18640-62-5

Basic information

• Product Name: 3-(4-ETHYLPHENYL)-1-PROPENE
• Synonyms: 3-(4-ETHYLPHENYL)-1-PROPENE
• CAS NO: 18640-62-5
• Molecular Formula: C₁₁H₁₄
• Molecular Weight: 146.23
• Mol File: 18640-62-5.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 72°C 4,2mm
• Appearance: /
• CAS DataBase Reference: 3-(4-ETHYLPHENYL)-1-PROPENE(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(4-ETHYLPHENYL)-1-PROPENE(18640-62-5)
• EPA Substance Registry System: 3-(4-ETHYLPHENYL)-1-PROPENE(18640-62-5)

Safety Data

• Statements: 36/37/38
• Safety Statements: 26-36/37/39
• Hazardous Substances Data: 18640-62-5(Hazardous Substances Data)

Upstream product

• 1585-07-5 1-bromo-4-ethylbenzene 
• 106-95-6 allyl bromide 
• 52436-73-4 4-ethylbenzenediazonium tetrafluoroborate 

Downstream Products

• 14387-10-1 (4-ethyl-phenyl)-acetic acid 
• 127506-37-0 (E)-3-(4-ethylphenyl)acrylaldehyde 
• 1011301-86-2 (E)-3-(4-ethylphenyl)prop-2-en-1-ol 

Relevant articles and documents

Palladium-catalyzed allylic C-H oxidation under simple operation and mild conditions

We discovered an effective and simple system (Pd/BQ/air/r.t.) for making allylic alcohols through Pd-catalyzed allylic C-H bond functionalization. This approach exhibits advantages due to its simple operation, mild conditions, and environmentally benign features. By modifying reaction conditions, it can be suitable for preparing unsaturated aldehydes, allylic esters, ethers, and amines.

Palladium-catalyzed oxidative allylation of bis[(pinacolato)boryl]methane: Synthesis of homoallylic boronic esters

A palladium-catalyzed oxidative allylation of bis[(pinacolato)boryl]methane to afford the corresponding homoallylic organoboronic esters with moderate to excellent yields is reported. This novel transformation provides an efficient strategy for the construction of homoallylic organoboronic esters in one step with a broad substrate scope. It is proposed that the palladium-catalyzed oxidative allylic C-H bond activation process may be involved in the catalytic cycle.

Biocatalytic racemization of (hetero)aryl-aliphatic α- hydroxycarboxylic acids by Lactobacillus spp. proceeds via an oxidation-reduction sequence

The biocatalytic racemization of a range of (hetero)aryl- and (di)aryl-aliphatic α-hydroxycarboxylic acids has been achieved by using whole resting cells of Lactobacillus spp. The essentially mild (physiological) reaction conditions ensure the suppression of undesired side reactions, such as elimination, decomposition or condensation. Cofactor/inhibitor studies using a cell-free extract of Lactobacillus paracasei DSM 20207 reveal that the addition of redox cofactors (NAD+/NADH) leads to a distinct increase in the racemization rate, while strong inhibition is observed in the presence of Thio-NAD+, which suggests that the racemization proceeds by an oxidation-reduction sequence rather than involvement of a "racemase" enzyme. Wiley-VCH Verlag GmbH & Co. KGaA, 2006.