhauer, Simon,Lentz, Dieter,Riedel, Sebastian
supporting information, p. 1072 - 1075 (2018/01/15)
The formation and experimental characterization of the first hexabromide dianion is presented. This dianion fills the last remaining gap in the series of polybromides from the tribromide [Br3]? to the undecabromide [Br11]
Practical regio- and stereoselective azidation and amination of terminal alkenes
Ojo, Olatunji S.,Miranda, Octavio,Baumgardner, Kyle C.,Bugarin, Alejandro
supporting information, p. 9354 - 9358 (2019/01/03)
There is significant interest in developing more rapid and efficient production of nitrogen-containing allylic compounds, as widely used in various syntheses. This work reports a variety of allylic azides and allylic amines synthesized by an efficient, new one-pot protocol that employs readily available terminal alkenes as starting materials. This method is highly regio- and stereoselective, affording the linear (E)-isomer, under metal-free conditions. This process tolerates several functional groups including halogen-containing molecules; it is general for azides and amine nucleophiles; and, adducts were obtained in good yields.