34918-74-6

Basic information

• Product Name: Benzenecarboximidoyl chloride, N-(4-methoxyphenyl)-
• CAS NO: 34918-74-6
• Molecular Formula: C14H12ClNO
• Molecular Weight: 245.708
• Mol File: 34918-74-6.mol
• Article Data: 21

Chemical Properties

• CAS DataBase Reference: Benzenecarboximidoyl chloride, N-(4-methoxyphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenecarboximidoyl chloride, N-(4-methoxyphenyl)-(34918-74-6)
• EPA Substance Registry System: Benzenecarboximidoyl chloride, N-(4-methoxyphenyl)-(34918-74-6)

Safety Data

• Hazardous Substances Data: 34918-74-6(Hazardous Substances Data)

Upstream product

• 7472-54-0 N-(p-methoxyphenyl)benzamide 
• 98-88-4 benzoyl chloride 
• 104-94-9 4-methoxy-aniline 

Downstream Products

• 27228-22-4 N-(4-methoxy-phenyl)-benzimidoyl isothiocyanate 
• 1281681-02-4 3-(N-4-methoxyphenylbenzimidoyl)-1-(3-pyridylmethyl)thiourea 
• 1281681-04-6 1-ethoxycarbonylmethyl-3-(N-4-methoxyphenylbenzymidoyl)thiourea 
• 38259-63-1 N-(4-methoxy-2-nitrophenyl)benzamide 
• 98888-78-9 (4-Methoxy-phenyl)-thiobenzoyl-thiocarbamic acid O-ethyl ester 
• 98888-77-8 (4-Methoxy-phenyl)-thiobenzoyl-thiocarbamic acid O-methyl ester 
• 57761-73-6 1-(4'-methoxyphenyl)-5-phenyl-1H-tetrazole 
• 783-08-4 [4-(benzylideneamino)phenyl]methanol 
• 87010-80-8 N₁-methyl-N₁,N₂-di-p-methoxyphenylbenzamidine 
• 62718-51-8 N₁-methyl-N₁-phenyl-N₂-p-methoxyphenylbenzamidine 
• 74172-72-8 N-(4-Methoxyphenyl)benzamid-phenylhydrazon 
• 36664-34-3 5-(4-chloro-phenyl)-1-[N-(4-methoxy-phenyl)-benzimidoyl]-1H-pyrazole-3-carboxylic acid methyl ester 
• 113934-52-4 N-(p-methoxyphenyl)benzimidic ester of 3,5,7-trimethyltropolone 
• 87010-81-9 N₁-methyl-N₁-m-chlorophenyl-N₂-p-methoxyphenylbenzamidine 

Relevant articles and documents

Synthesis of N-Hydroxy-N-(o-chlorophenyl)-N'-(p-methoxyphenyl)benzamidine Hydrochloride and Its Reactions with Various Metal Ions

A new reagent N-hydroxy-N-(o-chlorophenyl)-N'-(p-methoxyphenyl)benzamidine hydrochloride, has been synthesized and is characterized on the basis of mp, elemental analysis, IR and UV spectra.The reactions of the reagent with metal ions suggest that new met

Acylation of 2-benzylpyridine N-oxides and subsequent in situ [3,3]-sigamatropic rearrangement reaction

An effective method for the acylation of 2-benzylpyridine N-oxides and their fast in situ [3,3]-sigmatropic rearrangement was reported. This transformation has a wide substrate scope under mild conditions, giving moderate to excellent yields. The application for the synthesis of chiral phenyl-2-pyridylmethanol products was briefly explored. Furthermore, an interesting example of tandem substitution and in situ [3,3]-sigamatropic rearrangement of 2-benzylpyridine N-oxide with benzenecarboximidoyl chloride was reported.

α-Imino Iridium Carbenes from Imidoyl Sulfoxonium Ylides: Application in the One-Step Synthesis of Indoles

Imidoyl sulfoxonium ylides are presented for the first time as potential precursors to generate α-imino metal-carbene intermediates and applied in direct C-H functionalization reactions catalyzed by [Ir(cod)Cl]2 (4 mol %) to provide 2-substituted indoles (up to 70% yield) in just one step. This class of sulfur ylide is successfully obtained from imidoyl chloride and dimethylsulfoxonium methylide (23 new examples in 45-85% yield) or by imino group formation from the corresponding β-keto sulfoxonium ylides and anilines in the presence of TiCl4 as a Lewis acid (9 examples in 33-94% yield).