26336-38-9Relevant articles and documents
Molecular Ions of TRansient Species: Vinylamine Cation
Albrecht, Bruno,Allan, Michael,Haselbach, Edwin,Neuhaus, Louis
, p. 220 - 223 (1984)
Vinylamine 1 was prepared by thermolysis of cyclobutylamine and its photoelectron spectrum was measured.I1a = 8.20 eV and I1v = 8.65 eV were found, the dominant vinrational progression (ν = 725 cm-1) indicating that in the course of 1(X) -> 1+(X) flattening around the N-atom occurs.The Franck-Condon profile of this band, however, suggests that a skeletal mode of ν ca. 1400 cm-1 (observed also in the iso-?-electronic systems vinyl-alcohol-cation and allyl radical) may also be excited.Comparison with the data for the isomer acetaldehyde-imine 2 and its cation 2+ shows that the isomer couple 1/2 constitutes a further notable example for a relative thermochemical stability inversion on going from neutrals to the cations.
Polyamino salts of alpha-hydroxyacids, alpha-ketoacids and related compounds
-
, (2008/06/13)
Cosmetic compositions are described wherein α-hydroxyacids, α-ketoacids and related compounds are formed into amine salts through neutralization with a multi-amine functionalized polymer. Particularly preferred are glycolic acid and lactic acid salts of poly(ethylenimine).
REACTIONS RETRODIENIQUES-IX. SYNTHESE PAR THERMOLYSE ECLAIR ET ETUDE D'ENAMINES PRIMAIRES INSTABLES
Ripoll, J. L.,Lebrun, H.,Thuillier, A.
, p. 2497 - 2504 (2007/10/02)
Etheneamine 1 and its methyl derivatives 2-7 have been synthesized from the adducts 8-14 by a retro-Diels-Alder reaction under flash thermolytic conditions.The primary enamines 1-4 have been identified (IR, (1)H and (13)C NMR in a pure state at -80 deg C; at the same temperature, the enamines 5-7, less stable, are already accompanied by their tautomeric imines 33 or 34.When warmed up to room temperature, the enamines 1-7 lead, following to their substitution, either to nitrogen heterocycles (30, 42) or to acyclic azadienes (35-37, 39, 40).