2909-79-7 Usage
Description
4-TERT-BUTYL-N,N-DIMETHYLANILINE is an organic compound that serves as an efficient polymerization accelerator. It is known for its role in the oxidative coupling process with indole, catalyzed by potassium iodide. 4-TERT-BUTYL-N,N-DIMETHYLANILINE is particularly useful in the field of polymer chemistry due to its ability to initiate free-radical/cationic hybrid photopolymerizations of acrylates and epoxides.
Uses
Used in Polymer Industry:
4-TERT-BUTYL-N,N-DIMETHYLANILINE is used as an amine initiator for free-radical/cationic hybrid photopolymerizations of acrylates and epoxides. Its application reason is to enhance the polymerization process, leading to improved efficiency and product quality in the production of various polymers.
Used in Chemical Research:
In the field of chemical research, 4-TERT-BUTYL-N,N-DIMETHYLANILINE is used as a catalyst in the oxidative coupling of tert-butyl-N,N-dimethylaniline with indole. This process is significant for the synthesis of various complex organic compounds and contributes to the advancement of chemical knowledge and innovation.
Check Digit Verification of cas no
The CAS Registry Mumber 2909-79-7 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 2,9,0 and 9 respectively; the second part has 2 digits, 7 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 2909-79:
(6*2)+(5*9)+(4*0)+(3*9)+(2*7)+(1*9)=107
107 % 10 = 7
So 2909-79-7 is a valid CAS Registry Number.
InChI:InChI=1/C12H19N/c1-12(2,3)10-6-8-11(9-7-10)13(4)5/h6-9H,1-5H3
2909-79-7Relevant articles and documents
Yoder et al.
, p. 539 (1969)
Aminomethylation of Aryl Bromides by Nickel-Catalyzed Electrochemical Redox Neutral Cross Coupling
Ma, Yueyue,Hong, Jufei,Yao, Xiantong,Liu, Chengyu,Zhang, Ling,Fu, Youtian,Sun, Maolin,Cheng, Ruihua,Li, Zhong,Ye, Jinxing
supporting information, p. 9387 - 9392 (2021/12/17)
We develop an electrochemical nickel-catalyzed aminomethylation of aryl bromides under mild conditions. The convergent paired electrolysis makes full use of anode and cathode processes, free of a terminal oxidant, a sacrificial anode, a metal reductant, and a prefunctionalized radical precursor. In addition, this method exhibits wide functional group tolerance (63 examples), including some sensitive substituents and aromatic heterocycles. This redox neutral cross coupling provides a more environmentally friendly and synthetic practical protocol for forging C(sp2)–C(sp3) bonds.
Fe(III)-catalyzed Oxidative Povarov Reaction with Molecular Oxygen Oxidant
Park, Du Yong,Hwang, Joon Young,Kang, Eun Joo
supporting information, p. 798 - 801 (2021/04/09)
The synthesis of tetrahydroquinoline derivatives from dimethyl anilines and enamides has been developed by Fe(III)-phenanthroline complex under aerobic condition. The oxidation of tertiary anilines involving a single electron transfer of Fe(phen)3(PF6)3 afforded the iminium ion intermediate, which reacted with electron-rich alkenes to build a six-membered N-heterocycles containing quaternary carbon center via the oxidative Povarov reaction process.