180746-14-9

Basic information

• Product Name: 1,1'-Biphenyl, 4-[(phenylsulfinyl)methyl]-
• CAS NO: 180746-14-9
• Molecular Formula: C19H16OS
• Molecular Weight: 292.401
• Mol File: 180746-14-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1,1'-Biphenyl, 4-[(phenylsulfinyl)methyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,1'-Biphenyl, 4-[(phenylsulfinyl)methyl]-(180746-14-9)
• EPA Substance Registry System: 1,1'-Biphenyl, 4-[(phenylsulfinyl)methyl]-(180746-14-9)

Safety Data

• Hazardous Substances Data: 180746-14-9(Hazardous Substances Data)

Upstream product

• 17114-78-2 9-tert-butylfluorene 
• 238-84-6 benzo[a]fluorene 
• 199-94-0 7H-benz[d,e]anthracene 
• 1572-46-9 9-benzylfluorene 
• 430430-71-0 ([1,1'-biphenyl]-4-ylmethyl)(phenyl)sulfane 
• 6099-23-6 1-(phenylsulfinyl)acetophenone 
• 2567-29-5 p-phenylbenzyl bromide 
• 16222-10-9 1-phenyl-2-(phenylthio)ethanone 
• 108-98-5 thiophenol 
• 376640-26-5 [1,1'-biphenyl]-4-ylmethyl methanesulfonate 
• 3597-91-9 biphenyl-4-yl methanol 
• 18916-14-8 trans-prop-2-ene-1,1,3-triyltribenzene 

Downstream Products

• 66785-28-2 lithium salt of 9-benzylfluorene 
• 238-84-6 benzo[a]fluorene 
• 17114-78-2 9-tert-butylfluorene 
• 199-94-0 7H-benz[d,e]anthracene 
• 18916-14-8 trans-prop-2-ene-1,1,3-triyltribenzene 
• 194733-29-4 4-((phenylsulfonyl)methyl)-1,1′-biphenyl 

Relevant articles and documents

A route to benzylic arylsulfoxides from β-ketosulfoxides

The K2CO3-mediated benzylation of β-ketosulfoxides 4 with 2.0?equiv of benzylic halides 5 affords benzylic arylsulfoxides 6 in moderate yields along with trace amounts of chalcones 7. The products 6 are assumed to form in situ intermediates of sulfenate anions from β-ketosulfoxides which are commonly involved in carbon–sulfur bond formation. A plausible mechanism has been proposed.