189017-49-0

Basic information

• Product Name: Methanone, (4-methylphenyl)[(2S,3R)-3-phenyloxiranyl]-
• CAS NO: 189017-49-0
• Molecular Formula: C16H14O2
• Molecular Weight: 238.286
• Mol File: 189017-49-0.mol
• Article Data: 26

Chemical Properties

• CAS DataBase Reference: Methanone, (4-methylphenyl)[(2S,3R)-3-phenyloxiranyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Methanone, (4-methylphenyl)[(2S,3R)-3-phenyloxiranyl]-(189017-49-0)
• EPA Substance Registry System: Methanone, (4-methylphenyl)[(2S,3R)-3-phenyloxiranyl]-(189017-49-0)

Safety Data

• Hazardous Substances Data: 189017-49-0(Hazardous Substances Data)

Upstream product

• 122-00-9 para-methylacetophenone 
• 100-52-7 benzaldehyde 
• 100-42-5 styrene 
• 104-87-0 4-methyl-benzaldehyde 
• 4224-96-8 3-phenyl-1-p-tolylprop-2-en-1-one 
• 14802-30-3 (E)-1-(4-methylphenyl)-3-phenyl-2-propen-1-one 

Relevant articles and documents

Asymmetric epoxidation of α,β-unsaturated ketones catalyzed by rare-earth metal amides RE[N(SiMe3)2]3with chiral TADDOL ligands

The catalytic asymmetric epoxidation of α,β-unsaturated ketones by tert-butylhydroperoxide (TBHP) has been well established using rare-earth metal amides RE[N(SiMe3)2]3 (RE = La(1), Nd(2), Sm(3), Y(4), Yb(5)) with chiral TADDOL ligands. It was found that

Highly Enantioselective Epoxidation of α,β-Unsaturated Ketones Using Amide-Based Cinchona Alkaloids as Hybrid Phase-Transfer Catalysts

A series of 20 one chiral epoxides were obtained with excellent yields (up to 99%) and enantioselectivities (up to >99% ee) using hybrid amide-based Cinchona alkaloids. Our method is characterized by low catalyst loading (0.5 mol %) and short reaction times. Moreover, the epoxidation process can be carried out in 10 cycles, without further catalyst addition to the reaction mixture. This methodology significantly enhance the scale of the process using very low catalyst loading.

The Synthesis of Hydrobenzoin-Based Monoaza Crown Ethers and Their Application as Recyclable Enantioselective Catalysts

Abstract: New recyclable monoaza-15-crown ethers have been synthesized starting from (R,R)-(+)- and (S,S)-(?)-hydrobenzoin. These macrocycles proved to be efficient and reusable phase transfer catalysts in a few asymmetric reactions under mild conditions.