2461-75-8

Basic information

• Product Name: Ethanone,2,2'-dithiobis[1-phenyl-
• Synonyms: Acetophenone,2,2''-dithiodi- (6CI,7CI,8CI); Bis(2-oxo-2-phenylethyl) disulfide; Diphenacyldisulfide; NSC 677471; Phenacyl disulfide
• CAS NO: 2461-75-8
• Molecular Formula: C16H14 O2 S2
• Molecular Weight: 302.418
• Mol File: 2461-75-8.mol
• Article Data: 12

Chemical Properties

• CAS DataBase Reference: Ethanone,2,2'-dithiobis[1-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone,2,2'-dithiobis[1-phenyl-(2461-75-8)
• EPA Substance Registry System: Ethanone,2,2'-dithiobis[1-phenyl-(2461-75-8)

Safety Data

• Hazardous Substances Data: 2461-75-8(Hazardous Substances Data)

Upstream product

• 492-38-6 2-phenylacrylic acid 
• 4636-16-2 iodoacetophenone 
• 5399-30-4 2-oxo-2-phenylethylthiocyanate 
• 70-11-1 α-bromoacetophenone 
• 532-27-4 1-chloroacetophenone 
• 53392-49-7 phenacyl thioacetate 
• 2462-02-4 2-mercaptoacetophenone 
• 98-83-9 isopropenylbenzene 
• 2919-20-2 1,1-di(p-tolyl)ethylene 
• 1712-70-5 1-chloro-4-(1-methylethenyl)-benzene 
• 4356-69-8 1,1-bis-(4-methoxyphenyl)ethylene 
• 530-48-3 1,1-Diphenylethylene 
• 2648-61-5 2,2-dichloroacetophenone 
• 75697-81-3 1-methyl-2-phenacylthioimidazoline 

Downstream Products

• 91880-70-5 ω-<β-Chlor-aethylmercapto>-acetophenon 
• 17336-21-9 3-phenyl-1-thia-4-aza-spiro[4.5]dec-3-ene 
• 14006-54-3 3-chloro-1-benzothiophen-2-carbaldehyde 
• 1260001-52-2 1,2-bis[(2-phenyl-1,3-dioxolan-2-yl)methyl]disulfane 
• 357913-52-1 phenacyl methyl disulfide 
• 3844-31-3 trans-thioindigo 
• 66692-87-3 2-ethyl-4-phenyl-2,5-dihydro-thiazole 
• 98-86-2 acetophenone 
• 495-71-6 phenacylacetophenone 
• 25310-06-9 <α-Imino-benzyl>-<α-phenacylmercapto-phenacyl>-disulfid 
• 40531-91-7 N,N-dimethyl-2-oxo-2-phenylethanethioamide 
• 15441-18-6 1,1'-Diphenyl-2,2'-thiobis(ethanone) 
• 15441-14-2 bis-(1-benzoyl-3-oxo-3-phenyl-propyl)-sulfide 
• 94066-53-2 Diphenacyltrisulfid 

Relevant articles and documents

Visible-Light-Mediated Additive-Free Decarboxylative Ketonization Reaction of Acrylic Acids: An Access to α-Thiocyanate Ketones

Visible-light-mediated additive-free decarboxylative functionalization of acrylic acids has been developed. The reaction uses inexpensive organic dye 9,10-dicyanoanthracene as a photocatalyst and uses the ubiquitous dioxygen as both an oxygen source and an oxidant. Through this mild and environmentally friendly method, a series of important α-thiocyanate ketones can be generated from easily available acrylic acids and ammonium thiocyanate. In addition, the facile transformation of product α-thiocyanate ketones makes this method have great potential for application in organic and pharmaceutical chemistry.

TBAI-Catalyzed Reaction between N-Tosylhydrazones and Sulfur: A Procedure toward 1,2,3-Thiadiazole

A TBAI-catalyzed reaction between N-tosyl hydrazone and sulfur was developed, leading to 1,2,3-thiadiazoles in moderate to good yields. It represents a facile and practical procedure to access thiadiazole under metal-free conditions. This procedure serves

Regiocontrolled synthesis of ring-fused thieno[2,3-c]pyrazoles through 1,3-dipolar cycloaddition of nitrile imines with sulfur-based acetylenes

1,3-Dipolar cycloadditions of C-carboxymethyl-N-arylnitrile imines with substituted acetylenes bearing thiol or sulfone groups were studied. The sulfur controls the regiochemistry of the reaction, and this protocol was applied to the synthesis of ring-fus