174708-97-5Relevant articles and documents
Flash Vacuum Thermolysis of Four Membered Rings Containing Nitrogen Atom. Part IV. Some Mechanistic Aspects of the Thermal Decomposition of Azetidines
Lesniak, S.
, p. 1484 - 1489 (2007/10/03)
Thermal cycloreversions of substituted azetidine rings under FVT conditions have been studied.It was found that the regiochemistry of these reactions depends on the nature of substituents present in the system.The assumed 1,4-diradical stepwise mechanism enabled us to compare the competition in breaking of the first bond (N-C2 or C2-C3) depending on the stability of newly formed 1,4-diradical. - Keywords: azetidines, flash vacuum thermolysis