384836-05-9

Basic information

• Product Name: N-(3,3-difluoro-2-propenyl)-N-(2-propynyl)tosylamide
• Synonyms: N-(3,3-difluoro-2-propenyl)-N-(2-propynyl)tosylamide
• CAS NO: 384836-05-9
• Molecular Weight: 285.315
• Mol File: 384836-05-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-(3,3-difluoro-2-propenyl)-N-(2-propynyl)tosylamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(3,3-difluoro-2-propenyl)-N-(2-propynyl)tosylamide(384836-05-9)
• EPA Substance Registry System: N-(3,3-difluoro-2-propenyl)-N-(2-propynyl)tosylamide(384836-05-9)

Safety Data

• Hazardous Substances Data: 384836-05-9(Hazardous Substances Data)

Upstream product

• 75-61-6 dibromodifluoromethane 
• 317842-50-5 4-methyl-N-(2-oxoethyl)-N-(prop-2-yn-1-yl)benzenesulfonamide 

Downstream Products

• 1254840-78-2 diethyl 4-difluoromethyl-3-(dimethylphenylsilylmethyl)cyclopent-2-ene-1,1-dicarboxylate 
• 1254840-79-3 (E)-diethyl 3-difluoromethyl-4-(dimethylphenylsilylmethylene)cyclopentane-1,1-dicarboxylate 
• 133886-43-8 2,3,3a,4-tetrahydro-2-[(4-methylphenyl)sulfonyl]-cyclopenta[c]pyrrol-5(1H)-one 
• 384836-06-0 N-(3-fluoro-2-propenyl)-N-(2-propynyl)tosylamide 

Relevant articles and documents

Scope and limitation of intramolecular Pauson-Khand reaction of fluorine-containing enynes

Intramolecular Pauson-Khand reaction of various fluorine-containing enynes was investigated under various conditions. The reaction of the substrates, which have fluorine atom(s) or fluorine-containing group(s) attached to alkenyl moiety, gave the corresponding cyclopentenones in low to moderate yield, while that of the substrates bearing fluorine-containing groups attached to alkynyl moiety afforded the corresponding cyclopentenones in low to high yield.