18209-60-4

Basic information

• Product Name: (N,N-DIMETHYLAMINO)DIMETHYLCHLOROSILANE
• Synonyms: SilanaMine,1-chloro-N,N,1,1-tetraMethyl-;1-chloro-n,n,1,1-tetramethyl-silanamin;(N,N-DIMETHYLAMINO)DIMETHYLCHLOROSILANE;Dimethylaminodimethylchlorosilane;1-chloro-N,N,1,1-tetramethylsilylamine;(N,N-DIMETHYLAMINO)DIMETHYLCHLOROSILANE 95%;Chlorodimethyl(dimethylamino)silane;N-(Chlorodimethylsilyl)-N-methylmethanamine
• CAS NO: 18209-60-4
• Molecular Formula: C₄H₁₂ClNSi
• Molecular Weight: 137.68
• EINECS: 242-095-3
• Mol File: 18209-60-4.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 108-109°C
• Flash Point: 7°C
• Appearance: /
• Density: 0,908 g/cm3
• Vapor Pressure: 70.4mmHg at 25°C
• Refractive Index: 1.422
• PKA: 5.61±0.70(Predicted)
• CAS DataBase Reference: (N,N-DIMETHYLAMINO)DIMETHYLCHLOROSILANE(CAS DataBase Reference)
• NIST Chemistry Reference: (N,N-DIMETHYLAMINO)DIMETHYLCHLOROSILANE(18209-60-4)
• EPA Substance Registry System: (N,N-DIMETHYLAMINO)DIMETHYLCHLOROSILANE(18209-60-4)

Safety Data

• Statements: 11-34
• Safety Statements: 9-16-26-33
• RIDADR: 2985
• TSCA: Yes
• Hazardous Substances Data: 18209-60-4(Hazardous Substances Data)

Usage

General Description

(N,N-DIMETHYLAMINO)DIMETHYLCHLOROSILANE is a chemical compound with the formula (CH3)2N(CH3)SiCl2. It is a colorless liquid that reacts with water to release hydrogen chloride gas. (N,N-DIMETHYLAMINO)DIMETHYLCHLOROSILANE is often used as a reagent for the preparation of organosilicon compounds and as a coupling agent for the functionalization of surfaces. It is also used in the production of silicone polymers and as a reactive intermediate in the synthesis of pharmaceuticals and agrochemicals. However, it is important to handle (N,N-DIMETHYLAMINO)DIMETHYLCHLOROSILANE with caution, as it is highly reactive and can be hazardous if not properly handled and stored.

InChI:InChI=1/C4H12ClNSi/c1-6(2)7(3,4)5/h1-4H3

Upstream product

• 124-40-3 dimethyl amine 
• 75-78-5 dimethylsilicon dichloride 
• 3768-58-9 bis(dimethylamino)dimethylsilane 
• 10038-98-9 germaniumtetrachloride 

Downstream Products

• 69185-21-3 p-Bromphenyl(dimethylamino)dimethylsilan 
• 22705-32-4 (dimethylamino)dimethylsilane 
• 13328-30-8 bis(N,N-dimethylamino)dichlorosilane 
• 75-78-5 dimethylsilicon dichloride 
• 86071-76-3 (2-Chlorphenyl)-dimethylamino-dimethylsilan 
• 86071-79-6 (2-Dimethylarsanophenyl)-dimethylaminodimethylsilan 
• 136559-68-7 1-(methoxydimethylsiloxy)-6-methylcyclohexene 
• 136559-67-6 1-(methoxydimethylsiloxy)-2-methylcyclohexene 
• 181231-67-4 Dimethylaminodimethyl-n-butylsilan 
• 86071-71-8 (2-Dimethylaminophenyl)dimethylamino-dimethylsilan 
• 86071-78-5 [(2-Dimethylphosphanyl-phenyl)-dimethyl-silanyl]-dimethyl-amine 
• 118319-20-3 Chloro-dimethyl-((E)-propenyl)-silane 
• 3768-58-9 bis(dimethylamino)dimethylsilane 
• 10038-98-9 germaniumtetrachloride 

Relevant articles and documents

Unsymmetrically substituted dimethyldiaminosilanes as ligands towards zirconium(IV)

Unsymmetrically substituted dimethyldiaminosilanes of the general formula SiMe2(NR2) (NR′2) have been prepared by treating LiNR2 with SiMe2C1(NR′2) (NR2, NR′2 = NMe2, NC4H 8, NHiPr, NHtBu, NHCH2CH2NMe2 or NHCH2CH2-OMe). Their ligating properties towards zirconium(iv) have been investigated as a function of the nitrogen substituents and the syntheses of the binary compound Zr[SiMe2-(NiPr)(NiBu)] 2 and of the zirconium derivatives ZrX3(L) [X = Cl, NMe2; L = SiMe(NR) (NR′2), NR = NiPr, NtBu, NCH 2CH2NMe2, NCH2CH2OMe; NR′2 = NMe2, NC4H8, NHiPr, NHtBu] are also reported. The solution structures and dynamics of the compounds have been elucidated by 1D/2D multinuclear NMR spectroscopy. Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004.

GROUP 4 METAL COMPLEX, PRODUCTION METHOD THEREOF, PREPARATION METHOD OF GROUP 4 METAL-CONTAINING THIN FILM

PROBLEM TO BE SOLVED: To provide a group 4 metal complex having excellent thermal stability and proper vapor pressure and suitable as a material for preparing a group 4 metal-containing thin film. SOLUTION: There is provided the group 4 metal complex represented by the general formula (1), where M represents a group 4 metal atom, R1, R2, R3 and R4 each represent independently a hydrogen atom or an alkyl group having 1 to 6 carbon atoms, R5, R6 and R7 each represent independently an alkyl group having 1 to 8 carbon atoms, R8, R9 and R10 each represent independently an alkyl group having 1 to 6 carbon atoms or a di (alkyl having 1 to 3 carbon atoms) amino group. SELECTED DRAWING: None COPYRIGHT: (C)2016,JPO&INPIT

Chloraminosilanes II. Preparation and spectroscopic studies on alkyl-(dimethylamino)chlorosilanes

Several new compounds containing both chloro and dimethylamino groups linked to silicon have been prepared. The general method involved reacting a solution of the appropriate polychlorosilane in ether at ca. - 50° with a chilled ethereal solution of dimethylamine. Prepared in this fashion were CH3Si(NMe2)Cl2, CH3Si(NMe2)2-Cl, PhSi(NMe2)Cl2, PhSi(NMe2)2Cl, CH3(H)Si(NMe2)Cl, (CH3)2Si(NMe2)Cl, CH2CH(CH3)Si(NMe2)Cl, and Ph2Si(NMe2)Cl. Comparison of the spectra of these compounds with those in the perhalo and peramine series showed that replacement of NMe2 for Cl resulted in an upfield shift of the resonances of the other groups linked to silicon, a shift which parallels that observed upon substitution of CH3 for Cl. The relationship of ν(SiH) in the IR and δ(SiH) in the NMR spectra was linear.