677-22-5 Usage
Description
TERT-BUTYLMAGNESIUM CHLORIDE, also known as a Grignard reagent, is an organomagnesium compound derived from magnesium chloride and tert-butyl chloride. It is characterized by its clear faint grey to grey-brown or light appearance and is known for its reactivity in organic synthesis.
Uses
Used in Organic Synthesis:
TERT-BUTYLMAGNESIUM CHLORIDE is used as a reagent for various organic synthesis processes. It facilitates the formation of carbon-carbon bonds and is particularly useful in the synthesis of complex organic molecules.
Used in Copper-Catalyzed Cross-Coupling Reactions:
In the field of chemical research and pharmaceuticals, TERT-BUTYLMAGNESIUM CHLORIDE is used as a reagent for copper-catalyzed cross-coupling reactions with primary-alkyl halides. This application is significant for the development of new compounds and materials with specific properties and functions.
Check Digit Verification of cas no
The CAS Registry Mumber 677-22-5 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 6,7 and 7 respectively; the second part has 2 digits, 2 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 677-22:
(5*6)+(4*7)+(3*7)+(2*2)+(1*2)=85
85 % 10 = 5
So 677-22-5 is a valid CAS Registry Number.
InChI:InChI=1/C4H9.ClH.Mg/c1-4(2)3;;/h1-3H3;1H;/q;;+1/p-1/rC4H9Mg.ClH/c1-4(2,3)5;/h1-3H3;1H/q+1;/p-1
677-22-5Relevant articles and documents
Parris,Ashby
, p. 1206,1208 (1971)
COMPLEXES OF IMIDAZOLE LIGANDS
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Page/Page column 81, (2012/01/05)
Metal imidazolate complexes are described where imidazoles ligands functionalized with bulky groups and their anionic counterpart, i.e., imidazolates are described. Compounds comprising one or more such polyalkylated imidazolate anions coordinated to a metal or more than one metal, selected from the group consisting of alkali metals, transition metals, lanthanide metals, actinide metals, main group metals, including the chalcogenides, are contemplated. Alternatively, multiple different imidazole anions, in addition to other different anions, can be coordinated to metals to make new complexes. The synthesis of novel compounds and their use to form thin metal containing films is also contemplated.
METHOD OF MANUFACTURING AN AMINOARYL-CONTAINING ORGANOSILICON COMPOUND AND METHOD OF MANUFACTURING AN INTERMEDIATE PRODUCT OF THE AFOREMENTIONED COMPOUND
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Page/Page column 17, (2008/06/13)
To provide an aminoaryl-containing organosilicon compound with high efficiency, after protecting amino groups of a haloaniline compound with a specific compound, to form a Grignard reagent and to deprotect the aforementioned groups by reacting the Grignard reagent with a silicon compound.