259729-27-6Relevant articles and documents
Enantioselective borohydride reduction of N-diphenylphosphinyl imines using optically active cobalt(II) complex catalysts
Sugi, Kiyoaki D.,Nagata, Takushi,Yamada, Tohru,Mukaiyama, Teruaki
, p. 493 - 494 (1997)
The enantioselective borohydride reduction using optically active cobalt(II) complex catalysts was successfully applied to various aryl N-diphenylphosphinyl imines, and the corresponding reduced products were obtained in good yields with high enantiomeric excesses (up to 99% ee). The optically active primary amines were obtained by the successive hydrolysis under mild conditions.
