436850-67-8

Basic information

• Product Name: N-benzyl-N,4-dimethylbenzenesulfinamide
• Synonyms: N-benzyl-N,4-dimethylbenzenesulfinamide
• CAS NO: 436850-67-8
• Molecular Weight: 259.372
• Mol File: 436850-67-8.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: N-benzyl-N,4-dimethylbenzenesulfinamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-benzyl-N,4-dimethylbenzenesulfinamide(436850-67-8)
• EPA Substance Registry System: N-benzyl-N,4-dimethylbenzenesulfinamide(436850-67-8)

Safety Data

• Hazardous Substances Data: 436850-67-8(Hazardous Substances Data)

Upstream product

• 6873-55-8 p-tolylsulfinyl amide 
• 103-67-3 benzyl-methyl-amine 
• 672-78-6 methyl p-toluene sulfinate 
• 1858-86-2 Ethyl p-toluenesulfinate 
• 6873-90-1 N-benzyl-4-methylbenzenesulfinamide 
• 74-88-4 methyl iodide 
• 824-79-3 sodium 4-methylbenzenesulfinate 

Downstream Products

• 672-78-6 methyl p-toluene sulfinate 
• 103-67-3 benzyl-methyl-amine 

Relevant articles and documents

Rare-Earth-Catalyzed Transsulfinamidation of Sulfinamides with Amines

A rare-earth-catalyzed transsulfinamidation of primary sulfinamides with alkyl, aryl, and heterocyclic amines for the synthesis of diverse secondary and tertiary sulfinamides has been realized. Unlike transition metal-catalyzed cross-coupling approaches restricted to non-commercially available disubstituted O-benzoyl hydroxylamines, this newly developed protocol is suitable for diverse readily available primary and secondary amines without any modifications. Excellent catalytic activity and selectivity are achieved with Eu(OTf)3 under mild reaction conditions, which extends the applicability of rare-earth catalysis.

Copper-Catalyzed Transsulfinamidation of Sulfinamides as a Key Step in the Preparation of Sulfonamides and Sulfonimidamides

Secondary or tertiary sulfinamides are prepared by copper-catalyzed transsulfinamidation of primary sulfinamides with O-benzoyl hydroxylamines. Subsequent oxidations of the resulting products lead to the corresponding sulfonamides. Treatment of N-aryl sulfinamides with O-benzoyl hydroxylamines under copper catalysis provides N-aryl sulfonimidamides.