16821-33-3

Basic information

• Product Name: 7-methoxy-3-(6'-methoxy-1',2',3',4',-tetrahydronaphth-1'-yl)-1,2-dihydronaphthalene
• CAS NO: 16821-33-3
• Molecular Weight: 320.431
• Mol File: 16821-33-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 7-methoxy-3-(6'-methoxy-1',2',3',4',-tetrahydronaphth-1'-yl)-1,2-dihydronaphthalene(CAS DataBase Reference)
• NIST Chemistry Reference: 7-methoxy-3-(6'-methoxy-1',2',3',4',-tetrahydronaphth-1'-yl)-1,2-dihydronaphthalene(16821-33-3)
• EPA Substance Registry System: 7-methoxy-3-(6'-methoxy-1',2',3',4',-tetrahydronaphth-1'-yl)-1,2-dihydronaphthalene(16821-33-3)

Safety Data

• Hazardous Substances Data: 16821-33-3(Hazardous Substances Data)

Upstream product

• 7677-24-9 trimethylsilyl cyanide 
• 16821-32-2 6-methoxy-1,2,3,4-tetrahydronaphthalen-1-ol 

Relevant articles and documents

CONTROLLING BENZYLIC FUNCTIONALITY AND STEREOCHEMISTRY: 2. SYNTHESIS OF THE PSEUDOPTEROSIN AGLYCONE

Homologation, cyclisation, and reduction converted the tetralin (2) to the hexahydrophenalenol (8), which was methylated to afford (19) via alkoxide-directed metallation.The degree of stereoselectivity resulting from reactions of (19) and congeners with allylsilane - Lewis acid combinations was markedly dependent upon substitution patterns, whereas Et2AlCN-SnCl4 produced pseudoaxial nitriles.The trimethyl nitrile (24) was elaborated to the pseudopterosin aglycone (4).