17105-71-4

Basic information

• Product Name: Formamide, N-methyl-N-(phenylmethyl)-
• CAS NO: 17105-71-4
• Molecular Formula: C9H11NO
• Molecular Weight: 149.192
• Mol File: 17105-71-4.mol
• Article Data: 98

Chemical Properties

• CAS DataBase Reference: Formamide, N-methyl-N-(phenylmethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Formamide, N-methyl-N-(phenylmethyl)-(17105-71-4)
• EPA Substance Registry System: Formamide, N-methyl-N-(phenylmethyl)-(17105-71-4)

Safety Data

• Hazardous Substances Data: 17105-71-4(Hazardous Substances Data)

Upstream product

• 1608-69-1 N-Acetoxymethyl-N-methyl-formamid 
• 71-43-2 benzene 
• 67-66-3 chloroform 
• 29823-47-0 N-benzyl-N-methylacetamide 
• 108932-50-9 N-Benzyl-2-(3,4-dimethoxy-phenyl)-N-methyl-acetamide 
• 555-57-7 Pargyline 
• 2520-97-0 N-allyl-N-α-methylbenzylamine 
• 64-18-6 formic acid 
• 103-67-3 benzyl-methyl-amine 
• 68-12-2 N,N-dimethyl-formamide 
• 616-38-6 carbonic acid dimethyl ester 
• 100-46-9 benzylamine 
• 27238-06-8 N-benzyl-N-methylmethanesulfonamide 
• 2591-86-8 N-Formylpiperidine 

Downstream Products

• 103-83-3 N,N'-dimethylbenzylamine 
• 1075240-71-9 C₂₅H₃₉NO₅Si 
• 2591-86-8 N-Formylpiperidine 
• 13493-24-8 N-benzyl-N-methyl-1-naphthamide 
• 61802-83-3 N-methyl-N-benzylbenzamide 
• 149098-91-9 (E)-N-benzyl-N-methyl-3-phenylprop-2-enamide 
• 4764-13-0 2-(N-piperidinylmethyl)phenol 
• 60460-63-1 2-(N-methyl-N-benzyl)aminomethylphenol 
• 103-67-3 benzyl-methyl-amine 
• 1076-26-2 1-methyl-2-naphthol 
• 3695-02-1 N-benzyl-N-methyl-p-toluenesulfonamide 
• 67-56-1 methanol 
• 1239326-96-5 benzyl(methyl)carbonocyanidic amide 
• 42882-26-8 N-methyl-N-(1-phenylethyl)amine 

Relevant articles and documents

Iridium-catalyzed formylation of amines with paraformaldehyde

Amines have been formylated using aqueous formaldehyde or paraformaldehyde and the iridium catalyst [CpIrI2]2. Paraformaldehyde acts as both a formylating agent and an oxidant.

-

-

Additive-free selective methylation of secondary amines with formic acid over a Pd/In2O3 catalyst

Formic acid is used as the sole carbon and hydrogen source in the methylation of aromatic and aliphatic amines to methylamines. The reaction proceeds via a formylation/transfer hydrogenation pathway over a solid Pd/In2O3 catalyst without the need for any additive.

Nickel-Catalyzed Amination of Aryl Chlorides with Amides

A nickel-catalyzed amination of aryl chlorides with diverse amides via C-N bond cleavage has been realized under mild conditions. A broad substrate scope with excellent functional group tolerance at a low catalyst loading makes the protocol powerful for synthesizing various aromatic amines. The aryl chlorides could selectively couple to the amino fragments rather than the carbonyl moieties of amides. Our protocol complements the conventional amination of aryl chlorides and expands the usage of inactive amides.