618-34-8

Basic information

• Product Name: (1-Chlorovinyl)benzene
• Synonyms: (1-Chloroethenyl)benzene;(1-Chlorovinyl)benzene;1-Chlorovinylbenzene;1-Phenyl-1-chloroethene
• CAS NO: 618-34-8
• Molecular Formula: C₈H₇Cl
• Molecular Weight: 138.5942
• Mol File: 618-34-8.mol
• Article Data: 38

Chemical Properties

• Melting Point: -23°C
• Boiling Point: 189.97°C (estimate)
• Flash Point: 70.1°C
• Appearance: /
• Density: 1.1016
• Refractive Index: 1.5612
• CAS DataBase Reference: (1-Chlorovinyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (1-Chlorovinyl)benzene(618-34-8)
• EPA Substance Registry System: (1-Chlorovinyl)benzene(618-34-8)

Safety Data

• Hazardous Substances Data: 618-34-8(Hazardous Substances Data)

Usage

General Description

(1-Chlorovinyl)benzene, also known as chlorostyrene, is a chemical compound with the formula C8H7Cl. It is a colorless liquid that is often used as a monomer in the production of polymers. (1-Chlorovinyl)benzene is commonly used in the synthesis of copolymers with styrene, which are used in the production of adhesives, paints, and coatings. It is also used in the manufacture of resins and plastics. Additionally, it is used as a chemical intermediate in the production of pharmaceuticals and agrochemicals. However, (1-Chlorovinyl)benzene should be handled with care due to its potential health hazards, including irritation to the skin, eyes, and respiratory system, as well as being a flammable liquid.

Upstream product

• 4885-02-3 Dichloromethyl methyl ether 
• 98-86-2 acetophenone 
• 1074-11-9 1-(1,2-dichloroethyl)benzene 
• 51246-12-9 (Z,Z)-di(2-chloro-2-phenylvinyl)boron chloride 
• 51246-11-8 trans-(2-chloro-2-phenylvinyl)dichloroborane 
• 536-74-3 phenylacetylene 
• 729-43-1 acetophenonazine 
• 98-81-7 1-bromovinylbenzene 
• 109391-87-9 (2-chloro-2-phenylethyl)phenylselenium dichloride 
• 75-05-8 acetonitrile 
• 86804-83-3 o-phenylene 1-phenylvinyl phosphite 
• 156908-55-3 1-nitroso-3-chloro-3-phenylazetidine 
• 156908-56-4 1-nitroso-2,2-dimethyl-3-chloro-3-phenylazetidine 
• 174708-97-5 1-benzyl-3-chloro-2,2-dimethyl-3-phenylazetidine 

Downstream Products

• 1923-01-9 trimethyl(1-phenylvinyl)silane 
• 612-71-5 1,3,5-triphenylbenzene 
• 13706-68-8 (+-)-phenylsuccinonitrile 
• 700-60-7 trichlorovinylbenzene 
• 65725-00-0 (β-chlorostyryl)phosphonic acid 
• 536-74-3 phenylacetylene 
• 98-86-2 acetophenone 
• 99183-97-8 2-Chlor-2-phenyl-cyclopropancarbonsaeure 
• 65322-28-3 1-Phenyl-trichlorcyclopropan 
• 7781-70-6 1,4-dibromo-2,3-diphenyl-2-butene 
• 93-58-3 benzoic acid methyl ester 
• 107-31-3 Methyl formate 
• 112778-40-2 (1-Chloro-3-difluoromethylene-cyclobutyl)-benzene 
• 112778-33-3 (1-Chloro-2,2-difluoro-3-methylene-cyclobutyl)-benzene 

Relevant articles and documents

A practical synthetic method for vinyl chlorides and vinyl bromides from ketones via the corresponding vinyl phosphate intermediates

A new synthetic method for the preparation of vinyl chlorides and vinyl bromides from acyclic and cyclic ketones is described. Vinyl halides are practically obtained from the corresponding vinyl phosphate intermediates with triphenylphosphine dihalide.

Synthesis of Unsymmetrical 1,4-Dicarbonyl Compounds by Photocatalytic Oxidative Radical Additions

Herein we report a photocatalytic oxidative radical addition reaction for the synthesis of unsymmetrical 1,4-dicarbonyl compounds. This reaction utilizes a desulfurization process to generate electrophilic radicals, which add to α-halogenated alkenes and undergo further oxidation to deliver 1,4-dicarbonyl compounds. This mild and highly efficient method provides a valuable alternative to known strategies.

A Chlorinating Reagent Yields Vinyl Chlorides with High Regioselectivity under Heterogeneous Gold Catalysis

A novel chlorinating reagent with a high concentration of HCl has enabled the highly regioselective hydrochlorination of unactivated alkynes using a commercial nanogold catalyst. No overchlorination or hydration products were formed, and various functional groups were tolerated. This hydrochlorination method could be conducted under open air.

Catalyst-free hydrochlorination protocol for terminal arylalkynes with hydrogen chloride

We present a simple and straightforward protocol for hydrochlorination of terminal arylalkynes to vinyl chlorides using hydrogen chloride under mild reaction conditions. This protocol does not involve any metal catalysts or additives. It is simple, inexpensive, and easy to prepare, and exhibits good reaction activity. The hydrochlorination proceeds smoothly to yield unique regioselective products via the Markovnikov addition rule.