22339-08-8

Basic information

• Product Name: [1R-(1alpha,2alpha,5alpha)]-4,6,6-trimethylbicyclo[3.1.1]hept-3-en-2-ol
• Synonyms: [1R-(1alpha,2alpha,5alpha)]-4,6,6-trimethylbicyclo[3.1.1]hept-3-en-2-ol;(1R,2S,5R)-4,6,6-Trimethylbicyclo[3.1.1]hepta-3-ene-2-ol;(1R,5β)-4,6,6-Trimethylbicyclo[3.1.1]hept-3-en-2β-ol;Ai3-23133;Einecs 244-920-2
• CAS NO: 22339-08-8
• Molecular Formula: C₁₀H₁₆O
• Molecular Weight: 152.23344
• EINECS: 244-920-2
• Mol File: 22339-08-8.mol
• Article Data: 59

Chemical Properties

• Boiling Point: 214.9°Cat760mmHg
• Flash Point: 84.5°C
• Appearance: /
• Density: 1.002g/cm³
• Storage Temp.: Refrigerator, Under inert atmosphere
• Solubility: Chloroform (Sparingly), Ethyl Acetate (Slightly), Methanol (Slightly)
• CAS DataBase Reference: [1R-(1alpha,2alpha,5alpha)]-4,6,6-trimethylbicyclo[3.1.1]hept-3-en-2-ol(CAS DataBase Reference)
• NIST Chemistry Reference: [1R-(1alpha,2alpha,5alpha)]-4,6,6-trimethylbicyclo[3.1.1]hept-3-en-2-ol(22339-08-8)
• EPA Substance Registry System: [1R-(1alpha,2alpha,5alpha)]-4,6,6-trimethylbicyclo[3.1.1]hept-3-en-2-ol(22339-08-8)

Safety Data

• Hazardous Substances Data: 22339-08-8(Hazardous Substances Data)

Usage

Uses

(+)-trans-Verbenol is synthesized as an inhibitor of Parkinsons disease.

Upstream product

• 80-56-8 Pinene 
• 80-56-8 rac-α-pinene 
• 7722-84-1 dihydrogen peroxide 
• 67-64-1 acetone 
• 7785-26-4 (-)-α-pinene 
• 98-83-9 isopropenylbenzene 
• 7785-70-8 (+)-α-pinene 
• 39863-91-7 trans-(R)-verbenol acetate 
• 546-67-8 lead(IV) tetraacetate 
• 1208105-24-1 (+)-verbenol acetate 
• 29135-40-8 (+)-trans-verbenol 4-nitrobenzoate 
• 18881-04-4 (S)-cis-Verbenol 
• 80-57-9 (-)-Verbenone 
• 18309-32-5 Verbenone 

Downstream Products

• 80-57-9 verbenone 
• 99-87-6 4-methylisopropylbenzene 
• 7316-84-9 pinan-4-ol 
• 190715-28-7 6,6-dimethyl4-methylidenebicyclo[3.1.1]hept-2-ene 
• 16814-28-1 (+/-)-4-trans-(2-Olivetyl)-pinen 
• 1203-21-0 2,6,6-trimethylbicyclo[3.1.1]hept-2-en-4-ol acetate 
• 22571-78-4 (+)-cis-pinononoic acid 
• 288848-24-8 (1S,3R)-3-acetyl-2,2-dimethylcyclobutane carboxylic acid 
• 916595-88-5 Acetic acid (2R,3R,4S,5R,6R)-4,5-diacetoxy-6-acetoxymethyl-2-(4,6,6-trimethyl-bicyclo[3.1.1]hept-3-en-2-yloxy)-tetrahydro-pyran-3-yl ester 
• 916595-90-9 (2R,3S,4S,5R,6R)-2-Hydroxymethyl-6-(4,6,6-trimethyl-bicyclo[3.1.1]hept-3-en-2-yloxy)-tetrahydro-pyran-3,4,5-triol 
• 18881-04-4 (S)-cis-Verbenol 

Relevant articles and documents

Selective Allylic Oxidation of Terpenic Olefins Using Co-Ag Supported on SiO2 as a Novel, Efficient, and Recyclable Catalyst

Co-Ag supported on the SiO2 catalyst was synthesized by the sol-gel method and characterized using XRD, FT-IR, TG-DTG, BET, CV, and SEM/EDX analysis. The catalytic performance of the resulting catalyst was examined by the oxidation of mono and sesquiterpenic olefins using hydrogen peroxide and tert-butyl peroxide as oxidant agents. Various parameters such as catalyst amount, temperature, and solvents have been studied. The Co-Ag supported on the SiO2 catalyst showed a high activity, selectivity, and recyclability for the selected oxidation reaction.

Cis-dioxidomolybdenum(VI) complexes with chiral tetradentate Schiff bases: Synthesis, spectroscopic characterization and catalytic activity in sulfoxidation and epoxidation

New chiral mononuclear cis-dioxidomolybdenum(VI) complexes, MoO2L1-MoO2L7, have been synthesized by the reaction of MoO2(acac)2 with tetradentate Schiff bases derived from various substitut