1732-72-5Relevant articles and documents
Synthesis and reactivity of alkoxy(trimethylsiloxy)phosphines and their derivatives
Prishchenko, Andrey A.,Livantsov, Mikhail V.,Novikova, Olga P.,Livantsova, Ludmila I.,Petrosyan, Valery S.
, p. 138 - 145 (2012)
Convenient procedures for the synthesis of new alkoxy(trimethylsiloxy) phosphines and their derivatives starting from the available alkyl hypophosphites and N-trimethylsilyl succinimide are proposed. Some properties of these new phosphines such as nucleophilic substitution of the trimethylsiloxy group at trivalent phosphorus, the Arbuzov reaction, and addition of PH and POSi fragments to multiple carbon-carbon bonds are presented.
A Convenient and Facile Synthesis of Dialkylphosphines
Majewski, Piotr
, p. 554 - 555 (1987)
A series of simple dialkylphosphines 2 has been prepared by the thermal disproportionation of dialkylphosphine oxides 1 induced by the R2P(O)Cl/R2PCl system, generated in situ from 1 with a catalytic amount of carbon tetrachloride.
Synthesis and reactivity of substituted α-carbonylphosphonites and their derivatives
Prishchenko, Andrey A.,Livantsov, Mikhail V.,Novikova, Olga P.,Livantsova, Ludmila I.,Petrosyan, Valery S.
experimental part, p. 352 - 372 (2012/08/28)
Convenient methods for the synthesis of functionalized organophosphorus compounds containing carbonyl groups as well as di- or trialkoxymethyl fragments attached to phosphorus, and their derivatives, starting from the available derivatives of trivalent phosphorus acids, are proposed, and some properties of the new functionalized organophosphorus compounds are presented. So, the alkylation and acylation reaction of (dialkoxymethyl) phosphonites and their analogs have been studied. It is found that the Arbuzov rearrangement of these compounds was accompanied by the phosphorus-carbon bond cleavage with unique retention of the three-coordinate phosphorus.