1797-75-7

Basic information

• Product Name: DIALLYL MALONATE
• Synonyms: DIALLYL MALONATE;diprop-2-enyl propanedioate
• CAS NO: 1797-75-7
• Molecular Formula: C₉H₁₂O₄
• Molecular Weight: 184.19
• Product Categories: monomer
• Mol File: 1797-75-7.mol
• Article Data: 21

Chemical Properties

• Boiling Point: 110-112°C 9mm
• Flash Point: 107.8 °C
• Appearance: /
• Density: 1.057 g/cm³
• Vapor Pressure: 0.0557mmHg at 25°C
• Refractive Index: 1.449
• CAS DataBase Reference: DIALLYL MALONATE(CAS DataBase Reference)
• NIST Chemistry Reference: DIALLYL MALONATE(1797-75-7)
• EPA Substance Registry System: DIALLYL MALONATE(1797-75-7)

Safety Data

• Statements: 36/37/38
• Safety Statements: 26-36
• Hazardous Substances Data: 1797-75-7(Hazardous Substances Data)

Usage

General Description

Diallyl malonate is a chemical compound that is used in various industrial applications. It is a clear, colorless liquid with a pungent odor, and it is highly flammable. Diallyl malonate is primarily used as a monomer in the production of polymers and resins, where it serves as a crosslinking agent for enhanced durability and strength. It is also used as a chemical intermediate in the production of pharmaceuticals, as well as in the synthesis of perfumes and fragrances. Additionally, it can be used as a flavoring agent in food products, although its use in this application is limited due to its potentially toxic properties. Diallyl malonate should be handled and stored with care, as it can be hazardous to human health and the environment.

InChI:InChI=1/C9H12O4/c1-3-5-12-8(10)7-9(11)13-6-4-2/h3-4H,1-2,5-7H2

Upstream product

• 107-18-6 allyl alcohol 
• 108-59-8 malonic acid dimethyl ester 
• 141-82-2 malonic acid 
• 16854-72-1 Dithiomalonsaeure-S,S'-diphenylester 
• 106-95-6 allyl bromide 
• 2033-24-1 cycl-isopropylidene malonate 
• 141-95-7 sodium malonate 
• 107-05-1 3-chloroprop-1-ene 
• 868-26-8 dimethyl 2-bromomalonate 
• 1663-67-8 malonoyl dichloride 
• 205114-96-1 2-Bromo-malonic acid allyl ester methyl ester 
• 504-64-3 carbon suboxide 

Downstream Products

• 1027542-25-1 (S)-2-Allyloxycarbonyl-3-((S)-3-tert-butoxycarbonylamino-4,4-dimethyl-2-oxo-pentyl)-succinic acid 1-allyl ester 4-benzyl ester 
• 1175184-76-5 C₁₄H₁₀O₆ 
• 339283-33-9 allyl 2-oxo-2H-chromene-3-carboxylate 
• 1402592-36-2 1,3-allyl 2-(diphenylsulfuranylidene)malonate 
• 249588-49-6 2-[2-(tert-butyl-dimethyl-silanyloxy)-3-tritylsulfanyl-propyl]-malonic acid diallyl ester 

Relevant articles and documents

Ball-Milling-Enabled Reactivity of Manganese Metal**

Efforts to generate organomanganese reagents under ball-milling conditions have led to the serendipitous discovery that manganese metal can mediate the reductive dimerization of arylidene malonates. The newly uncovered process has been optimized and its mechanism explored using CV measurements, radical trapping experiments, EPR spectroscopy, and solution control reactions. This unique reactivity can also be translated to solution whereupon pre-milling of the manganese is required.

Synthesis and structure of allylated derivatives of fullerenes C60 and C70

New chromatographically pure monoand hexamethanofullerenes C60 and C70 containing active allylic groups were synthesized by Bingel—Hirsch reaction. These compounds are promising for the studies of biological activity, as well as for obtaining on their basis new fullerenecontaining materials. The purity and composition of the synthesized compounds were confirmed by MALDI-TOF mass spectrometry and HPLC, their structure was established by 1H and 13C NMR spectroscopy and X-ray diffraction.

Synthesis of coumarin-3-carboxylic esters via FeCl3-catalyzed multicomponent reaction of salicylaldehydes, Meldrum's acid and alcohols

A FeCl3-catalyzed multicomponent reaction was developed for the facile synthesis of coumarin-3-carboxylic ester derivatives in a highly atom-economic and environmentally friendly way. Using simple and cheaply available salicylaldehydes, Meldrum's acid and alcohols as the starting materials, the method needs no extra additives and features wide substrate scope, good functional group tolerance and mild reaction conditions.